Mineral Foam Stability via Bubble Size Control

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Solution Overview

Problem

Existing methods for producing mineral foams are unable to create stable foams that prevent slumping when poured vertically, due to issues like coalescence and Ostwald ripening, which affects their stability and thermal insulation properties.

Innovation Solution

A continuous process involving the preparation of cement slurries and aqueous foams with specific properties, where the D50 of air bubbles is less than 400 µm, is used to create a stable mineral foam with low thermal conductivity and high stability, eliminating the need for autoclave or thermal treatment steps.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Stability of the object's composition

If mineral foam is poured into an element of considerable height, then the mineral foam may slump due to a lack of stability, but vertical pouring is necessary for construction applications

Engineering Contradiction:
Improvefoam stabilityVSAvoidvertical pouring capability
Core Design Contradiction:
Stability of the object's compositionVSEase of operation

Solution Approach 1:

The patent changes the physical parameters of the foam by controlling bubble size (D50 ≤ 400 μm) and using specific surfactant concentrations to achieve optimal stability. This allows the foam to maintain its structure during vertical pouring from heights ≥ 2 meters while still being pourable

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent introduces surfactants as intermediary substances that mediate between the cement slurry and air bubbles. These surfactants reduce surface tension and stabilize the foam structure, enabling the foam to resist gravitational slumping during vertical pouring operations

Inventive Principle:
Principle #24Intermediary (Mediator)

2Stability of the object's composition

If the mineral foam contains larger air bubbles, then the foam is easier to produce, but the foam becomes unstable and slumps due to coalescence and Ostwald ripening

Engineering Contradiction:
Improvefoam stabilityVSAvoidfoam production complexity
Core Design Contradiction:
Stability of the object's compositionVSEase of manufacture

Solution Approach 1:

The patent specifies a precise parameter range for bubble size (D50 ≤ 400 μm) that prevents Ostwald ripening and coalescence. This controlled parameter range maintains foam stability while using conventional foaming equipment and procedures, keeping manufacturing simple

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent performs preliminary stabilization of the foam structure by controlling bubble nucleation and growth during the foaming process. By pre-establishing the optimal bubble size distribution before pouring, the foam maintains stability without requiring complex post-processing or specialized equipment

Inventive Principle:
Principle #10Preliminary action

3Strength

If the mineral foam has higher density, then the mechanical strength is improved, but the thermal insulation properties deteriorate

Engineering Contradiction:
Improvemechanical strengthVSAvoidthermal conductivity
Core Design Contradiction:
StrengthVSTemperature

Solution Approach 1:

The patent optimizes the water-to-cement ratio and foam concentration to achieve a density range (100-600 kg/m³) that balances mechanical strength and thermal insulation. This parameter optimization ensures adequate structural strength while maintaining low thermal conductivity for effective insulation

Inventive Principle:
Principle #35Parameter changes

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The process produces mineral foams with excellent stability, low thermal conductivity, and improved mechanical properties, allowing for vertical pouring without significant slumping and enhanced thermal insulation in construction materials.

Implementation Method 1

the D50 of the bubbles is less than or equal to 400 μm

Methodology Applied
Scientific EffectSurface tension: Surface Tension

Implementation Method 2

These slump problems of the foam may be due to coalescence phenomena

Methodology Applied
Scientific EffectCoalescence phenomena:

Implementation Method 3

to Ostwald ripening phenomena or to draining phenomena

Methodology Applied
Scientific EffectOstwald ripening phenomena: Ostwald Ripening

Implementation Method 4

mineral foam is very advantageous for many applications due to its thermal insulation properties

Methodology Applied
Scientific EffectThermal insulation: Thermal Insulation

Implementation Method 5

This material is generally more lightweight than typical concrete due to its pores or empty spaces

Methodology Applied
Scientific EffectPorosity: Porosity

Implementation Method 6

cast the slurry of foamed cement and leave it to set

Methodology Applied
Scientific EffectSetting:

Data Source

PatentEP2834206B1Insulating mineral foam
Publication Date: 2017.02.08 SA CIMENTS LAFARGE
  • EP2834206B1 patent drawing
  • EP2834206B1 patent drawing
  • EP2834206B1 patent drawing

AI summary

The present invention relates to a process for production of insulating mineral foams produced from a slurry of cement and an aqueous foam. The invention also relates to the mineral foam obtained by this process, its uses and elements of construction produced with this mineral foam.