Multilayer Ceramic Capacitor Doping Layout for Insulation Reliability

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Solution Overview

Problem

Multilayer ceramic capacitors face challenges in achieving high reliability while maintaining miniaturization and increased capacitance, especially in harsh environments, due to the limitations of rare earth element addition.

Innovation Solution

A multilayer electronic component design that includes a body with a capacitance formation portion having internal and external portions with varying concentrations of rare earth elements, where the average number of moles of rare earth elements in the internal portion (RE1) is less than in the external portion (RE2), and both are less than in the cover portions (RE3), optimizing the distribution to enhance reliability.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Reliability

If rare earth elements are added to improve reliability, then reliability is improved, but dielectric constant decreases and TCC properties deteriorate

Engineering Contradiction:
ImprovereliabilityVSAvoiddielectric constant
Core Design Contradiction:
ReliabilityVSQuantity of substance

Solution Approach 1:

The patent applies local quality by creating a core-shell structure where rare earth elements are selectively concentrated in the grain boundary region (shell) rather than being uniformly distributed throughout the grain (core). This localized placement ensures that rare earth elements suppress oxygen vacancy movement at grain boundaries to improve reliability, while minimizing their impact on the dielectric properties of the grain interior.

Inventive Principle:
Principle #3Local quality

Solution Approach 2:

The patent segments the grain structure into core and shell regions with different compositional characteristics. The core region maintains high dielectric constant properties while the shell region contains concentrated rare earth elements for reliability enhancement. This segmentation allows independent optimization of dielectric performance and reliability.

Inventive Principle:
Principle #1Segmentation

2Reliability

If rare earth elements are added excessively to improve reliability, then reliability is improved, but manufacturing cost increases

Engineering Contradiction:
ImprovereliabilityVSAvoidmanufacturing cost
Core Design Contradiction:
ReliabilityVSLoss of substance

Solution Approach 1:

By concentrating rare earth elements specifically in the grain boundary region rather than distributing them uniformly throughout the entire ceramic body, the patent achieves effective reliability improvement with reduced overall rare earth content. This localized approach minimizes material cost while maintaining the critical function of suppressing oxygen vacancy movement at grain boundaries.

Inventive Principle:
Principle #3Local quality

Solution Approach 2:

The patent applies partial action by adding rare earth elements only where needed (at grain boundaries) rather than throughout the entire material. This partial placement achieves the necessary reliability improvement without the excessive material addition that would increase manufacturing cost.

Inventive Principle:
Principle #16Partial or excessive action

3Volume of moving object

If miniaturization is pursued to reduce component size, then component size is reduced, but achieving high reliability becomes more difficult

Engineering Contradiction:
Improvecomponent sizeVSAvoidreliability
Core Design Contradiction:
Volume of moving objectVSReliability

Solution Approach 1:

The patent changes the compositional parameter by introducing rare earth elements specifically at grain boundaries to suppress oxygen vacancy movement. This compositional modification enables miniaturized capacitors to maintain high reliability by preventing insulation resistance degradation, which is particularly critical in smaller components where defect tolerance is reduced.

Inventive Principle:
Principle #35Parameter changes

Data Source

PatentEP4564388A1Multilayer electronic capacitor
Publication Date: 2025.06.04 SAMSUNG ELECTRO MECHANICS CO LTD
  • EP4564388A1 patent drawingFigure 1
  • EP4564388A1 patent drawingFigure 2
  • EP4564388A1 patent drawingFigure 3~4

AI summary

A multilayer electronic component includes a body including a capacitance formation portion including dielectric layers and internal electrodes, and cover portions disposed on both ends of the capacitance formation portion; and external electrodes disposed on the body, wherein the capacitance formation portion includes an internal portion and an external portion, and wherein, when the average number of moles of rare earth elements based on 100 moles of titanium (Ti) included in the internal portion is defined as RE1, the average number of moles of rare earth elements based on 100 moles of titanium (Ti) included in the external portion is defined as RE2, and the average number of moles of rare earth elements based on 100 moles of titanium (Ti) included in the cover portion is defined as RE3, RE1 < RE2 and RE3 < RE2 is satisfied.