Heat-Treated Hot-Rolled Steel Sheet with Mn Gradient for LME Resistance

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Solution Overview

Problem

High strength steel sheets with improved weldability and resistance to liquid metal embrittlement (LME) are needed to reduce vehicle weight while maintaining safety and mechanical properties, as existing steels are brittle and prone to LME-induced cracking during welding.

Innovation Solution

A hot rolled and annealed steel sheet with a specific composition and microstructure, including 0.03-0.18% C, 6.0-11.0% Mn, 0.05-0.5% Mo, 0.0005-0.005% B, and optional elements like Al and Ti, with a microstructure of 10-60% austenite, 40-90% ferrite, and less than 5% martensite, and an inhomogeneous manganese distribution, is developed to enhance toughness and weldability.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Strength

If manganese content is increased to improve ductility and toughness, then the steel becomes too hard and brittle for further processing, but reducing manganese content compromises mechanical properties

Engineering Contradiction:
ImprovetoughnessVSAvoidprocessability
Core Design Contradiction:
StrengthVSEase of manufacture

Solution Approach 1:

The patent applies parameter changes by precisely controlling the manganese content within a specific range (6.0-11.0%) and combining it with controlled amounts of boron (0.0005-0.005%) and molybdenum (0.05-0.5%). This optimized composition parameter set achieves the desired balance between toughness and processability, allowing the steel to maintain high strength while remaining workable through standard manufacturing processes.

Inventive Principle:
Principle #35Parameter changes

2Strength

If carbon or silicon content is increased to improve strength, then LME resistance deteriorates, but reducing these elements compromises mechanical properties

Engineering Contradiction:
ImprovestrengthVSAvoidLME resistance
Core Design Contradiction:
StrengthVSObject-affected harmful factors

Solution Approach 1:

The patent implements parameter changes by strictly limiting carbon content to 0.03-0.18% and silicon content to 1.20% or less, while compensating for strength through optimized manganese (6.0-11.0%) and molybdenum (0.05-0.5%) additions. This revised parameter set maintains adequate strength levels while ensuring LME index remains at 0.36 or less, thereby achieving both mechanical performance and LME resistance.

Inventive Principle:
Principle #35Parameter changes

3Ease of manufacture

If batch annealing is used to soften the hot band for further processing, then the steel becomes easier to process, but toughness is significantly reduced

Engineering Contradiction:
ImproveprocessabilityVSAvoidtoughness
Core Design Contradiction:
Ease of manufactureVSStrength

Solution Approach 1:

The patent applies preliminary action by optimizing the chemical composition parameters before the hot rolling process. By pre-configuring the steel with controlled manganese (6.0-11.0%), boron (0.0005-0.005%), and molybdenum (0.05-0.5%) content, the steel achieves appropriate softness and ductility during hot rolling without requiring subsequent batch annealing. This preliminary compositional optimization eliminates the need for toughness-reducing annealing treatments while maintaining excellent processability.

Inventive Principle:
Principle #10Preliminary action

4Weight of moving object

If high strength steel is used to reduce vehicle weight, then fuel efficiency improves, but weldability and resistance to LME deteriorate

Engineering Contradiction:
Improvevehicle weightVSAvoidweldability
Core Design Contradiction:
Weight of moving objectVSObject-affected harmful factors

Solution Approach 1:

The patent implements comprehensive parameter changes by optimizing the complete chemical composition: carbon (0.03-0.18%), manganese (6.0-11.0%), boron (0.0005-0.005%), molybdenum (0.05-0.5%), and silicon (≤1.20%). This optimized parameter set enables the production of high strength steel with adequate weldability and LME resistance, allowing vehicle weight reduction while maintaining manufacturing quality and safety requirements.

Inventive Principle:
Principle #35Parameter changes

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The steel sheet achieves a Charpy impact energy of over 0.4 J/mm² and a low LME index of 0.36 or less, ensuring high toughness and good weldability, while maintaining resistance to LME and brittleness, thus addressing the challenges of weight reduction and safety in automotive applications.

Implementation Method 1

The presence of manganese helps to increase ductility of steels thanks to the stabilization of austenite

Methodology Applied
Scientific EffectAustenite stabilization: Phase Change

Implementation Method 2

A hot rolled and heat-treated steel sheet, made of a steel having a composition comprising... said steel sheet having a microstructure comprising...

Methodology Applied
Scientific EffectHeat treatment: Heat Treatment

Data Source

PatentUS20230287547A1Hot rolled and heat-treated steel sheet and method of manufacturing the same
Publication Date: 2023.09.14 ARCELORMITTAL SA
  • US20230287547A1 patent drawing

AI summary

A hot rolled and heat-treated steel sheet, made of a steel having a composition including, by weight percent: C: 0.03-0.18%, Mn: 6.0-11.0%, Mo: 0.05-0.5%, B: 0.0005-0.005%, S≤0.010%, P≤0.020%, N≤0.008%, and including optionally one or more of the following elements, in weight percentage: Al<3%, Si≤1.20%, Ti≤0.050%, Nb=0.050%, Cr≤0.5%, V≤0.2%, the remainder of the composition being iron and unavoidable impurities resulting from the smelting, the steel sheet having a microstructure including, in surface fraction, from 10% to 60% of retained austenite, from 40% to 90% of ferrite, less than 5% of martensite, carbides below 0.8%, and an inhomogeneous repartition of manganese, characterized by a manganese distribution with a slope above or equal to −40.