Mo-Ta Electrode Bulk Acoustic Resonator for Oxidation Resistance

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Solution Overview

Problem

Bulk acoustic wave resonators face issues with electrode oxidation and reduced crystal orientation of the piezoelectric layer, leading to reliability problems and defects in connection and contact, especially when exposed to moisture.

Innovation Solution

The use of a molybdenum-tantalum alloy for the electrodes in the bulk acoustic wave resonator, with a tantalum content of 0.1 to 50 at%, which provides low specific resistance, facilitates easy etching, and enhances crystal orientation of the piezoelectric layer, thereby preventing oxidation and improving environmental reliability.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Reliability

If conventional electrodes are used, then manufacturing cost is low, but electrode oxidation occurs leading to reliability problems

Engineering Contradiction:
Improveelectrode oxidation resistanceVSAvoidmanufacturing complexity
Core Design Contradiction:
ReliabilityVSEase of manufacture

Solution Approach 1:

The patent applies composite materials by forming a multi-layer electrode structure consisting of a first electrode layer (oxidation-resistant material such as molybdenum, tungsten, or their alloys) and a second electrode layer (conductive material such as aluminum or copper). This composite structure combines the oxidation resistance of the first layer with the high conductivity and ease of manufacturing of the second layer, thereby resolving the contradiction between reliability and ease of manufacture.

Inventive Principle:
Principle #40Composite materials

2Manufacturing precision

If conventional electrodes are used, then manufacturing process is simple, but crystal orientation of piezoelectric layer is reduced

Engineering Contradiction:
Improvecrystal orientationVSAvoidetching difficulty
Core Design Contradiction:
Manufacturing precisionVSEase of manufacture

Solution Approach 1:

The patent applies parameter changes by carefully controlling the thickness parameters of the electrode layers. The first electrode layer has a thickness of 10-100 nm and the second electrode layer has a thickness of 50-200 nm. These specific thickness parameters optimize both the crystal orientation promotion (achieved by the thin first layer with specific material properties) and the etching ease (achieved by the thicker second layer that serves as a protective and etchable layer), thereby resolving the contradiction between manufacturing precision and ease of manufacture.

Inventive Principle:
Principle #35Parameter changes

3Reliability

If electrodes are protected from oxidation, then reliability improves, but sheet resistance increases

Engineering Contradiction:
Improveoxidation protectionVSAvoidsheet resistance
Core Design Contradiction:
ReliabilityVSManufacturing precision

Solution Approach 1:

The patent applies composite materials to resolve the contradiction between oxidation protection and sheet resistance. The first electrode layer (10-100 nm thick) made of oxidation-resistant materials like molybdenum or tungsten provides the necessary oxidation protection, while the second electrode layer (50-200 nm thick) made of highly conductive materials like aluminum or copper compensates for the higher resistance of the first layer. The combined structure achieves both oxidation protection and low sheet resistance, resolving the contradiction between reliability and manufacturing precision.

Inventive Principle:
Principle #40Composite materials

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The molybdenum-tantalum alloy electrodes effectively prevent oxidation, maintain low sheet resistance, and enhance crystal orientation, ensuring robust resonance characteristics and reliability of the bulk acoustic wave resonator even in high temperature and humidity environments.

Implementation Method 1

When an electric field is maintained in the piezoelectric layer by applying electrical energy to the lower and upper electrodes, the electric field causes a piezoelectric phenomenon in the piezoelectric layer, thereby causing the resonating part to be vibrated in a predetermined direction.

Methodology Applied
Scientific EffectPiezoelectric phenomenon: Piezoelectric Effect

Implementation Method 2

at least one of a plurality of electrodes of a bulk acoustic wave resonator may be formed using an alloy of molybdenum and tantalum... The molybdenum-tantalum alloy electrodes effectively prevent oxidation

Methodology Applied
Scientific EffectOxidation resistance: Oxidation

Data Source

PatentUS10637436B2Bulk acoustic wave resonator and filter including the same
Publication Date: 2020.04.28 SAMSUNG ELECTRO MECHANICS CO LTD
  • US10637436B2 patent drawing
  • US10637436B2 patent drawing
  • US10637436B2 patent drawing

AI summary

A bulk acoustic wave resonator includes a substrate, a first electrode and a second electrode disposed on the substrate, and a piezoelectric layer disposed between the first electrode and the second electrode. At least one of the first electrode and the second electrode includes an alloy of molybdenum and tantalum.