Mo-W Interconnect Filling for Low-Resistivity Semiconductor Contacts

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Solution Overview

Problem

The deposition of low resistivity metal films in semiconductor fabrication processes becomes challenging as devices shrink and more complex patterning schemes are utilized, particularly in filling features of varying sizes with metals like molybdenum and tungsten.

Innovation Solution

A method involving atomic layer deposition (ALD) of molybdenum (Mo) followed by chemical vapor deposition (CVD) or physical vapor deposition (PVD) of tungsten (W) is employed to fill features of different critical dimensions, allowing for efficient filling of both small and large features with low resistivity metals.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Manufacturing precision

If conventional deposition methods are used to fill features of varying sizes, then filling of large features is achieved, but filling precision and uniformity in small features deteriorates

Engineering Contradiction:
Improvefilling precisionVSAvoidadaptability to varying feature sizes
Core Design Contradiction:
Manufacturing precisionVSAdaptability or versatility

Solution Approach 1:

The deposition process is segmented into two distinct stages: ALD for precise filling of small features and CVD for efficient filling of large features. This segmentation allows each method to optimize its performance for specific feature size ranges, achieving both high precision and broad adaptability across varying feature dimensions.

Inventive Principle:
Principle #1Segmentation

Solution Approach 2:

Different deposition methods are applied to different spatial regions based on feature size: ALD is used for small features where conformal coverage and precision are critical, while CVD is used for large features where deposition speed and efficiency are prioritized. This local quality approach ensures optimal filling performance for each feature type.

Inventive Principle:
Principle #3Local quality

2Manufacturing precision

If ALD is used to fill all features, then filling precision is improved, but deposition time and productivity worsen

Engineering Contradiction:
Improvefilling precisionVSAvoiddeposition speed
Core Design Contradiction:
Manufacturing precisionVSProductivity

Solution Approach 1:

The feature population is segmented by size, with ALD applied only to small features requiring high precision and CVD applied to large features where speed is more important. This segmentation maintains high filling precision for critical small features while significantly improving overall productivity by using faster CVD methodology for larger features.

Inventive Principle:
Principle #1Segmentation

Solution Approach 2:

The deposition strategy applies different quality levels to different feature types: high-precision ALD for small features and high-speed CVD for large features. This local quality differentiation optimizes the balance between precision and productivity by matching deposition method characteristics to feature-specific requirements.

Inventive Principle:
Principle #3Local quality

3Productivity

If CVD is used to fill all features, then deposition speed is improved, but filling uniformity and precision in small features worsens

Engineering Contradiction:
Improvedeposition speedVSAvoidfilling uniformity
Core Design Contradiction:
ProductivityVSManufacturing precision

Solution Approach 1:

Features are segmented by size to determine appropriate deposition method: small features receive ALD treatment for uniform conformal coverage, while large features receive CVD treatment for rapid filling. This segmentation ensures that small features achieve the necessary filling uniformity while overall productivity is maintained through efficient CVD processing of large features.

Inventive Principle:
Principle #1Segmentation

Solution Approach 2:

The deposition process delivers different quality characteristics to different feature types: ALD provides superior conformal coverage and uniformity for small features, while CVD provides high-speed deposition for large features. This local quality approach resolves the contradiction by ensuring each feature type receives the appropriate deposition quality for its specific requirements.

Inventive Principle:
Principle #3Local quality

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

This approach enables the efficient and scalable deposition of low resistivity metallization stacks, effectively addressing the challenge of filling features of varying sizes with high precision and low resistance, thereby improving the performance of semiconductor devices.

Implementation Method 1

depositing a bulk layer of molybdenum (Mo) by atomic layer deposition (ALD)

Methodology Applied
Scientific EffectAtomic layer deposition:

Implementation Method 2

depositing a bulk layer of tungsten (W) on the bulk layer of Mo by chemical vapor deposition (CVD) or physical vapor deposition (PVD)

Methodology Applied
Scientific EffectChemical vapor deposition: Chemical Vapour Deposition

Implementation Method 3

depositing a bulk layer of tungsten (W) on the bulk layer of Mo by chemical vapor deposition (CVD) or physical vapor deposition (PVD)

Methodology Applied
Scientific EffectPhysical vapor deposition: Physical Vapour Deposition

Data Source

PatentUS20250183097A1Low resistivity contacts and interconnects
Publication Date: 2025.06.05 LAM RES CORP
  • US20250183097A1 patent drawing
  • US20250183097A1 patent drawing
  • US20250183097A1 patent drawing

AI summary

Metallization schemes involve atomic layer deposition (ALD) of molybdenum (Mo) and in some embodiments, ALD of Mo in a feature without a barrier layer. In some embodiments, deposition of the ALD Mo film may be followed by chemical vapor deposition (CVD) or physical vapor deposition (PVD) of a Mo film. In some embodiments, the CVD or PVD Mo film is part of the metallization stack. In other embodiments, the CVD or PVD Mo film is deposited as a sacrificial overburden layer. In some embodiments, deposition of the ALD Mo film may be followed by CVD or PVD of another metal such as tungsten (W). In some embodiments, the CVD or PVD W film is part of the metallization stack. In other embodiments, the CVD or PVD W film is deposited as a sacrificial overburden layer.