Multilayer Ceramic Capacitor External Electrode Cracking Prevention
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Solution Overview
Problem
Existing multilayer ceramic capacitors are prone to cracking due to stress caused by substrate deflection, as the amount of glass component in external electrodes is not adequately specified, leading to insufficient crack suppression.
Innovation Solution
A multilayer ceramic capacitor design with a first metal layer containing 5 wt% or more ceramic, contacting the edge faces, and a second metal layer with less than 5 wt% ceramic, contacting the side faces, is implemented to enhance adhesiveness and prevent cracking.
Engineering Contradictions & Design Principles
Engineering Contradiction Analysis
1Reliability
If a single metal layer with glass component is used for external electrodes, then the electrode structure is simple, but crack suppression is insufficient due to stress from substrate deflection
Solution Approach 1:
The external electrode is divided into two distinct metal layers: a first metal layer with 5-20 wt% glass component for adhesion to the multilayer chip, and a second metal layer with 0-5 wt% glass component for low-temperature sintering and crack suppression. This segmentation allows each layer to perform its specific function optimally, resolving the contradiction between reliability and structural simplicity.
Solution Approach 2:
Different glass component amounts are applied to different locations/functions within the external electrode structure. The first metal layer contains higher glass content (5-20 wt%) for strong bonding to the ceramic chip, while the second metal layer contains lower glass content (0-5 wt%) for flexibility and crack prevention. This local differentiation of material properties resolves the contradiction by optimizing each region for its specific purpose.
2Reliability
If the glass component amount in external electrodes is not specified, then the manufacturing process is flexible, but crack suppression is insufficient
Solution Approach 1:
The invention specifies precise parameter ranges for glass component content in each metal layer: 5-20 wt% in the first metal layer and 0-5 wt% in the second metal layer. These parameter specifications transform the manufacturing process from flexible but unreliable to controlled and reliable, resolving the contradiction between ease of manufacture and crack suppression effectiveness.
3Reliability
If external electrodes extend to side faces of the multilayer chip, then electrical connection is improved, but stress concentration increases leading to cracking
Solution Approach 1:
The external electrode uses a composite structure of two metal layers with different glass component ratios. The second metal layer with low glass content (0-5 wt%) provides a more compliant, less brittle interface with the side faces, reducing stress concentration while maintaining electrical connection. This composite material approach resolves the contradiction between electrical connectivity and stress-induced cracking.
Applied Scientific Principles
This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.
Function Achieved in This Case
The design effectively suppresses cracking by maintaining connection between external and internal electrodes, reducing peeling and stress conduction, thereby ensuring the reliability of the multilayer ceramic capacitors.
Implementation Method 1
a first metal layer whose ceramic amount is 5 wt % or more contacts with the two edge faces
Implementation Method 2
a second metal layer whose ceramic amount is less than 5 wt % contacts with the at least one of the side faces
Data Source
AI summary
A multilayer ceramic capacitor includes: a multilayer chip having a parallelepiped shape in which each of a plurality of ceramic dielectric layers and each of a plurality of internal electrode layers are alternately stacked and are alternately exposed to two edge faces of the multilayer chip; and a pair of external electrodes that are formed from the two edge faces to at least one of side faces of the multilayer chip; wherein in the external electrodes, a first metal layer whose ceramic amount is 5 wt % or more contacts with the two edge faces, and a second metal layer whose ceramic amount is less than 5 wt % contacts with the at least one of the side faces.


