MIM Capacitor Electrode Surface Roughness Control

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Solution Overview

Problem

Existing semiconductor devices with MIM capacitors face challenges in maintaining withstand voltage values and reducing variations as the thickness of the main conductive film increases, as current manufacturing techniques do not adequately address the thickness dependence of the withstand voltage value, leading to performance degradation.

Innovation Solution

A semiconductor device manufacturing method involving the sequential formation of films such as titanium, titanium nitride, aluminum, and titanium nitride layers for the lower electrode, with a specific surface roughness to thickness ratio of 14% or less, to improve the planarity and reduce surface roughness of the electrode, thereby stabilizing the withstand voltage value.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Quantity of substance

If the thickness of the main conductive film is increased, then the capacitance of the MIM capacitor is increased, but the surface roughness increases and the withstand voltage value decreases with increased variations

Engineering Contradiction:
ImprovecapacitanceVSAvoidwithstand voltage value
Core Design Contradiction:
Quantity of substanceVSReliability

Solution Approach 1:

The patent applies parameter changes by controlling the thickness of the aluminum main conductive film within a specific range (50 nm to 200 nm) and managing the surface roughness ratio relative to the insulating film thickness. By optimizing these parameters, the invention achieves adequate capacitance while suppressing surface roughness to maintain high withstand voltage values and reduce variations.

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent uses a composite structure consisting of multiple layers including barrier films (titanium, titanium nitride), the main conductive film (aluminum), and insulating films. This composite material approach allows each layer to contribute specific properties: barrier films prevent diffusion, the aluminum film provides conductivity and capacitance, and the insulating film provides dielectric properties, collectively achieving both high capacitance and high withstand voltage.

Inventive Principle:
Principle #40Composite materials

2Quantity of substance

If the thickness of the main conductive film is increased, then the capacitance is improved, but the planarity of the electrode surface deteriorates

Engineering Contradiction:
ImprovecapacitanceVSAvoidplanarity of electrode surface
Core Design Contradiction:
Quantity of substanceVSManufacturing precision

Solution Approach 1:

The patent controls the thickness of the aluminum main conductive film within a specific range (50 nm to 200 nm) and manages the surface roughness ratio relative to the insulating film thickness. By optimizing these parameters, the invention achieves adequate capacitance while suppressing surface roughness to maintain high planarity.

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent forms barrier films (titanium and titanium nitride layers) before depositing the aluminum main conductive film. These preliminary barrier films provide a smooth foundation that prevents aluminum grain growth and surface roughening, thereby maintaining planarity even as the aluminum film thickness increases for higher capacitance.

Inventive Principle:
Principle #10Preliminary action

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

This approach effectively suppresses the decrease in withstand voltage value and variations, enhancing the performance and yield rate of MIM capacitors by maintaining a low surface roughness and improving the (111) orientation of the main conductive film, even as the thickness of the main conductive film increases.

Implementation Method 1

a main conductive film containing aluminum is formed

Methodology Applied
Scientific EffectPhysical Vapour Deposition: Physical Vapour Deposition

Implementation Method 2

heat treatment is performed at a temperature higher than the formation temperature of the conductive film, thereby reorienting the Al crystal grains contained in the conductive film

Methodology Applied
Scientific EffectHeat Treatment: Heat Treatment

Implementation Method 3

reorienting the Al crystal grains contained in the conductive film

Methodology Applied
Scientific EffectCrystallisation: Crystallisation

Data Source

PatentUS9142608B2Manufacturing method of semiconductor device and semiconductor device
Publication Date: 2015.09.22 ASAHI KASEI MICRODEVICES CORP
  • US9142608B2 patent drawing
  • US9142608B2 patent drawing
  • US9142608B2 patent drawing

AI summary

A step of forming a stacked film serving as a lower electrode, a step of forming an insulating film serving as a capacitive film on the stacked film, and a step of patterning the insulating film and the stacked film are performed. In the step of forming the stacked film, a film containing titanium, a film containing titanium and nitrogen, a main conductive film containing aluminum, a film containing titanium, and a film containing titanium and nitrogen are sequentially formed from below. The ratio of the surface roughness of the upper surface of the stacked film to the thickness of the insulating film is 14% or less.