Mixed Alloy Defect Redirection for Deep UV LED

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Solution Overview

Problem

High dislocation densities and mechanical stresses in deep UV light emitting diodes (LEDs) lead to poor crystal quality and reduced operating lifetime, exacerbated by lattice mismatch between substrates and structural layers, particularly in AlGaN/sapphire templates, which impede efficient light emission and device reliability.

Innovation Solution

A defect redirection layer with varying Al content is introduced between the substrate and the high-Al content MQWH active region, comprising a mixed alloy region of alternating AlN and GaN layers, gradually transitioning from high to low Al content to reduce threading dislocations and strain-induced cracking.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Reliability

If AlGaN template layer is formed on sapphire substrate, then device structure is established, but high dislocation density propagates to active layer reducing light emission efficiency

Engineering Contradiction:
Improvelight emission efficiencyVSAvoidthreading dislocation density
Core Design Contradiction:
ReliabilityVSObject-affected harmful factors

Solution Approach 1:

A defect redirection layer composed of AlN and GaN layers is introduced as an intermediary between the AlGaN template layer and the InGaN active layer. This intermediary layer redirects threading dislocations away from the growth direction, preventing them from reaching the active layer and maintaining high light emission efficiency.

Inventive Principle:
Principle #24Intermediary (Mediator)

Solution Approach 2:

The defect redirection layer is segmented into multiple alternating layers of AlN and GaN with different thicknesses. The AlN layers have higher dislocation density while the GaN layers have lower dislocation density, creating a segmented structure that effectively redirects dislocations through the layered configuration.

Inventive Principle:
Principle #1Segmentation

2Illumination intensity

If high Al content is used in structural layers, then deep UV emission is achieved, but lattice mismatch increases causing mechanical stress and cracking

Engineering Contradiction:
Improvedeep UV emission wavelengthVSAvoidmechanical stress resistance
Core Design Contradiction:
Illumination intensityVSStrength

Solution Approach 1:

The aluminum content parameter is varied through the layer structure. The AlGaN template layer has high Al content (50-70%) for deep UV emission, while the defect redirection layer uses alternating AlN (100% Al) and GaN (0% Al) layers. This parameter change creates a gradual transition that reduces lattice mismatch stress while maintaining the required deep UV emission capability.

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The defect redirection layer is a composite structure combining AlN and GaN materials in alternating layers. This composite approach allows optimization of each layer's properties - AlN provides high Al content for UV emission while GaN provides mechanical strength and lower dislocation density, together resolving the contradiction between deep UV emission and mechanical stress resistance.

Inventive Principle:
Principle #40Composite materials

Data Source

PatentUS8513643B2Mixed alloy defect redirection region and devices including same
Publication Date: 2013.08.20 GENESEE VALLEY INNOVATIONS LLC
  • US8513643B2 patent drawing
  • US8513643B2 patent drawing
  • US8513643B2 patent drawing

AI summary

An optical semiconductor device such as a light emitting diode is formed on a transparent substrate having formed thereon a template layer, such as AlN, which is transparent to the wavelength of emission of the optical device. A mixed alloy defect redirection region is provided over the template layer such that the composition of the defect redirection region approaches or matches the composition of the regions contiguous thereto. For example, the Al content of the defect redirection region may be tailored to provide a stepped or gradual Aluminum content from template to active layer. Strain-induced cracking and defect density are reduced or eliminated.