Mist-Based CO2 Absorber Size Reduction

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Solution Overview

Problem

Conventional post-combustion carbon capture systems, particularly those using packed bed reactors, are large and costly due to the need for extensive absorption towers, limiting the practicality and efficiency of CO2 removal from combustion exhaust streams.

Innovation Solution

A two-stage mist-based absorption system where a liquid mist with droplets smaller than 70 micrometers is used to increase the interfacial area with the gas stream, combined with an electrostatic separation zone to capture and recycle the mist, reducing the size and cost of the absorption system.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Reliability

If packed bed reactors are used to capture >90% of CO2 from power plants, then CO2 capture efficiency is improved, but the size and capital cost of absorption towers increase significantly

Engineering Contradiction:
ImproveCO2 capture efficiencyVSAvoidabsorption tower size
Core Design Contradiction:
ReliabilityVSVolume of stationary object

Solution Approach 1:

The invention changes the physical state and size parameters of the absorbent from bulk liquid in packed beds to fine droplets (1-100 micrometers) in aerosol form. This parameter change increases the surface area to volume ratio by several orders of magnitude, enabling high CO2 capture efficiency in a much smaller reactor volume. The droplet-based approach transforms the absorption process from a volume-intensive operation to a surface-area-intensive operation, resolving the contradiction between capture efficiency and tower size.

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The invention uses gas-dynamic principles to suspend and circulate liquid droplets within the gas stream. By introducing the absorbent as an aerosol that flows with the gas phase, the system eliminates the need for large packed beds and gravity-driven liquid flow. The pneumatic transport of droplets through the reactor enables efficient contact between absorbent and flue gas in a compact configuration, directly addressing the size reduction requirement while maintaining high capture efficiency.

Inventive Principle:
Principle #29Pneumatics and hydraulics

2Ease of manufacture

If absorption towers are reduced in size to lower capital costs, then economic viability is improved, but CO2 capture efficiency may be compromised

Engineering Contradiction:
Improvecapital costVSAvoidCO2 capture efficiency
Core Design Contradiction:
Ease of manufactureVSReliability

Solution Approach 1:

The invention changes the physical state and size parameters of the absorbent from bulk liquid in packed beds to fine droplets (1-100 micrometers) in aerosol form. This parameter change increases the surface area to volume ratio by several orders of magnitude, enabling high CO2 capture efficiency in a much smaller reactor volume. The droplet-based approach transforms the absorption process from a volume-intensive operation to a surface-area-intensive operation, resolving the contradiction between capture efficiency and tower size.

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The invention uses gas-dynamic principles to suspend and circulate liquid droplets within the gas stream. By introducing the absorbent as an aerosol that flows with the gas phase, the system eliminates the need for large packed beds and gravity-driven liquid flow. The pneumatic transport of droplets through the reactor enables efficient contact between absorbent and flue gas in a compact configuration, directly addressing the size reduction requirement while maintaining high capture efficiency.

Inventive Principle:
Principle #29Pneumatics and hydraulics

3Reliability

If liquid absorbent is used in conventional packed bed reactors, then CO2 absorption is effective, but the system requires large towers over 20 meters in height

Engineering Contradiction:
ImproveCO2 absorption effectivenessVSAvoidtower height
Core Design Contradiction:
ReliabilityVSLength of stationary object

Solution Approach 1:

The invention changes the physical state and size parameters of the absorbent from bulk liquid in packed beds to fine droplets (1-100 micrometers) in aerosol form. This parameter change increases the surface area to volume ratio by several orders of magnitude, enabling high CO2 capture efficiency in a much smaller reactor volume. The droplet-based approach transforms the absorption process from a volume-intensive operation to a surface-area-intensive operation, resolving the contradiction between capture efficiency and tower size.

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The invention uses gas-dynamic principles to suspend and circulate liquid droplets within the gas stream. By introducing the absorbent as an aerosol that flows with the gas phase, the system eliminates the need for large packed beds and gravity-driven liquid flow. The pneumatic transport of droplets through the reactor enables efficient contact between absorbent and flue gas in a compact configuration, directly addressing the size reduction requirement while maintaining high capture efficiency.

Inventive Principle:
Principle #29Pneumatics and hydraulics

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

This approach achieves CO2 capture efficiencies of up to 95% while significantly reducing the size and capital expenditure of CO2 absorber units, making post-combustion carbon capture more practical and economically viable.

Implementation Method 1

expose the liquid mist to the gas stream under conditions that facilitate transfer of at least some of the gaseous species from the gas stream to the liquid mist

Methodology Applied
Scientific EffectAbsorption: Absorption (physical)

Implementation Method 2

an electrostatic separation zone along the gas flow pathway, fluidly connected to the gaseous species absorption zone and configured to electrostatically separate at least some of the liquid mist from the gas stream

Methodology Applied
Scientific EffectElectrostatic separation: Electrostatics

Data Source

PatentUS20250001355A1Systems and methods for removing species from gas streams
Publication Date: 2025.01.02 MASSACHUSETTS INST OF TECH
  • US20250001355A1 patent drawing
  • US20250001355A1 patent drawing
  • US20250001355A1 patent drawing

AI summary

Various embodiments address removal of one or more species from a gas stream by exposing the gas stream to divided portions of a fluid, such as droplets of water or mist, where the fluid, and/or content of the fluid, can absorb or modify the species and thereby remove it at least partially from the gas stream. Removal of CO2 from a combustion exhaust stream is one embodiment.