Mixed Refrigerant Cooling for PDH Effluent Separation

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Solution Overview

Problem

Current Propane Dehydrogenation (PDH) separation systems face high power consumption, increased costs due to turbo-expander/generator sets, high Reactor Effluent Compressor discharge pressure, and limited flexibility in adjusting olefin and hydrogen separation temperatures.

Innovation Solution

A Mixed Refrigerant (MR) system with heat exchangers and drums is used to provide refrigeration, eliminating the need for turbo-expander/generator sets and allowing for reduced Reactor Effluent Compressor discharge pressure, while enabling independent adjustment of refrigeration levels and reducing capital and operating costs.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Reliability

If turbo-expander/generator sets are used to de-pressurize reactor effluent, then refrigeration is provided for separation, but power consumption increases and maintenance requirements increase

Engineering Contradiction:
Improvesystem reliabilityVSAvoidpower consumption
Core Design Contradiction:
ReliabilityVSUse of energy by moving object

Solution Approach 1:

The patent removes the turbo-expander/generator sets from the system entirely, extracting the problematic component that causes high power consumption and maintenance requirements. Instead, a mixed refrigerant compression system is implemented that provides the necessary refrigeration without the energy-intensive expansion machinery, thereby improving reliability while reducing power consumption.

Inventive Principle:
Principle #2Taking out (Extraction)

Solution Approach 2:

The mechanical turbo-expander/generator system is replaced with a mixed refrigerant compression system that uses compression and heat exchange mechanisms instead of expansion turbines. This substitution eliminates the need for complex mechanical moving parts that require maintenance and consume significant power, while still achieving the required refrigeration effect for olefin separation.

Inventive Principle:
Principle #28Mechanics substitution (Replace mechanical system)

2Reliability

If high discharge pressure is used in Reactor Effluent Compressor, then separation is achieved, but capital costs and operating costs increase

Engineering Contradiction:
Improveseparation efficiencyVSAvoidcapital cost
Core Design Contradiction:
ReliabilityVSEase of manufacture

Solution Approach 1:

The patent changes the pressure parameter profile in the system by using a mixed refrigerant compression system that operates at lower discharge pressures compared to conventional single-stage compression. This parameter change allows effective separation to be achieved without requiring excessively high compressor discharge pressures, thereby reducing both capital costs for equipment rated for high pressure and operating costs associated with high-pressure operation.

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The use of mixed refrigerant compositions (comprising multiple hydrocarbon components in specific ratios) enables effective separation at lower pressures. The composite nature of the refrigerant mixture allows for optimized heat exchange and phase separation characteristics that maintain separation efficiency while operating under less demanding pressure conditions, reducing equipment costs.

Inventive Principle:
Principle #40Composite materials

3Temperature

If conventional refrigeration systems are used, then cooling is provided, but flexibility to adjust separation temperatures is limited

Engineering Contradiction:
Improveseparation temperatureVSAvoidtemperature adjustment flexibility
Core Design Contradiction:
TemperatureVSAdaptability or versatility

Solution Approach 1:

The mixed refrigerant compression system provides dynamic control capabilities that allow flexible adjustment of refrigeration levels and separation temperatures. By controlling compressor discharge pressure, refrigerant composition ratios, and heat exchange conditions, the system can dynamically adapt to different operating requirements and adjust separation temperatures without being constrained by fixed design parameters, thereby improving versatility.

Inventive Principle:
Principle #15Dynamics

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The MR system lowers overall power consumption, improves system reliability, and allows for more flexible and efficient separation of olefin and hydrogen, reducing capital and operating costs while maintaining product recovery efficiency.

Implementation Method 1

a main heat exchanger configured to receive and partially condense the effluent fluid stream

Methodology Applied
Scientific EffectHeat transfer: Heat Exchanger

Implementation Method 2

partially condense the effluent fluid stream so that a mixed phase effluent stream is formed

Methodology Applied
Scientific EffectCondensation: Condensation

Implementation Method 3

The main heat exchanger receives and warms at least a portion of the primary vapor stream to provide refrigeration

Methodology Applied
Scientific EffectHeating: Heating

Implementation Method 4

A mixed or single component refrigerant compression system provides refrigeration in the main heat exchanger

Methodology Applied
Scientific EffectCompression cooling: Compression

Data Source

PatentUS12092392B2Dehydrogenation separation unit with mixed refrigerant cooling
Publication Date: 2024.09.17 U S BANK TRUST CO NAT ASSOC AS THE NOTES COLLATERAL AGENT
  • US12092392B2 patent drawing
  • US12092392B2 patent drawing
  • US12092392B2 patent drawing

AI summary

A main heat exchanger receives and partially condenses an effluent fluid stream so that a mixed phase effluent stream is formed. A primary separation device receives and separates the mixed phase effluent stream into a primary vapor stream including hydrogen and a primary liquid stream including an olefinic hydrocarbon. The main heat exchanger receives and warms at least a portion of the primary vapor stream to provide refrigeration for partially condensing the effluent fluid stream. The main heat exchanger also receives, warms and partially vaporizes the primary liquid stream. A mixed refrigerant compression system also provides refrigeration in the main heat exchanger.