Modified Ceramsite Packing for Biomembrane Trickling Filter

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Solution Overview

Problem

Current biomembrane trickling filter technologies face challenges with low desulfurization efficiency, long biomembrane colonization times, and poor stability due to inadequate packing characteristics, such as high cost, low mechanical strength, and insufficient microorganism attachment on conventional inert packings like rock wool-compost and zeolite.

Innovation Solution

Chemically modified ceramsite packing is developed with enhanced specific surface area, porosity, and bio-affinity through acid impregnation, ultrasonic treatment, and high-temperature calcination, facilitating better immobilization of desulfurization microorganisms and improving biomembrane colonization, allowing for counter-current gas-liquid phase operation to enhance SO2 removal efficiency.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Ease of manufacture

If conventional inert packing (rock wool-compost, zeolite) is used in biomembrane trickling filter, then the structure is simple and cost is low, but the specific surface area is insufficient, mechanical strength is low, and microorganism attachment is poor leading to long colonization time

Engineering Contradiction:
Improvepacking structure simplicityVSAvoidbiomembrane colonization speed
Core Design Contradiction:
Ease of manufactureVSProductivity

Solution Approach 1:

The patent applies parameter changes by chemically modifying the ceramsite packing surface through acid impregnation and high-temperature calcination. This changes the surface chemistry and physical properties of the packing, increasing specific surface area and creating favorable conditions for microorganism attachment, thereby accelerating biomembrane colonization while maintaining structural simplicity

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent uses composite materials by combining ceramsite base material with metal salts (such as iron salts) through impregnation and calcination processes. This creates a composite packing material with enhanced surface area, improved mechanical strength, and increased bio-affinity, resolving the contradiction between simplicity and colonization speed

Inventive Principle:
Principle #40Composite materials

2Ease of manufacture

If conventional inert packing is used, then manufacturing cost is low, but mechanical strength and abrasion resistance are insufficient

Engineering Contradiction:
Improvepacking costVSAvoidmechanical strength and abrasion resistance
Core Design Contradiction:
Ease of manufactureVSStrength

Solution Approach 1:

The patent applies parameter changes through high-temperature calcination (500-800°C) of the impregnated ceramsite packing. This thermal treatment strengthens the packing structure, improves mechanical strength and abrasion resistance, while the acid impregnation process enhances surface properties without significantly increasing cost

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent utilizes porous materials by maintaining and optimizing the porous structure of ceramsite packing. The porous characteristics provide high specific surface area and good permeability, while the chemical modification enhances the mechanical strength of the porous structure, resolving the contradiction between cost and strength

Inventive Principle:
Principle #31Porous materials

3Ease of operation

If conventional packing is used, then the system is simple to operate, but desulfurization efficiency is low due to insufficient microorganism attachment

Engineering Contradiction:
Improvesystem operation simplicityVSAvoiddesulfurization efficiency
Core Design Contradiction:
Ease of operationVSProductivity

Solution Approach 1:

The patent applies parameter changes by modifying the packing surface chemistry through acid impregnation and calcination, creating a surface with enhanced bio-affinity. This increases microorganism attachment and desulfurization efficiency while maintaining simple operation characteristics

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent uses the successful bio-trickling filtration process model and applies it to modified ceramsite packing. The process remains simple to operate but the modified packing enhances microorganism attachment and desulfurization efficiency, resolving the contradiction between operational simplicity and treatment efficiency

Inventive Principle:
Principle #26Copying

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The modified ceramsite packing increases desulfurization efficiency, reduces biomembrane colonization time, and provides a stable, compact biomembrane, achieving high removal rates of sulfur dioxide from flue gas with reduced operational costs and environmental impact.

Implementation Method 1

According to the adsorption theory, the packing should be selected with large specific surface area, good bio-affinity... The modified ceramsite packing increases desulfurization efficiency... facilitating better immobilization of desulfurization microorganisms

Methodology Applied
Scientific EffectAdsorption: Adsorption

Implementation Method 2

Chemically modified ceramsite packing is developed with enhanced specific surface area, porosity, and bio-affinity through acid impregnation, ultrasonic treatment, and high-temperature calcination

Methodology Applied
Scientific EffectUltrasonic vibration: Ultrasonic Vibration

Implementation Method 3

Chemically modified ceramsite packing is developed with enhanced specific surface area, porosity, and bio-affinity through acid impregnation, ultrasonic treatment, and high-temperature calcination

Methodology Applied
Scientific EffectThermal treatment: Heat Treatment

Data Source

PatentUS9833740B2Modified ceramsite packing useful for biomembrane trickling filter and a process for removing SO2 from flue gas using the trickling filter
Publication Date: 2017.12.05 CHINA PETROLEUM & CHEMICAL CORP
  • US9833740B2 patent drawing
  • US9833740B2 patent drawing

AI summary

A process of removing SO2 from a flue gas with a trickling filter using modified ceramsite packing is described. The biological flue gas desulfurization process includes: feeding the flue gas containing sulfur dioxide through the column bottom into the biomembrane trickling filter at certain temperature, contacting with the modified ceramsite biomembrane packing and purifying, which purified flue gas is discharged via the column top; and spraying the nutrient fluid rich in high concentration of the desulfurization strain through the top to the modified ceramsite biomembrane packing, thereby the sulfur-bearing pollution source in the flue gas is degraded, so as to discharge a purified flue gas satisfying the environmental requirements.