Milled Cocoa Extract Polyphenol Preservation

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Solution Overview

Problem

Traditional cocoa processing methods, such as fermentation and roasting, significantly reduce the concentration of polyphenolic compounds in cocoa products, particularly higher oligomeric polyphenols, leading to a loss of their health benefits and affecting the flavor and bitterness of cocoa-based products.

Innovation Solution

The development of a milled cocoa extract with a reduced particle size of less than 15 microns, containing at least 300 milligrams of total cocoa polyphenols per gram, which is obtained by solvent extracting unfermented or underfermented cocoa beans and incorporating it into food products, pharmaceuticals, or dietary supplements, thereby preserving the polyphenol content and improving flavor profiles.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Quantity of substance

If traditional cocoa processing methods (fermentation and roasting) are used, then the flavor and color of cocoa products are developed, but the concentration of polyphenolic compounds is significantly reduced

Engineering Contradiction:
Improveconcentration of polyphenolic compoundsVSAvoidprocessing complexity
Core Design Contradiction:
Quantity of substanceVSEase of manufacture

Solution Approach 1:

The patent applies preliminary action by using solvent extraction on unfermented or underfermented cocoa beans before the fermentation and roasting processes that would otherwise degrade polyphenols. This allows the polyphenolic compounds to be isolated and preserved in their high-concentration state, while the remaining cocoa material can still undergo traditional processing for flavor and color development without losing the extracted polyphenols.

Inventive Principle:
Principle #10Preliminary action

Solution Approach 2:

The patent directly applies extraction by using solvents to remove and isolate polyphenolic compounds from cocoa beans before traditional processing. This separates the polyphenol-rich extract from the cocoa material, allowing the extract to be preserved independently while the remaining material undergoes conventional fermentation and roasting for flavor development without polyphenol loss.

Inventive Principle:
Principle #2Taking out (Extraction)

2Quantity of substance

If cocoa beans are fermented and roasted, then characteristic flavor and color are developed, but higher oligomeric polyphenols are reduced more rapidly than lower oligomers

Engineering Contradiction:
Improvehigher oligomeric polyphenol concentrationVSAvoidpolyphenol composition stability
Core Design Contradiction:
Quantity of substanceVSStability of the object's composition

Solution Approach 1:

The patent performs solvent extraction of polyphenols before fermentation and roasting processes occur. This preliminary action captures the polyphenolic compounds, particularly higher oligomeric polyphenols, in their intact high-molecular-weight forms before they would be degraded by the thermal and chemical processes of traditional cocoa processing.

Inventive Principle:
Principle #10Preliminary action

Solution Approach 2:

The patent uses solvent extraction to selectively remove polyphenolic compounds from cocoa beans, separating them from the material that undergoes fermentation and roasting. This extraction preserves the complete polyphenol profile including higher oligomers, while allowing the remaining cocoa material to develop characteristic flavor and color through traditional processing.

Inventive Principle:
Principle #2Taking out (Extraction)

3Ease of operation

If milled cocoa extract with reduced particle size is used, then solubility and bioavailability are improved, but manufacturing complexity increases

Engineering Contradiction:
Improvesolubility and bioavailabilityVSAvoidmilling process complexity
Core Design Contradiction:
Ease of operationVSDevice complexity

Solution Approach 1:

The patent replaces complex mechanical milling processes with a chemical dissolution approach. The polyphenolic extract is dissolved in a suitable solvent to create a liquid or semi-liquid formulation, which inherently provides excellent solubility and bioavailability without requiring intensive mechanical size reduction. This substitution of mechanical processing with chemical dissolution simplifies the manufacturing process while achieving the desired solubility benefits.

Inventive Principle:
Principle #28Mechanics substitution (Replace mechanical system)

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The milled cocoa extract maintains high cocoa polyphenol content and reduces bitterness and astringency in chocolate products, enhancing their flavor and nutritional value without the loss of polyphenols during processing, as demonstrated in milk chocolate and other cocoa-based products.

Implementation Method 1

The cocoa extracts are obtained by solvent extracting cocoa beans, also referred to as cacao beans, or the cocoa solids prepared from the cocoa beans or nibs

Methodology Applied
Scientific EffectSolvent extraction: Liquid-Liquid Extraction

Data Source

PatentUS10155017B2Edible products having a high cocoa polyphenol content and improved flavor and the milled cocoa extracts used therein
Publication Date: 2018.12.18 MARS INC
  • US10155017B2 patent drawing
  • US10155017B2 patent drawing
  • US10155017B2 patent drawing

AI summary

Milling dry extracts containing cocoa polyphenols (CPs) to reduce the particle size improves the flavor of edible products (e.g., foods, medical foods, nutritional supplements, and pharmaceuticals) or additives containing the milled cocoa extracts. The products, e.g., chocolates, are less astringent and less bitter. The mean particle size after milling is less than about 15 microns, preferably less than about 10 microns, and most preferably less than about 5 microns. The total CP content of the milled extracts is at least about 300 milligrams and preferably about 300 to about 700 milligrams per gram of milled extract. The additives consist essentially of (i) the milled high CP cocoa extract and (ii) a fat (e.g., cocoa butter), an oil (e.g., vegetable oil), or a syrup (e.g., corn syrup).