Modular Conductivity Cell for Membrane Analysis

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Solution Overview

Problem

Current devices for measuring conductivity in solid electrolytes are limited in their ability to simulate real operating conditions, particularly in fuel cells and batteries, as they often measure conductivity on the surface rather than through the membrane, leading to ohmic losses and inaccurate results.

Innovation Solution

A modular conductivity cell with two compartments separated by a membrane, capable of operating at varying temperatures and pressures, using blocking or selective electrodes to measure ionic, electronic, and mixed conductivity, allowing gases or liquids to flow through the membrane, and equipped with a heating system for temperature control.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Ease of operation

If conductivity is measured on the surface of the membrane, then measurement simplicity is improved, but measurement precision deteriorates due to ohmic losses

Engineering Contradiction:
Improvemeasurement simplicityVSAvoidconductivity measurement accuracy
Core Design Contradiction:
Ease of operationVSMeasurement precision

Solution Approach 1:

The invention transitions from surface measurement (2D) to through-membrane measurement (3D) by positioning electrodes on opposite sides of the membrane, forcing current to traverse the entire membrane thickness and eliminating surface-only measurement limitations

Inventive Principle:
Principle #17Another dimension (Dimensionality change)

2Adaptability or versatility

If a modular cell design with gas/liquid flow is implemented, then simulation of real operating conditions is improved, but device complexity increases

Engineering Contradiction:
Improvesimulation capabilityVSAvoidcell structure complexity
Core Design Contradiction:
Adaptability or versatilityVSDevice complexity

Solution Approach 1:

The cell body serves multiple functions simultaneously: it contains the membrane, provides gas/liquid flow paths, supports electrodes, enables temperature control, and facilitates conductivity measurement, eliminating the need for separate components for each function

Inventive Principle:
Principle #6Universality (Multi-functionality)

Solution Approach 2:

The invention combines the measurement cell, flow channels, temperature control system, and electrode supports into a single integrated modular structure, reducing the number of separate components while maintaining all necessary functionalities

Inventive Principle:
Principle #5Merging (Combining)

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

This design enables accurate measurement of conductivity through the membrane, reducing ohmic losses and providing more realistic data on charge carrier behavior, suitable for simulating conditions in fuel cells, batteries, and electrochemical sensors.

Implementation Method 1

a heating system formed by electric resistance

Methodology Applied
Scientific EffectJoule heating: Joule Heating

Implementation Method 2

an opening for the temperature control thermocouple

Methodology Applied
Scientific EffectSeebeck effect: Seebeck Effect

Implementation Method 3

measure ionic, electronic and mixed conductivity in polymeric and ceramic membranes

Methodology Applied
Scientific EffectIonic conduction: Conduction (electrical)

Implementation Method 4

measure ionic, electronic and mixed conductivity in polymeric and ceramic membranes

Methodology Applied
Scientific EffectElectronic conduction: Conduction (electrical)

Data Source

PatentUS9074982B2Modular device to measure ionic, electronic and mixed conductivity in polymeric and ceramic membranes
Publication Date: 2015.07.07 INST MEXICANO DEL GASOLINEEO
  • US9074982B2 patent drawing
  • US9074982B2 patent drawing
  • US9074982B2 patent drawing

AI summary

This invention consists in a device and a method to determine the ionic, electronic and mixed (electronic-ionic) conductivity in polymer, ceramic and composite (polymeric-ceramic) membranes. The invention device may work from room temperature to 300° C. and the method includes the collection and analysis of electrochemical impedance spectra during cell operation.