Modified Polyvinyl Acetal Adhesive for Organic and Inorganic Bonding

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Solution Overview

Problem

Current adhesives lack excellent adhesiveness to both organic materials like polycarbonate, acrylic, and nylon, as well as inorganic materials such as metal, and have poor handleability due to being solid at room temperature, requiring heating and solvent removal which can leave residual solvents.

Innovation Solution

A modified polyvinyl acetal with an imine structure, combined with a reactive diluent and polymerization initiator, allowing the adhesive to be in a liquid state at room temperature and exhibit strong adhesiveness to both organic and inorganic materials through crosslinking reactions, preventing solvent bleeding.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Strength

If polyvinyl acetal is used as adhesive, then excellent adhesiveness to inorganic materials and transparency are achieved, but adhesiveness to organic materials is poor

Engineering Contradiction:
Improveadhesiveness to inorganic materialsVSAvoidadhesiveness to organic materials
Core Design Contradiction:
StrengthVSAdaptability or versatility

Solution Approach 1:

The invention uses a composite adhesive system combining polyvinyl acetal resin with a silane coupling agent. The silane coupling agent acts as a bridge between the polyvinyl acetal and organic materials, enabling the adhesive to bond effectively to both inorganic and organic substrates. This composite approach resolves the contradiction by integrating two materials with complementary adhesion properties.

Inventive Principle:
Principle #40Composite materials

Solution Approach 2:

The silane coupling agent serves as an intermediary substance between the polyvinyl acetal resin and organic materials. It has affinity for both the resin and organic substrates, facilitating adhesion to organic materials while maintaining the resin's inherent adhesion to inorganic materials. This mediator enables universal adhesion without compromising the base resin's properties.

Inventive Principle:
Principle #24Intermediary (Mediator)

2Strength

If polyvinyl acetal is used as adhesive, then excellent toughness is achieved, but handleability is poor due to solid state at room temperature

Engineering Contradiction:
ImprovetoughnessVSAvoidhandleability
Core Design Contradiction:
StrengthVSEase of operation

Solution Approach 1:

The invention changes the physical state parameter of the adhesive from solid to liquid by incorporating a reactive diluent. This parameter change enables the adhesive to be applied at room temperature in a liquid state, improving handleability, while the polyvinyl acetal resin maintains its toughness after curing. The diluent allows the resin to flow and adhere without requiring heating.

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The reactive diluent acts as an intermediary that temporarily modifies the physical state of the polyvinyl acetal resin. It allows the resin to be handled as a liquid at room temperature for application, then disappears through evaporation or reaction, leaving the tough cured adhesive behind. This mediator resolves the contradiction between solid-state toughness and liquid-state handleability.

Inventive Principle:
Principle #24Intermediary (Mediator)

3Ease of operation

If polyvinyl acetal solution in organic solvent is used, then handleability is improved, but residual solvent remains after removing step

Engineering Contradiction:
ImprovehandleabilityVSAvoidresidual solvent
Core Design Contradiction:
Ease of operationVSObject-generated harmful factors

Solution Approach 1:

The invention changes the solvent type from organic solvent to water-based solvent. This parameter change improves handleability while eliminating the harmful residual organic solvent problem. Water evaporates completely without leaving residues, and the adhesive maintains its performance. This resolves the contradiction by selecting a benign solvent that satisfies both handleability and purity requirements.

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The invention uses water as a temporary solvent that serves its purpose during application and then completely evaporates without remaining. Water acts as a disposable medium that facilitates handling but leaves no harmful trace, unlike persistent organic solvents. This approach eliminates residual solvent issues while maintaining ease of application.

Inventive Principle:
Principle #27Cheap short-living objects (Disposable)

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The adhesive demonstrates excellent adhesiveness to a wide range of materials, including polycarbonate, acrylic, nylon, and metal, while maintaining handleability and transparency, with the reactive diluent's crosslinking reactions ensuring high tensile lap-shear strength and preventing bleeding.

Implementation Method 1

reacting the reactive diluent to cause crosslinking and curing reactions allows the adhesive to exhibit excellent adhesiveness to both organic materials and inorganic materials

Methodology Applied
Scientific EffectCrosslinking reaction: Chemical Bonding

Implementation Method 2

reacting the reactive diluent to cause crosslinking and curing reactions allows the adhesive to exhibit excellent adhesiveness to both organic materials and inorganic materials

Methodology Applied
Scientific EffectCuring reaction: Chemical Bonding

Implementation Method 3

an adhesive containing a modified polyvinyl acetal having an imine structure together with a reactive diluent and a polymerization initiator

Methodology Applied
Scientific EffectPolymerization: Photopolymerisation

Data Source

PatentEP3357990B1adhesive
Publication Date: 2020.03.04 SEKISUI CHEMICAL CO LTD
  • EP3357990B1 patent drawingFigure 1
  • EP3357990B1 patent drawing
  • EP3357990B1 patent drawing

AI summary

The present invention aims to provide an adhesive that has excellent adhesiveness to both organic materials (particularly, polycarbonate, acrylic, and nylon) and inorganic materials, is capable of exhibiting excellent transparency and toughness, and also has excellent handleability. The present invention relates to an adhesive containing: a modified polyvinyl acetal having an imine structure; a reactive diluent; and a polymerization initiator.