Binder Composition for Fine Mineral Pelletizing

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Solution Overview

Problem

Existing pelletization methods for fine iron ore require high silica content binders like clay minerals, which increase silica content in pellets and can lead to sintering issues, and require significant hydrated lime, causing volume expansion and structural damage during the pelletization process.

Innovation Solution

A binder composition comprising a colloid agent that exerts cohesive forces and a synthetic polymer that disperses mineral particles, reducing the need for silica-based binders and hydrated lime by forming a synergistic effect that enhances the compressive strength of green and dried pellets.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Strength

If clay minerals are used as binders to achieve sufficient pellet strength, then the adhesive and cohesive forces are improved, but the silica content in the finished pellet increases

Engineering Contradiction:
Improvepellet strengthVSAvoidsilica content
Core Design Contradiction:
StrengthVSQuantity of substance

Solution Approach 1:

The invention changes the chemical composition parameters of the binder system by replacing clay minerals with a combination of organic binder and inorganic compound. This substitution maintains the necessary adhesive and cohesive forces while reducing the silica content in the finished pellet, directly resolving the contradiction between pellet strength and silica content

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The invention uses a composite binder system consisting of an organic binder (such as starch, cellulose, or lignin) combined with an inorganic compound (such as calcium carbonate or magnesium oxide). This composite approach provides both the mechanical bonding strength needed for pellet integrity and the chemical properties to reduce silica content, thereby resolving the contradiction between these two parameters

Inventive Principle:
Principle #40Composite materials

2Strength

If calcium oxide is hydrated during the pelletization process to increase mechanical stability, then the cohesive force is improved, but the volume expansion damages the pellet structure

Engineering Contradiction:
Improvemechanical stabilityVSAvoidvolume expansion
Core Design Contradiction:
StrengthVSVolume of moving object

Solution Approach 1:

The invention performs the hydration of calcium oxide in advance, before the pelletization process. By pre-hydrating the calcium oxide to form calcium hydroxide, the volume expansion occurs before pellet formation, avoiding structural damage. The pre-treated binder then provides cohesive force during pelletization without causing harmful volume changes, resolving the contradiction between mechanical stability and volume expansion

Inventive Principle:
Principle #10Preliminary action

Solution Approach 2:

The invention separates the hydration process from the pelletization process into distinct stages. The binder is pre-treated (hydrated) separately, then applied to the ore during pelletization. This segmentation allows the volume expansion to occur independently without affecting pellet structure, while still providing the necessary mechanical stability

Inventive Principle:
Principle #1Segmentation

3Quantity of substance

If fine mineral particles are used as feed material, then the ore concentration is improved, but the particles pack into a nonpermeable bed and are carried away as dust

Engineering Contradiction:
Improveore concentrationVSAvoidpermeability
Core Design Contradiction:
Quantity of substanceVSReliability

Solution Approach 1:

The invention uses a binder as an intermediary substance between fine mineral particles. The binder coats and binds the fine particles together, forming larger agglomerates that maintain the high ore concentration of fine particles while preventing them from packing into nonpermeable beds and reducing dust carryaway, thus resolving the contradiction between ore concentration and permeability

Inventive Principle:
Principle #24Intermediary (Mediator)

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The binder composition improves the compressive strength of pellets and reduces the amount of silica and hydrated lime required, resulting in more stable and efficient pelletization with reduced dust loss and improved permeability in blast furnaces.

Implementation Method 1

a) at least one colloid agent which exerts a cohesive force on the mineral particles forming the pellets

Methodology Applied
Scientific EffectCohesive force: Cohesion

Implementation Method 2

b) at least one synthetic polymer which disperses mineral particles in the pellets

Methodology Applied
Scientific EffectDispersion: Dispersion (of waves)

Data Source

PatentUS11124855B2Binder composition for the agglomeration of fine minerals and pelletizing process
Publication Date: 2021.09.21 CLARIANT SA
  • US11124855B2 patent drawing
  • US11124855B2 patent drawing
  • US11124855B2 patent drawing

AI summary

A process for pelletizing particles of a fine mineral ore, the process comprises the steps ofa) mixing the particles of a fine mineral ore with a binder composition to obtain a pellet feed,b) forming the pellet feed into balls,c) drying the balls to form dried balls,d) preheating the dried balls at 60 to 105° C. until constant weight to form preheated balls,e) subsequently heating the preheated balls to a temperature of 1200° C. to 1400° C. to obtain pellets,wherein the binder composition comprisesa) at least one colloid agent which exerts a cohesive force on the particles of a fine mineral ore forming the pellets, andb) at least one synthetic polymer which disperses the particles of a fine mineral ore in the pellets,wherein the synthetic polymer is a maleic acid/acrylic acid or a maleic acid/methacrylic acid copolymer.