M-O Coated Nitride Nanostructures for Stable Light Emission

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Solution Overview

Problem

Existing small light emitting devices using semiconductor nanocrystals face challenges in maintaining robust electrical/magnetic properties and stability during subsequent production processes, particularly due to issues with agglomeration and surface damage of one-dimensional nanostructures like Group 13 metal nitride-based rods.

Innovation Solution

A luminescent nanostructure is developed with a semiconductor nanocrystal comprising Group 13 metal nitride and an organic compound with an M-O moiety (M being Ti, Al, Zr, or Si) bound to its surface, which enhances dispersibility, surface charge control, and electrical/magnetic properties, thereby improving process stability and maintaining intrinsic properties.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Volume of moving object

If semiconductor nanocrystals are used in small light emitting devices, then the device size is reduced, but the electrical/magnetic properties and stability deteriorate during subsequent production processes

Engineering Contradiction:
Improvedevice sizeVSAvoidelectrical/magnetic properties stability
Core Design Contradiction:
Volume of moving objectVSReliability

Solution Approach 1:

The patent uses a composite structure consisting of a semiconductor nanocrystal core (Group 13 metal nitride) coated with an organic compound shell (containing M-O moiety where M is Ti, Al, Zr, Sn, or Si). This composite structure allows the device to maintain small size while the organic shell provides protection against agglomeration and surface damage, thereby preserving electrical and magnetic properties during production processes.

Inventive Principle:
Principle #40Composite materials

Solution Approach 2:

The organic compound shell acts as an intermediary layer between the semiconductor nanocrystal and the production environment. This intermediary protects the nanocrystal surface from damage and prevents agglomeration, maintaining the intrinsic properties of the nanocrystal while enabling small device size.

Inventive Principle:
Principle #24Intermediary (Mediator)

2Length of moving object

If one-dimensional nanostructures are used, then the device size is reduced, but agglomeration and surface damage occur during subsequent processes

Engineering Contradiction:
Improvenanostructure sizeVSAvoidresistance to agglomeration and surface damage
Core Design Contradiction:
Length of moving objectVSStability of the object's composition

Solution Approach 1:

The one-dimensional nanostructure is designed as a composite with a semiconductor nanocrystal core and an organic compound shell. The organic shell prevents agglomeration and protects the surface of the nanostructure, maintaining its stability and intrinsic properties during subsequent production processes while keeping the structure small in size.

Inventive Principle:
Principle #40Composite materials

Solution Approach 2:

The organic compound shell serves as a protective intermediary that prevents direct interaction between the nanostructure surface and the production environment, thereby preventing surface damage and agglomeration while maintaining the small one-dimensional structure.

Inventive Principle:
Principle #24Intermediary (Mediator)

3Ease of operation

If the nanostructure surface is exposed, then the intrinsic properties can be accessed, but the properties are damaged during subsequent processes

Engineering Contradiction:
Improveaccess to intrinsic propertiesVSAvoidproperty maintenance during processing
Core Design Contradiction:
Ease of operationVSReliability

Solution Approach 1:

The organic compound shell acts as a protective intermediary that allows the nanostructure to maintain its intrinsic properties while being protected from damage during subsequent production processes. The shell is designed to be compatible with various processing conditions while preserving the electrical and magnetic properties of the core.

Inventive Principle:
Principle #24Intermediary (Mediator)

Solution Approach 2:

The composite structure with protected surface allows the intrinsic properties of the semiconductor nanocrystal to be accessed and utilized while the organic shell provides ongoing protection during processing, resolving the contradiction between surface accessibility and property maintenance.

Inventive Principle:
Principle #40Composite materials

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The luminescent nanostructure exhibits improved dispersion characteristics, process stability, and light emitting properties, making it suitable for use in light emitting devices and display devices.

Implementation Method 1

an organic compound having an M-O moiety (wherein M is Ti, Al, Zr, Sn, or Si) that is bound to a surface (e.g., at least a portion of the surface) of the luminescent nanostructure

Methodology Applied
Scientific EffectChemisorption: Chemisorption

Data Source

PatentUS12389721B2Luminescent nanostructure, production method thereof, and light emitting device including the same
Publication Date: 2025.08.12 SAMSUNG ELECTRONICS CO LTD
  • US12389721B2 patent drawing
  • US12389721B2 patent drawing
  • US12389721B2 patent drawing

AI summary

A luminescent nanostructure, a production method for making the luminescent nanostructure, and an electronic device including the luminescent nanostructure. The luminescent nanostructure includes a semiconductor nanocrystal including a Group 13 metal nitride. The luminescent nanostructure has an aspect ratio of greater than or equal to about 1, and an organic compound having an M-O moiety, wherein M is Ti, Al, Zr, Sn, or Si that is bound to at least a portion of the surface of the luminescent nanostructure.