Modular Electrolytic Cells for Solid Feedstock Reduction

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Solution Overview

Problem

Existing electrolytic reduction processes for solid feedstock face challenges in scaling up production to an industrial level due to energy inefficiencies and contamination issues, as the entire electrolytic cell, including the molten salt, needs to be heated and cooled, leading to energy loss and product contamination.

Innovation Solution

The method involves using a plurality of electrolytic cells with a circulation system for molten salt, allowing for different salt compositions and temperatures to be used at various stages of the reduction process, and continuous replacement of cells to maintain a consistent reduction reaction, while purifying the salt to prevent contamination and maintain optimal conditions.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Productivity

If the entire electrolytic cell including molten salt is heated for each reduction process, then the reduction reaction can proceed, but energy consumption increases and production efficiency decreases

Engineering Contradiction:
Improveproduction efficiencyVSAvoidenergy consumption
Core Design Contradiction:
ProductivityVSUse of energy by moving object

Solution Approach 1:

The system divides the electrolytic cell into separable components: a reusable outer cell structure and replaceable inner liners containing feedstock. This allows the cell to be segmented for rapid replacement without heating the entire structure, reducing energy consumption and enabling continuous production across multiple cells.

Inventive Principle:
Principle #1Segmentation

Solution Approach 2:

The molten salt is prepared and heated in advance in the reusable cell structure before the feedstock liner is inserted. This preliminary heating eliminates the need to reheat the entire cell for each batch, as the thermal energy is already in place to maintain the reduction reaction.

Inventive Principle:
Principle #10Preliminary action

2Productivity

If the entire electrolytic cell is heated to molten salt temperature, then the reduction process can occur, but the time required for heating increases production cycle time

Engineering Contradiction:
Improveproduction rateVSAvoidheating time
Core Design Contradiction:
ProductivityVSLoss of time

Solution Approach 1:

The cell is segmented into a permanent heated structure and disposable feedstock containers. The heated structure remains at operating temperature continuously, while only small feedstock liners are replaced, eliminating the time required to heat the entire cell for each batch.

Inventive Principle:
Principle #1Segmentation

Solution Approach 2:

The reusable cell structure maintains continuous heating and molten salt circulation, ensuring the reduction environment is always ready. Multiple cells can operate in parallel with continuous feedstock replacement, eliminating idle heating time and maximizing production rate.

Inventive Principle:
Principle #20Continuity of useful action

3Use of energy by moving object

If the same molten salt is reused across multiple reduction cycles, then energy is saved, but the salt becomes contaminated and product purity decreases

Engineering Contradiction:
Improveenergy efficiencyVSAvoidproduct purity
Core Design Contradiction:
Use of energy by moving objectVSManufacturing precision

Solution Approach 1:

The system separates the reusable molten salt system from the disposable feedstock-containing liners. Fresh salt can be added with each new liner while the bulk salt reservoir is maintained and circulated, ensuring product purity without wasting the thermal energy invested in the salt.

Inventive Principle:
Principle #1Segmentation

Solution Approach 2:

The circulation system continuously filters and maintains the molten salt, removing impurities that accumulate during reduction. This self-purification allows the salt to be reused indefinitely while maintaining product purity specifications.

Inventive Principle:
Principle #25Self-service

4Device complexity

If a single large electrolytic cell is used, then equipment complexity is reduced, but scaling up production becomes difficult

Engineering Contradiction:
Improvesystem simplicityVSAvoidscalability
Core Design Contradiction:
Device complexityVSProductivity

Solution Approach 1:

The system uses multiple standardized modular cells rather than one large cell. Each module is identical and can be independently operated, making it easy to scale production by simply adding more modules to the array without increasing individual cell complexity.

Inventive Principle:
Principle #1Segmentation

Solution Approach 2:

The reusable cell structure and circulation system serve multiple functions: heating, salt circulation, filtration, and support for multiple feedstock liners. This universal design allows the same infrastructure to handle large production volumes through parallel processing rather than requiring increasingly complex single-cell designs.

Inventive Principle:
Principle #6Universality (Multi-functionality)

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

This approach enables efficient and continuous reduction of solid feedstock to metal, reducing energy consumption and contamination risks, allowing for the production of high-purity metals on an industrial scale by maintaining salt composition and temperature, and preventing impurities from affecting the reduction process.

Implementation Method 1

applying a potential across the electrodes of each of the cells. The applied potential is sufficient to cause reduction of the feedstock within the cell

Methodology Applied
Scientific EffectElectrochemical reduction: Electrolysis

Implementation Method 2

circulating molten salt from a molten salt reservoir such that salt flows through the electrolytic cells

Methodology Applied
Scientific EffectFluid circulation: Convection

Implementation Method 3

The salt is heated to a molten state within the cell

Methodology Applied
Scientific EffectThermal heating: Heating

Data Source

PatentEP2430217B1Apparatus and method for reduction of a solid feedstock
Publication Date: 2019.05.01 METALYSIS
  • EP2430217B1 patent drawingFigure 1
  • EP2430217B1 patent drawingFigure 2
  • EP2430217B1 patent drawingFigure 3

AI summary

In a method for reduction of a solid feedstock, such as a solid metal compound, in an electrolytic apparatus a portion of the feedstock is arranged in each of two or more electrolytic cells (50, 60, 70, 80). A molten salt is provided as an electrolyte in each cell. The molten salt is circulated from a molten salt reservoir (10) such that salt flows through each of the cells. Feedstock is reduced in each cell by applying a potential across electrodes in each cell, the potential being sufficient to cause reduction of the feedstock. The invention also provides an apparatus for implementing the method.