Modular Electrolyzer with Integrated Pressure Control and Recombiners

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Solution Overview

Problem

Existing hydrogen generation technologies via water electrolysis face challenges in producing high-pressure hydrogen with high purity, as they often require cumbersome and unreliable pressure control systems and external recombiners that increase costs and risk safety issues, while also being inflexible in membrane replacement and production rate adjustments.

Innovation Solution

A modular electrolyzer unit with integrated catalytic recombiners, custom-designed bipolar plates, and titan frits with nanoparticulate catalysts, along with pressure chamber plates for adaptive pressure control, allowing for high-pressure and high-purity hydrogen production with flexible membrane replacement and adjustable production rates.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Stress or pressure

If pressure-containment vessels and external pressure control systems are used to produce high-pressure hydrogen, then hydrogen pressure can be maintained at high levels, but the device complexity and reliability deteriorate due to cumbersome and unreliable pressure control systems

Engineering Contradiction:
Improvehydrogen pressureVSAvoidpressure control system complexity
Core Design Contradiction:
Stress or pressureVSDevice complexity

Solution Approach 1:

The patent integrates pressure control functionality directly into the electrolyzer cell structure by incorporating spring-loaded diaphragms and overflow valves within the cell assembly itself, merging the pressure regulation function with the electrolysis function. This eliminates the need for separate external pressure control systems and containment vessels, reducing overall device complexity while maintaining high-pressure hydrogen production capability.

Inventive Principle:
Principle #5Merging (Combining)

Solution Approach 2:

The electrolyzer cell employs self-regulating pressure control mechanisms where spring-loaded diaphragms automatically maintain constant differential pressure across the membrane, and overflow valves autonomously release excess pressure when thresholds are exceeded. These self-service pressure control features operate without external monitoring or intervention, improving reliability while simplifying the system architecture.

Inventive Principle:
Principle #25Self-service

2Manufacturing precision

If external recombiners are used to produce high-purity hydrogen, then hydrogen purity can be improved, but the device complexity and safety deteriorate due to increased system complexity and safety risks from external hydrogen handling

Engineering Contradiction:
Improvehydrogen purityVSAvoidsystem complexity
Core Design Contradiction:
Manufacturing precisionVSDevice complexity

Solution Approach 1:

The patent integrates catalytic recombiner elements directly within the electrolyzer cell structure, merging the gas purification function with the electrolysis function. The recombiners are positioned to treat gases at their source, eliminating the need for separate external recombiner units and the associated hydrogen transport infrastructure, thereby reducing system complexity and safety risks.

Inventive Principle:
Principle #5Merging (Combining)

Solution Approach 2:

The patent employs catalytic materials as intermediary substances that facilitate the recombination of hydrogen and oxygen gases within the cell. These catalysts act as mediators that enable high-purity hydrogen production through in-situ recombination reactions, avoiding the need for complex external purification systems while maintaining hydrogen purity through controlled catalytic processes.

Inventive Principle:
Principle #24Intermediary (Mediator)

3Stress or pressure

If thick and massive endplates or complex pressure control systems are used to handle high pressure, then pressure containment is improved, but the weight and device complexity worsen

Engineering Contradiction:
Improvepressure containmentVSAvoidendplate weight
Core Design Contradiction:
Stress or pressureVSWeight of moving object

Solution Approach 1:

The patent employs spring-loaded diaphragms that dynamically adjust to maintain constant differential pressure across the membrane regardless of absolute pressure changes. This parameter-based pressure regulation approach allows the use of lighter endplate structures compared to static thick-walled pressure vessels, as the active pressure compensation mechanism compensates for the reduced structural mass.

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent utilizes thin-film membrane structures combined with spring-loaded diaphragms to achieve pressure containment and regulation. These flexible thin-film elements replace massive rigid endplates, significantly reducing weight while maintaining effective pressure containment through the elastic properties of the spring-diaphragm assembly that compensates for pressure differential forces.

Inventive Principle:
Principle #30Flexible shells and thin films

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The modular electrolyzer unit achieves reliable high-pressure and high-purity hydrogen production, eliminating the need for external pressure control and recombiners, enhancing flexibility and safety, and maintaining stable cell resistance across a wide range of pressures.

Implementation Method 1

Water elecrolysis by means of polymer-electrolyte membranes (PEM) arranged between cathode and anode plates is a promising hydrogen generation technique

Methodology Applied
Scientific EffectElectrolysis: Electrolysis

Implementation Method 2

The catalytic recombiners integrated into each electrolyzer cell allow high gas purity over a wide range of pressures

Methodology Applied
Scientific EffectCatalysis: Catalysis

Data Source

PatentUS11718921B2Modular electrolyzer unit to generate gaseous hydrogen at high pressure and with high purity
Publication Date: 2023.08.08 THALESNANO ZRT
  • US11718921B2 patent drawing
  • US11718921B2 patent drawing
  • US11718921B2 patent drawing

AI summary

The present invention relates to the field of generating gaseous hydrogen at high pressures and with high purity via electrolysis of water by means of an electrolyzer unit (100) with a novel structure.