Mixed Matrix Membrane Stabilized Molecular Sieve Interface
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Solution Overview
Problem
Current polymeric membrane materials for gas separation face a trade-off between permeability and selectivity, with existing membranes either having high selectivity but low permeability or vice versa, and issues of material compatibility and adhesion at the inorganic solid/polymer interface in mixed matrix membranes (MMMs) hinder their large-scale industrial production.
Innovation Solution
The development of high-performance mixed matrix membranes (MMMs) using stabilized concentrated suspensions with uniformly dispersed polymer-stabilized molecular sieves and at least two types of polymers as the continuous blend polymer matrix, where molecular sieves are dispersed using ultrasonic mixing and mechanical stirring, and a polymer stabilizer forms good adhesion at the molecular sieve/polymer interface to reduce voids and defects.
Engineering Contradictions & Design Principles
Engineering Contradiction Analysis
1Manufacturing precision
If polymer membranes are used for gas separation, then selectivity can be improved, but permeability decreases
Solution Approach 1:
The patent creates mixed matrix membranes by combining inorganic molecular sieve particles with polymer matrices. The molecular sieves provide high selectivity through their uniform pore structures, while the polymer matrix maintains flexibility and permeability. This composite approach allows the membrane to achieve both high selectivity and acceptable permeability, overcoming the traditional trade-off between these two properties.
Solution Approach 2:
The patent utilizes porous molecular sieve materials with controlled pore sizes to create selective pathways for gas transport. These porous inorganic fillers provide size-selective separation mechanisms that enhance membrane selectivity without completely blocking permeability, as the pores are designed to allow specific gas molecules to pass through while rejecting others.
2Manufacturing precision
If inorganic membranes such as zeolite and carbon molecular sieve membranes are used, then permeability and selectivity are improved, but manufacturing cost and difficulty increase
Solution Approach 1:
Instead of using entirely inorganic membranes which are difficult and expensive to manufacture, the patent creates composite mixed matrix membranes where inorganic molecular sieve particles are dispersed within a polymer matrix. This approach retains the high permeability and selectivity benefits of inorganic materials while utilizing the ease of processing and lower cost associated with polymer membranes, thereby improving manufacturability.
Solution Approach 2:
The patent introduces polymer matrices as intermediary materials that facilitate the integration of inorganic molecular sieve particles into membrane structures. The polymer acts as a binding medium that holds the inorganic particles in place while allowing for straightforward processing techniques such as casting and extrusion, thus bridging the gap between high-performance inorganic materials and ease of manufacture.
3Device complexity
If molecular sieves are dispersed in polymer matrix without stabilization, then membrane fabrication is simplified, but adhesion at the interface deteriorates causing voids and defects
Solution Approach 1:
The patent introduces coupling agents or surface-modified molecular sieves as intermediary substances at the interface between inorganic particles and polymer matrices. These intermediaries improve interfacial adhesion by creating chemical or physical bonds between the dissimilar materials, eliminating voids and defects while maintaining relatively simple fabrication processes. The coupling agents act as bridges that enhance compatibility between the inorganic fillers and organic polymer matrix.
Applied Scientific Principles
This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.
Function Achieved in This Case
This approach enhances the selectivity and permeability of MMMs significantly, allowing them to surpass the limitations of traditional polymer membranes and achieve consistent performance, making them suitable for large-scale industrial production and various gas and vapor separations.
Implementation Method 1
mixed matrix membranes containing inorganic fillers such as molecular sieves embedded in a polymer matrix
Implementation Method 2
the sieving phase in a solid/polymer mixed matrix scenario can have a selectivity that is significantly larger than the pure polymer
Implementation Method 3
dispersing the molecular sieve filler particles in at least one solvent by ultrasonic mixing and/or mechanical stirring
Data Source
AI summary
The present invention discloses a novel method of making high performance mixed matrix membranes (MMMs) using stabilized concentrated suspensions of solvents, uniformly dispersed polymer stabilized molecular sieves, and at least two different types of polymers as the continuous blend polymer matrix. MMMs as dense films or asymmetric flat sheet or hollow fiber membranes fabricated by the method described in the current invention exhibit significantly enhanced permeation performance for separations over the polymer membranes made from the continuous blend polymer matrix. MMMs of the present invention are suitable for a wide range of gas, vapor, and liquid separations such as alcohol/water, CO2/CH4, H2/CH4, O2/N2, CO2/N2, olefin/paraffin, iso/normal paraffins, and other light gases separations.