Modified Resin Injection for Paraffin and Asphaltene Control

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Solution Overview

Problem

The precipitation of paraffins and asphaltenes during crude oil extraction leads to well plugging and reduced productivity, necessitating frequent maintenance and increased operational costs due to the adsorption of these components on rock formations and pipes.

Innovation Solution

A process involving the forced injection of a modified alkylphenol-aldehyde resin, obtained through a Mannich reaction, into rock formations to adsorb and subsequently desorb the resin, thereby inhibiting paraffin and asphaltene precipitation, allowing for efficient crude oil extraction with reduced resin usage and treatment frequency.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Reliability

If resin is continuously injected into the rock formation to prevent paraffin and asphaltene precipitation, then well productivity is maintained, but operational costs and treatment frequency increase

Engineering Contradiction:
Improvewell productivityVSAvoidoperational costs
Core Design Contradiction:
ReliabilityVSLoss of energy

Solution Approach 1:

The resin is injected in advance into the rock formation before paraffin and asphaltene precipitation occurs, allowing the resin to adsorb onto the rock surfaces and create a protective layer that prevents subsequent precipitation. This preliminary action eliminates the need for continuous injection and frequent maintenance interventions.

Inventive Principle:
Principle #10Preliminary action

Solution Approach 2:

The rock formation acts as a porous medium that adsorbs and retains the resin within its pore structure. The resin becomes trapped in the rock pores through adsorption, creating a long-lasting protective effect that reduces the frequency of reinjection needed to maintain well productivity.

Inventive Principle:
Principle #31Porous materials

2Reliability

If high concentrations of resin are injected to ensure sufficient coverage, then precipitation prevention is improved, but resin consumption and treatment complexity increase

Engineering Contradiction:
Improveprecipitation preventionVSAvoidresin consumption
Core Design Contradiction:
ReliabilityVSQuantity of substance

Solution Approach 1:

The resin is selectively adsorbed onto the rock surfaces and retained within the pore structures where precipitation problems occur. This localized concentration of resin at critical interfaces (rock-oil contact zones) provides effective precipitation prevention while minimizing overall resin consumption throughout the entire well system.

Inventive Principle:
Principle #3Local quality

Solution Approach 2:

The rock formation itself serves as the delivery and retention mechanism for the resin. The natural adsorption capacity of the rock surfaces and pore structures automatically concentrates and holds the resin in place, eliminating the need for additional injection infrastructure or complex delivery systems.

Inventive Principle:
Principle #25Self-service

3Ease of repair

If frequent maintenance operations are performed to clean plugged wells, then well functionality is restored, but productivity loss and operational burden increase

Engineering Contradiction:
Improvewell maintenanceVSAvoidwell productivity
Core Design Contradiction:
Ease of repairVSProductivity

Solution Approach 1:

The resin is injected in advance to prevent paraffin and asphaltene precipitation before it occurs. By creating a protective adsorbed layer on the rock surfaces, the resin preemptively blocks the mechanism that would lead to well plugging, thereby preventing the need for subsequent maintenance operations and preserving continuous productivity.

Inventive Principle:
Principle #9Preliminary anti-action

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The process effectively maintains paraffins in a dispersed state, preventing agglomeration and deposition, reducing maintenance needs and operational costs by ensuring resin concentration in the extracted crude oil for extended periods, thus enhancing well productivity and reducing maintenance frequency.

Implementation Method 1

the adsorption of the resin in the rock formation of the well

Methodology Applied
Scientific EffectAdsorption: Adsorption

Implementation Method 2

the desorption of the resin out of the rock formation

Methodology Applied
Scientific EffectDesorption: Desorption

Implementation Method 3

maintains paraffins in a dispersed state, preventing agglomeration and deposition

Methodology Applied
Scientific EffectDispersion: Dispersion (of waves)

Data Source

PatentUS12384957B2Process for extracting a crude oil with injection of resin
Publication Date: 2025.08.12 TOTALENERGIES ONETECH

AI summary

A process for extracting a crude oil from a rock formation containing crude oil comprises the following steps:(i) a first step of forced injection of a modified alkylphenol-aldehyde resin into the rock formation containing a crude oil, and(ii) a second step of extracting the crude oil from the rock formation.The modified alkyl phenol-aldehyde resin may be obtained by Mannich reaction of an alkylphenol-aldehyde condensation resin, with at least one C1-C8 aldehyde and/or at least one C1-C8 ketone, and at least one hydrocarbon compound having at least one alkyl polyamine group having between 1 and 30 carbon atoms. The alkylphenol-aldehyde condensation resin may be obtained by condensation of at least one alkylphenol substituted by at least one linear or branched alkyl group having 1 to 30 carbon atoms, with at least one compound selected from C1-C8 aldehydes and/or C1-C8 ketones.