Steel Sheet Composition With Mn-Enriched Austenite for Formability

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Solution Overview

Problem

Current steel sheets used in automotive manufacturing lack an optimal balance of high strength, ductility, and formability, particularly in achieving yield and tensile strengths between 1100 MPa and 1700 MPa, uniform elongation of at least 10%, total elongation of at least 13%, and a hole expansion ratio of at least 20%, while maintaining good weldability and resistance spot weldability.

Innovation Solution

A cold-rolled and heat-treated steel sheet with a specific composition and microstructure, comprising 0.10%≤C≤0.40%, 3.5%≤Mn≤8.0%, 0.5%≤Si≤2.5%, 0.003%≤Al≤3.0%, and optional elements like Cr, Ti, Nb, and V, with a microstructure of 10% to 50% retained austenite, at most 8% fresh martensite, and tempered martensite, and a quenching and partitioning process to achieve the desired mechanical properties.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Strength

If the yield strength and tensile strength are increased to reduce automotive weight, then the fuel efficiency is improved, but the ductility and formability deteriorate

Engineering Contradiction:
Improveyield strength and tensile strengthVSAvoidductility and formability
Core Design Contradiction:
StrengthVSEase of operation

Solution Approach 1:

The patent applies parameter changes by precisely controlling the chemical composition parameters (C: 0.15-0.40%, Mn: 3.5-8.0%, Si: 0.5-2.5%, Al: 0.003-3.0%, Mo: 0.001-0.5%, Cr: 0.01-2.0%, Ti: 0.010-0.080%, Nb: 0.010-0.080%, V: 0.010-0.30%, B: 0.0005-0.003%) and heat treatment parameters (quenching temperature, partitioning temperature and time) to achieve a microstructure with 10-50% retained austenite and tempered martensite, simultaneously improving strength and ductility

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent creates a composite microstructure consisting of multiple phases (retained austenite, tempered martensite, and optionally bainite and/or ferrite) within the steel sheet. This composite structure at the microstructural level provides both the strength from martensite and the ductility from retained austenite, resolving the contradiction between strength and formability

Inventive Principle:
Principle #40Composite materials

2Strength

If the strength is increased to achieve high mechanical properties, then the structural integrity is improved, but the stretch flangeability deteriorates

Engineering Contradiction:
Improvemechanical strengthVSAvoidstretch flangeability
Core Design Contradiction:
StrengthVSEase of operation

Solution Approach 1:

The patent applies local quality by creating Mn-enriched austenite regions (with Mn content higher than 1.3×Mn%) dispersed throughout the microstructure. These localized Mn-enriched zones act as sites for strain hardening and delay necking, improving stretch flangeability while maintaining overall high strength from the tempered martensite matrix

Inventive Principle:
Principle #3Local quality

3Ease of operation

If the uniform elongation and total elongation are increased to improve formability, then the ductility is improved, but the yield strength and tensile strength deteriorate

Engineering Contradiction:
Improveuniform elongation and total elongationVSAvoidyield strength and tensile strength
Core Design Contradiction:
Ease of operationVSStrength

Solution Approach 1:

The patent applies preliminary action through the partitioning heat treatment step, where carbon is pre-distributed to the retained austenite before final cooling. This preliminary carbon enrichment of the austenite phase prepares it for subsequent strain-induced transformation during deformation, enabling both high elongation and high strength through the TRIP effect

Inventive Principle:
Principle #10Preliminary action

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The solution achieves a steel sheet with yield strength between 1100 MPa and 1700 MPa, tensile strength between 1300 MPa and 2000 MPa, uniform elongation of at least 10%, total elongation of at least 13%, and a hole expansion ratio of at least 20%, while maintaining good weldability and resistance spot weldability, enhancing the combination of strength and ductility.

Implementation Method 1

the sheets are cooled from an annealing temperature, down to a quenching temperature below the Ms transformation point, and thereafter heated to a partitioning temperature and maintained at this temperature for a given time. The resulting steel sheets have a structure comprising martensite and retained austenite

Methodology Applied
Scientific EffectPhase transformation: Phase Change

Implementation Method 2

said retained austenite comprising: Mn-enriched austenite, having a Mn content higher than 1.3*Mn %, Mn % designating the Mn content of the steel sheet, and Mn-poor austenite, having an Mn content comprised between 0.5*Mn % and 1.3*Mn %

Methodology Applied
Scientific EffectSolid solution strengthening: Solid Solution Strengthening

Data Source

PatentUS11434541B2High strength and high formability steel sheet and manufacturing method
Publication Date: 2022.09.06 ARCELORMITTAL SA

AI summary

A cold-rolled and heat-treated steel sheet, having a composition including, by weight percent: 0.10%≤C≤0.40%, 3.5%≤Mn≤8.0%, 0.5%≤Si≤2.5%, 0.003%≤Al≤3.0%, with Si+Al≥0.8%, 0.001%≤Mo≤0.5%, S≤0.010%, P≤0.020%, N≤0.008%, and optionally one or more elements selected from a group comprising Cr, Ti, Nb, V and B, such that: 0.01%≤Cr≤2.0%, 0.010%≤Ti≤0.080%, 0.010%≤Nb≤0.080%, 0.010%≤V≤0.30%, 0.0005%≤B≤0.003%, the remainder of the composition being iron and unavoidable impurities resulting from the smelting. The microstructure includes, in surface fraction, between 10% and 50% of retained austenite, at most 8% of fresh martensite, and tempered martensite. The retained austenite includes Mn-enriched austenite, having a Mn content higher than 1.3*Mn %, Mn % designating the Mn content of the steel sheet, a surface fraction of the Mn-enriched austenite with respect to the whole microstructure is between 2% and 12%, and Mn-poor austenite, having an Mn content between 0.5*Mn % and 1.3*Mn %.