Mixed Bed Ion Exchange Resin Segmentation for Ultrapure Water

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Solution Overview

Problem

Current ion exchange media in water deionization systems face challenges in achieving high kinetic performance without increasing hydraulic pressure, which limits the compactness and capacity of water purification systems, especially in ultrapure water production.

Innovation Solution

A method involving a combination of standard ion exchange media with small bead ion exchange media, where water is first passed through a mixed bed ion exchanger with beads of 0.5-0.7 mm diameter and then through a second mixed bed ion exchanger with beads less than 0.5 mm diameter, maintaining a volume ratio between 10:1 and 1:5, to enhance kinetic performance and capacity while minimizing pressure drop.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Productivity

If small bead ion exchange media (diameter < 0.5 mm) is used to improve kinetic performance, then ion exchange capacity and compactness are enhanced, but hydraulic pressure increases significantly

Engineering Contradiction:
Improveion exchange capacityVSAvoidhydraulic pressure
Core Design Contradiction:
ProductivityVSStress or pressure

Solution Approach 1:

The ion exchange system is segmented into two distinct stages with different bead sizes. The first stage uses standard bead size (0.5-0.7 mm) to handle bulk ion exchange with low pressure drop, while the second stage uses small bead size (< 0.5 mm) to provide high kinetic performance and polishing. This segmentation allows each stage to be optimized for its specific function, resolving the contradiction between capacity and pressure.

Inventive Principle:
Principle #1Segmentation

Solution Approach 2:

Different regions of the water purification system are assigned different local qualities in terms of bead size. The upstream region (first ion exchanger) uses larger beads suitable for high flow capacity, while the downstream region (second ion exchanger) uses smaller beads for high kinetic performance. This local differentiation allows the system to achieve both low pressure drop and high ion exchange capacity without compromise.

Inventive Principle:
Principle #3Local quality

2Stress or pressure

If standard ion exchange media (bead diameter 0.5-0.7 mm) is used, then hydraulic pressure remains low, but kinetic performance and capacity are limited

Engineering Contradiction:
Improvehydraulic pressureVSAvoidion exchange capacity
Core Design Contradiction:
Stress or pressureVSProductivity

Solution Approach 1:

The system merges two types of ion exchange media with different bead sizes into a sequential configuration. The first ion exchanger with standard beads and the second ion exchanger with small beads work together in series, combining the advantages of both media types - low pressure drop from standard beads and high kinetic performance from small beads - to achieve superior overall system performance.

Inventive Principle:
Principle #5Merging (Combining)

3Volume of moving object

If only small bead ion exchange media is used throughout the system, then compactness and kinetic performance improve, but pressure drop increases and lifespan decreases

Engineering Contradiction:
Improvesystem compactnessVSAvoidresin bed lifespan
Core Design Contradiction:
Volume of moving objectVSDuration of action of stationary object

Solution Approach 1:

The resin bed is segmented into two zones with different bead sizes. The first zone with larger beads承受s the mechanical stress of high flow rates and protects the second zone with small beads from excessive pressure that would cause fragmentation. This segmentation preserves the small beads in the second zone, extending their operational lifespan while maintaining system compactness.

Inventive Principle:
Principle #1Segmentation

Solution Approach 2:

The first ion exchanger with standard-sized beads acts as a cushioning element before the water enters the second ion exchanger with small beads. It absorbs and mitigates the hydraulic pressure and mechanical stress, providing protective pre-treatment that prevents premature wear and fragmentation of the more vulnerable small beads downstream, thereby extending overall system lifespan.

Inventive Principle:
Principle #11Beforehand cushioning (Prior cushioning)

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

This combination achieves high-performance water polishing with increased capacity and compactness of the consumable media, reducing pressure drop and extending the lifespan of the resin bed while maintaining ultrapure water quality.

Implementation Method 1

Ion exchangers, also called ion exchange resins throughout this invention, are known and proven for the elimination of ionic impurities from water in pure and ultrapure water production

Methodology Applied
Scientific EffectIon exchange: Ion Exchange

Implementation Method 2

In the state of the art the final polishing step in ultrapure water production is accomplished by using ion exchange media allowing for the removal of anions and cations

Methodology Applied
Scientific EffectIon exchange: Ion Exchange

Data Source

PatentEP3580179B1A method for producing ultrapure water
Publication Date: 2024.01.17 MERCK PATENT GMBH
  • EP3580179B1 patent drawingFigure 1
  • EP3580179B1 patent drawingFigure 2A~2B
  • EP3580179B1 patent drawingFigure 3A

AI summary

The present invention relates to a method for producing purified water comprising a step (a) of passing water through a first mixed bed ion exchanger comprising beads having a diameter between 0.5 and 0.7 mm and a step (b) of passing water through a second mixed bed ion exchanger comprising beads having a diameter of less than 0.5 mm. The invention further relates to a module comprising the first and second mixed bed ion exchanger and to a water treatment system for producing ultrapure water comprising the first and second mixed bed ion exchanger.