Mixed Matrix Membrane Stabilized Molecular Sieve Interface

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Solution Overview

Problem

Current polymeric membrane materials for gas separation face a trade-off between permeability and selectivity, with existing membranes either having high selectivity but low permeability or vice versa, and issues of material compatibility and adhesion at the inorganic solid/polymer interface in mixed matrix membranes (MMMs) hinder their large-scale industrial production.

Innovation Solution

The development of high-performance mixed matrix membranes (MMMs) using stabilized concentrated suspensions with uniformly dispersed polymer-stabilized molecular sieves and at least two types of polymers as the continuous blend polymer matrix, where molecular sieves are dispersed using ultrasonic mixing and mechanical stirring, and a polymer stabilizer forms good adhesion at the molecular sieve/polymer interface to reduce voids and defects.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Manufacturing precision

If polymer membranes are used for gas separation, then selectivity can be improved, but permeability decreases

Engineering Contradiction:
ImproveselectivityVSAvoidpermeability
Core Design Contradiction:
Manufacturing precisionVSProductivity

Solution Approach 1:

The patent creates mixed matrix membranes by combining inorganic molecular sieve particles with polymer matrices. The molecular sieves provide high selectivity through their uniform pore structures, while the polymer matrix maintains flexibility and permeability. This composite approach allows the membrane to achieve both high selectivity and acceptable permeability, overcoming the traditional trade-off between these two properties.

Inventive Principle:
Principle #40Composite materials

Solution Approach 2:

The patent utilizes porous molecular sieve materials with controlled pore sizes to create selective pathways for gas transport. These porous inorganic fillers provide size-selective separation mechanisms that enhance membrane selectivity without completely blocking permeability, as the pores are designed to allow specific gas molecules to pass through while rejecting others.

Inventive Principle:
Principle #31Porous materials

2Manufacturing precision

If inorganic membranes such as zeolite and carbon molecular sieve membranes are used, then permeability and selectivity are improved, but manufacturing cost and difficulty increase

Engineering Contradiction:
Improvepermeability and selectivityVSAvoidmanufacturing cost and difficulty
Core Design Contradiction:
Manufacturing precisionVSEase of manufacture

Solution Approach 1:

Instead of using entirely inorganic membranes which are difficult and expensive to manufacture, the patent creates composite mixed matrix membranes where inorganic molecular sieve particles are dispersed within a polymer matrix. This approach retains the high permeability and selectivity benefits of inorganic materials while utilizing the ease of processing and lower cost associated with polymer membranes, thereby improving manufacturability.

Inventive Principle:
Principle #40Composite materials

Solution Approach 2:

The patent introduces polymer matrices as intermediary materials that facilitate the integration of inorganic molecular sieve particles into membrane structures. The polymer acts as a binding medium that holds the inorganic particles in place while allowing for straightforward processing techniques such as casting and extrusion, thus bridging the gap between high-performance inorganic materials and ease of manufacture.

Inventive Principle:
Principle #24Intermediary (Mediator)

3Device complexity

If molecular sieves are dispersed in polymer matrix without stabilization, then membrane fabrication is simplified, but adhesion at the interface deteriorates causing voids and defects

Engineering Contradiction:
Improvefabrication simplicityVSAvoidadhesion and defect-free interface
Core Design Contradiction:
Device complexityVSReliability

Solution Approach 1:

The patent introduces coupling agents or surface-modified molecular sieves as intermediary substances at the interface between inorganic particles and polymer matrices. These intermediaries improve interfacial adhesion by creating chemical or physical bonds between the dissimilar materials, eliminating voids and defects while maintaining relatively simple fabrication processes. The coupling agents act as bridges that enhance compatibility between the inorganic fillers and organic polymer matrix.

Inventive Principle:
Principle #24Intermediary (Mediator)

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

This approach enhances the selectivity and permeability of MMMs significantly, allowing them to surpass the limitations of traditional polymer membranes and achieve consistent performance, making them suitable for large-scale industrial production and various gas and vapor separations.

Implementation Method 1

mixed matrix membranes containing inorganic fillers such as molecular sieves embedded in a polymer matrix

Methodology Applied
Scientific EffectMolecular sieve: Molecular Sieve

Implementation Method 2

the sieving phase in a solid/polymer mixed matrix scenario can have a selectivity that is significantly larger than the pure polymer

Methodology Applied
Scientific EffectAdsorption: Adsorption

Implementation Method 3

dispersing the molecular sieve filler particles in at least one solvent by ultrasonic mixing and/or mechanical stirring

Methodology Applied
Scientific EffectUltrasonic vibration: Ultrasonic Vibration

Data Source

PatentUS7815712B2Method of making high performance mixed matrix membranes using suspensions containing polymers and polymer stabilized molecular sieves
Publication Date: 2010.10.19 UOP LLC

AI summary

The present invention discloses a novel method of making high performance mixed matrix membranes (MMMs) using stabilized concentrated suspensions of solvents, uniformly dispersed polymer stabilized molecular sieves, and at least two different types of polymers as the continuous blend polymer matrix. MMMs as dense films or asymmetric flat sheet or hollow fiber membranes fabricated by the method described in the current invention exhibit significantly enhanced permeation performance for separations over the polymer membranes made from the continuous blend polymer matrix. MMMs of the present invention are suitable for a wide range of gas, vapor, and liquid separations such as alcohol/water, CO2/CH4, H2/CH4, O2/N2, CO2/N2, olefin/paraffin, iso/normal paraffins, and other light gases separations.