Mixed Ether Vaseline Substitute Melting Range

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Solution Overview

Problem

Current cosmetic and pharmaceutical preparations face challenges in finding substitutes for petroleum jelly that offer a wide melting range and sensory properties similar to Vaseline, while also being derived from renewable sources and avoiding the accumulation of paraffins in the body.

Innovation Solution

A mixture of mixed ethers is developed through a condensation reaction of unbranched fatty alcohols with specific chain lengths, isostearyl alcohol, and optional fatty alcohols, optimized to have a melting range between -25°C and +70°C, replicating the application and sensory properties of petroleum jelly.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Reliability

If petroleum jelly is used as an ointment base, then it provides good topical tolerability and a wide melting range, but it leads to accumulation of paraffins in the body and closes skin pores

Engineering Contradiction:
Improvetopical tolerabilityVSAvoidaccumulation of paraffins in body
Core Design Contradiction:
ReliabilityVSObject-affected harmful factors

Solution Approach 1:

The patent changes the chemical composition parameters from petroleum-based hydrocarbons to plant-based triglycerides and waxes, while maintaining the desired melting range and topical tolerability properties. This substitution resolves the contradiction by eliminating paraffin accumulation while preserving the beneficial sensory and tolerability characteristics.

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent employs readily available plant-based materials (coconut oil, palm oil, shea butter, beeswax) that can be easily sourced and processed, replacing the need for petroleum extraction and refining. These natural materials are biodegradable and do not accumulate in the body, thus resolving the harmful accumulation issue while maintaining effectiveness.

Inventive Principle:
Principle #27Cheap short-living objects (Disposable)

2Adaptability or versatility

If beeswax and vegetable oil are used as a substitute for petroleum jelly, then they are derived from renewable raw materials, but they cannot be produced in large quantities in the short term

Engineering Contradiction:
Improverenewable raw materialsVSAvoidproduction quantity
Core Design Contradiction:
Adaptability or versatilityVSProductivity

Solution Approach 1:

The patent combines multiple plant-based materials (coconut oil, palm oil, shea butter, beeswax) in specific proportions to create a composite ointment base. This merging of materials allows for large-scale production by utilizing the availability of each individual component, while maintaining the renewable and sustainable characteristics.

Inventive Principle:
Principle #5Merging (Combining)

Solution Approach 2:

The invention creates a composite formulation using four different plant-based components, each contributing specific properties. This composite approach enables scalable production by leveraging the individual availability and production capacity of each material, while achieving the desired rheological and sensory properties that single materials cannot provide.

Inventive Principle:
Principle #40Composite materials

3Adaptability or versatility

If previous replacement bases for petroleum jelly are used, then they are extracted from renewable raw materials, but they have relatively narrow melting ranges

Engineering Contradiction:
Improverenewable raw materialsVSAvoidmelting range
Core Design Contradiction:
Adaptability or versatilityVSTemperature

Solution Approach 1:

The patent adjusts the melting range parameter by carefully selecting and proportioning plant-based materials with different melting points. Coconut oil (low melting point), palm oil (medium melting point), shea butter (higher melting point), and beeswax (highest melting point) are combined to achieve a wide overall melting range that matches petroleum jelly, while remaining renewable.

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

By creating a composite of four plant-based materials with progressively different melting characteristics, the patent achieves a wide composite melting range. The lower-melting coconut and palm oils provide liquidity at lower temperatures, while shea butter and beeswax maintain structure at higher temperatures, collectively achieving a wide melting range comparable to petroleum jelly.

Inventive Principle:
Principle #40Composite materials

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The mixed ethers provide a broad melting range and improved application properties, such as increased foam in surfactant systems, making them suitable replacements for petroleum jelly in cosmetic and pharmaceutical preparations.

Implementation Method 1

A mixture of mixed ethers is developed through a condensation reaction of unbranched fatty alcohols with specific chain lengths, isostearyl alcohol, and optional fatty alcohols

Methodology Applied
Scientific EffectCondensation reaction:

Implementation Method 2

they have a melting range between -25 °C and +70 °C, measured according to dynamic differential scanning calorimetry (DSC), the width of the melting range being at least 30 temperature degrees and the maximum of the melting range is 35 ± 10 °C

Methodology Applied
Scientific EffectMelting: Melting

Data Source

PatentEP2814453B1Mixed ether as vaseline substitute
Publication Date: 2017.08.02 BASF SE
  • EP2814453B1 patent drawing
  • EP2814453B1 patent drawing

AI summary

The invention relates to mixed esters, the use thereof in cosmetic and/or pharmaceutical preparations, and to cosmetic and/or pharmaceutical preparations containing mixed esters. Ester mixtures with a melting range of between -25°C and +70°C are particularly suitable for use as a Vaseline substitute, the melting range spanning at least 30 temperature degrees and the maximum melting range being 35 ±10°C. Said ester mixtures can be obtained, for example, by means of condensation reaction of: a) 25 to 90% by weight of unbranched fatty alcohols with a chain length of 12 to 18 carbon atoms, b) 5 to 50% by weight of isostearyl alcohol, c) 0 to 35% by weight of a fatty alcohol with a chain length of 20 and/or 22 carbon atoms and, d) 0 to 25% by weight of a fatty alcohol with 8 and/or 10 carbon atoms.