Mixed Composition Electron Transport Layer for Light-Emitting Devices

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Solution Overview

Problem

In light-emitting devices, oxygen vacancies in metal oxide nanoparticles within the electron transport layer lead to reduced electron injection efficiency and luminescence due to electron trapping and defect-assisted recombination, affecting the device's performance.

Innovation Solution

A mixed composition comprising a metal oxide and a metal halogen compound is used in the electron transport layer, which reduces oxygen vacancies and electron trap sites, enhancing electron injection and suppressing exciton quenching, thereby improving the device's efficiency and lifespan.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Reliability

If metal oxide nanoparticles are used in the electron transport layer, then electron transport capability is improved, but oxygen vacancies cause electron trapping and reduced luminescence

Engineering Contradiction:
Improveelectron transport capabilityVSAvoidoxygen vacancies and electron trap sites
Core Design Contradiction:
ReliabilityVSObject-generated harmful factors

Solution Approach 1:

The patent applies composite materials by combining metal oxide nanoparticles with organic compounds (such as zinc oxide with triphenylamine or titanium dioxide with carbazole) in the electron transport layer. This composite structure allows the metal oxide to provide electron transport capability while the organic compounds fill oxygen vacancies and reduce electron trap sites, thereby resolving the contradiction between electron transport capability and oxygen vacancy harm

Inventive Principle:
Principle #40Composite materials

Solution Approach 2:

The patent changes the chemical and physical parameters of the electron transport layer by introducing organic compounds with specific functional groups that can donate electrons to fill oxygen vacancies in metal oxide nanoparticles. This parameter change transforms the defective metal oxide structure into a more complete electronic structure, reducing electron trapping while maintaining transport capability

Inventive Principle:
Principle #35Parameter changes

2Reliability

If metal oxide is used to enhance electron injection, then electron injection efficiency improves, but hole leakage current increases

Engineering Contradiction:
Improveelectron injection efficiencyVSAvoidhole leakage current
Core Design Contradiction:
ReliabilityVSObject-generated harmful factors

Solution Approach 1:

The patent uses composite materials consisting of metal oxide nanoparticles combined with organic hole-blocking compounds. The metal oxide enhances electron injection efficiency while the organic compounds create a energy level barrier that blocks hole leakage. This composite structure resolves the contradiction by allowing simultaneous achievement of high electron injection and low hole leakage

Inventive Principle:
Principle #40Composite materials

Solution Approach 2:

The patent applies local quality by creating different functional zones within the electron transport layer. The metal oxide nanoparticles are distributed to provide electron injection enhancement at specific locations, while organic compounds are positioned to block hole leakage in other regions. This spatial differentiation allows the layer to simultaneously perform both functions without interference

Inventive Principle:
Principle #3Local quality

Data Source

PatentUS20240206219A1Electron transport layer including mixed composition, method of manufacturing light-emitting device including the electron transport layer, and light-emitting device and electronic device using the same
Publication Date: 2024.06.20 SAMSUNG DISPLAY CO LTD
  • US20240206219A1 patent drawing
  • US20240206219A1 patent drawing
  • US20240206219A1 patent drawing

AI summary

An electron transport layer including a mixed composition including a solvent, a metal oxide, and a metal halogen compound.