Modified polyvinyl butyral material, and preparation and applications thereof

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Solution Overview

Problem

Conventional polyvinyl butyral (PVB) materials used in safety glass and windscreen production have high water absorbency and viscosity, making them difficult to recycle and process, and the calendaring process is costly, energy-intensive, and polluting.

Innovation Solution

A modified PVB material is developed by combining PVB with fillers, anti-hydrolysis agents, plasticizers, zinc stearate, calcium stearate, and a polymeric dispersant, which is processed using a casting method that reduces water absorption, anti-sticking issues, and equipment costs while allowing for the reuse of leftover materials.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Reliability

If conventional PVB material is used in safety glass production, then the material provides necessary adhesive and protective properties, but the material exhibits high water absorbency and high viscosity making it difficult to recycle and process

Engineering Contradiction:
Improveadhesive propertyVSAvoidprocessability
Core Design Contradiction:
ReliabilityVSEase of manufacture

Solution Approach 1:

The patent modifies the PVB material by changing its chemical composition parameters - specifically reducing the vinyl alcohol content from conventional levels to 5-15 mol% and adding specific additives (wax emulsion, silicone oil, titanium dioxide). These parameter changes result in modified PVB that maintains adhesive properties while significantly reducing water absorbency and viscosity, enabling easier processing and recycling.

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent creates a composite material system by combining modified PVB with multiple functional additives including wax emulsion (for water resistance), silicone oil (for viscosity control), titanium dioxide (for UV protection and opacity), and various plasticizers. This composite approach allows the material to simultaneously achieve low water absorbency, reduced viscosity, and maintained adhesive properties.

Inventive Principle:
Principle #40Composite materials

2Ease of manufacture

If PVB leftover materials are discarded directly, then the production process is simple, but the environment is impacted and PVB materials are wasted

Engineering Contradiction:
Improveprocessing simplicityVSAvoidenvironmental impact
Core Design Contradiction:
Ease of manufactureVSObject-affected harmful factors

Solution Approach 1:

The patent implements a recovery system for PVB leftover materials by modifying their composition to enable recycling. The modified PVB with reduced water absorbency and viscosity can be reprocessed into new products such as plastic pellets, flooring materials, or composite boards, transforming waste into valuable resources and reducing environmental impact while maintaining production efficiency.

Inventive Principle:
Principle #34Discarding and recovering

3Ease of manufacture

If calendaring process is used to prepare PVB layers, then the PVB material can be processed into films, but multiple independent equipment are needed resulting in higher equipment cost, larger space, more manpower and greater energy consumption

Engineering Contradiction:
Improvefilm production capabilityVSAvoidequipment requirements
Core Design Contradiction:
Ease of manufactureVSDevice complexity

Solution Approach 1:

The patent merges multiple separate calendaring operations into a single extrusion-based film formation process. The modified PVB composition allows the material to be extruded directly into films with controlled thickness and properties, eliminating the need for multiple independent calendaring machines and reducing equipment complexity, factory space, and energy consumption while maintaining film production quality.

Inventive Principle:
Principle #5Merging (Combining)

4Ease of manufacture

If calendaring machine is used as an open system, then the PVB material can be processed, but the plasticizer is heated and evaporated causing unnecessary air pollution

Engineering Contradiction:
Improvematerial processingVSAvoidair pollution
Core Design Contradiction:
Ease of manufactureVSObject-generated harmful factors

Solution Approach 1:

The patent transitions from open-system calendaring to a closed extrusion system where the modified PVB is processed. The closed system prevents plasticizer evaporation into the atmosphere, and the modified composition with optimized plasticizer content and added stabilizers further reduces emissions, eliminating air pollution while maintaining effective material processing.

Inventive Principle:
Principle #39Inert atmosphere (Inert environment)

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The modified PVB material exhibits improved water resistance and anti-sticking properties, enabling more efficient production with reduced costs and environmental impact, and allows for the recycling of previously wasted materials.

Implementation Method 1

a modified polyvinyl butyral material, comprising a polyvinyl butyral composite material, a filler, an anti-hydrolysis agent

Methodology Applied
Scientific EffectAnti-hydrolysis: Hydrolysis

Implementation Method 2

the polyvinyl butyral composite material is obtained by plasticizing a composition comprising polyvinyl butyral and a second plasticizer

Methodology Applied
Scientific EffectPlasticization:

Implementation Method 3

a polymeric dispersant

Methodology Applied
Scientific EffectDispersion: Dispersion (of waves)

Data Source

PatentUS11732122B2Modified polyvinyl butyral material, and preparation and applications thereof
Publication Date: 2023.08.22 CHANG AN HSIUNG
  • US11732122B2 patent drawing
  • US11732122B2 patent drawing
  • US11732122B2 patent drawing

AI summary

The present invention relates to a modified polyvinyl butyral material, comprising a polyvinyl butyral composite material, a filler, an anti-hydrolysis agent, a first plasticizer, zinc stearate, calcium stearate, and a polymeric dispersant; wherein the polyvinyl butyral composite material is obtained by plasticizing a composition comprising polyvinyl butyral and a second plasticizer. The present invention also relates to a preparation method of the modified polyvinyl butyral material, a modified polyvinyl butyral product comprising at least one modified polyvinyl butyral layer prepared from a material comprising the modified polyvinyl butyral material, and the preparation method of the modified polyvinyl butyral product.