Modified Activated Carbon for Selective Smoke Filtration

Resolve Bottlenecks,
Find Innovative Solutions
Generate Solutions

Solution Overview

Problem

Conventional cigarette filter elements that incorporate activated carbon or charcoal materials are non-selective, leading to the removal of flavor constituents from mainstream cigarette smoke, resulting in poor taste or off-taste during smoking.

Innovation Solution

A modified activated carbon is created by forming a uniform, porous carbon membrane on an activated carbon substrate through pre-treatment and carbonization, which selectively removes gas phase constituents from cigarette smoke while maintaining flavor, achieved by coating the substrate with a carbon precursor and controlling pore size distribution.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Object-affected harmful factors

If activated carbon or charcoal materials are incorporated into cigarette filter elements, then gas phase constituents are removed from mainstream smoke, but flavor constituents are also removed resulting in poor taste or off-taste

Engineering Contradiction:
Improveremoval of gas phase constituentsVSAvoidadverse taste
Core Design Contradiction:
Object-affected harmful factorsVSObject-generated harmful factors

Solution Approach 1:

The patent applies local quality by creating a selective carbon coating only on the external surface of the activated carbon particles, rather than using bulk activated carbon throughout. This surface coating approach allows the material to remove gas phase constituents while preserving flavor compounds, as the coating is thin enough to permit selective permeation. The coating thickness and composition are controlled to achieve this local differentiation in functionality.

Inventive Principle:
Principle #3Local quality

Solution Approach 2:

The patent creates a composite structure by coating activated carbon particles with a carbon-rich material (such as sucrose, starch, or cellulose derivatives) that has different adsorption characteristics. This composite approach combines the gas-phase removal capability of activated carbon with the flavor-preservation properties of the coating material, resulting in a material that selectively removes harmful constituents while maintaining taste quality.

Inventive Principle:
Principle #40Composite materials

2Object-affected harmful factors

If a carbon coating is applied to activated carbon substrate, then selectivity is improved, but manufacturing complexity increases

Engineering Contradiction:
Improveselectivity of constituent removalVSAvoidmanufacturing process complexity
Core Design Contradiction:
Object-affected harmful factorsVSDevice complexity

Solution Approach 1:

The patent employs preliminary action by pre-treating the activated carbon particles with a surfactant or bonding agent before applying the carbon coating. This pre-treatment step prepares the surface to receive the coating material uniformly and ensures proper adhesion during the carbonization process. By performing this preparation in advance, the overall manufacturing process becomes more controllable and reproducible, reducing variability in the final product.

Inventive Principle:
Principle #10Preliminary action

Solution Approach 2:

The patent utilizes parameter changes by controlling the carbonization process through precise adjustment of temperature, time, and atmosphere conditions. The coating material is carbonized at specific temperature ranges (typically 200-400°C) for controlled durations to achieve the desired coating thickness and porosity. By optimizing these parameters, the process achieves high selectivity while maintaining manufacturing efficiency and reducing complexity through standardized process conditions.

Inventive Principle:
Principle #35Parameter changes

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The modified activated carbon effectively filters targeted gas phase constituents from mainstream cigarette smoke, reducing dust formation and adverse taste, while preserving the flavor of the smoke, thereby enhancing the smoking experience.

Implementation Method 1

pre-treating the activated carbon substrate to make an exposed surface of the activated carbon substrate substantially hydrophilic

Methodology Applied
Scientific EffectHydrophilic treatment: Hydrophile

Implementation Method 2

heating the coated activated carbon substrate at a temperature sufficient to carbonize the carbon precursor to form the uniform, porous carbon membrane

Methodology Applied
Scientific EffectCarbonization: Pyrolysis

Implementation Method 3

The modified activated carbon effectively filters targeted gas phase constituents from mainstream cigarette smoke

Methodology Applied
Scientific EffectAdsorption: Adsorption

Data Source

PatentUS9394179B2Method of making modified activated carbon
Publication Date: 2016.07.19 PHILIP MORRIS USA INC
  • US9394179B2 patent drawing
  • US9394179B2 patent drawing
  • US9394179B2 patent drawing

AI summary

A process for making modified activated carbon from an activated carbon substrate. The activated carbon substrate is pre-treated to make an exposed surface of the activated carbon substrate substantially hydrophilic, coated with a carbon precursor to form a coated activated carbon, and then the coated activated carbon substrate is heated to carbonize the carbon precursor to from the modified activated carbon. The modified activated carbon comprises a uniform porous carbon membrane formed on an exposed surface of the activated carbon substrate. The carbon membrane can mediate the absorption and/or adsorption kinetics of the activated carbon substrate. The modified activated carbon, which can be incorporated into one or more components of a cigarette, can selectively remove gaseous constituents from mainstream smoke during smoking.