Modular Endogas Generator with Parallel Catalytic Tubes

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Solution Overview

Problem

Existing endogas generators lack modularity in reducing flow rates without compromising the optimal composition of endogas, leading to inefficiencies and potential catalyst damage, and are unable to produce enriched atmospheres with higher CO and H2 percentages required for certain metal treatments.

Innovation Solution

A modular endogas generator with a catalytic reactor consisting of multiple parallel tubes using noble metal oxide catalysts, allowing independent regulation of each tube's feed and operation, enabling flexible flow rate adjustment and catalyst regeneration during operation, while maintaining optimal endogas composition.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Productivity

If the flow rate of endogas is reduced below nominal capacity in conventional generators, then productivity decreases, but the composition of endogas deteriorates from optimal levels

Engineering Contradiction:
Improveflow rate of endogasVSAvoidcomposition of endogas
Core Design Contradiction:
ProductivityVSStability of the object's composition

Solution Approach 1:

The catalytic reactor is divided into multiple independent catalytic tubes (at least three) arranged in parallel, each capable of independent operation. This segmentation allows selective activation/deactivation of individual tubes to maintain optimal composition at various flow rates, resolving the contradiction between productivity reduction and composition stability.

Inventive Principle:
Principle #1Segmentation

2Ease of manufacture

If nickel-based catalysts are used to produce endogas, then manufacturing cost is reduced, but the spatial speed and selectivity towards CO and H2 are insufficient

Engineering Contradiction:
Improvecatalyst manufacturing costVSAvoidspatial speed of catalyst
Core Design Contradiction:
Ease of manufactureVSProductivity

Solution Approach 1:

The patent changes the catalyst material parameter from nickel-based to noble metal-based (platinum, palladium, rhodium, or their oxides). This parameter change dramatically increases spatial speed from less than 4000 h-1 to greater than 4000 h-1, and improves selectivity towards CO and H2 production, justifying the higher manufacturing cost through enhanced performance.

Inventive Principle:
Principle #35Parameter changes

3Productivity

If the diameter of catalytic retorts is increased to provide sufficient catalyst volume, then productivity increases, but device complexity and space requirements increase

Engineering Contradiction:
Improvecatalyst volumeVSAvoidreactor structure
Core Design Contradiction:
ProductivityVSDevice complexity

Solution Approach 1:

Instead of using a single large-diameter retort, the patent segments the catalyst volume into multiple smaller-diameter catalytic tubes arranged in parallel. This segmentation maintains sufficient total catalyst volume for high productivity while simplifying individual tube structures and reducing overall device complexity.

Inventive Principle:
Principle #1Segmentation

4Productivity

If conventional endogas generators operate at reduced flow rates, then productivity decreases, but catalyst regeneration capability is lost

Engineering Contradiction:
Improveendogas flow rateVSAvoidcatalyst regeneration capability
Core Design Contradiction:
ProductivityVSAdaptability or versatility

Solution Approach 1:

The patent enables continuous catalyst regeneration by allowing non-operational catalytic tubes to be regenerated in-situ while other tubes continue producing endogas. This maintains continuous useful action of the system, combining reduced productivity mode with ongoing catalyst maintenance capability.

Inventive Principle:
Principle #20Continuity of useful action

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

Enables production of endogas with increased CO and H2 percentages, maintaining optimal composition even at reduced flow rates, and allows for continuous operation with catalyst regeneration, reducing downtime and operational costs.

Implementation Method 1

each said catalytic tube contains, at least in one tube section, a catalyst based on noble metal oxides for partial oxidation of an air-methane (or other hydrocarbon) or air-methane-carbon dioxide (or other hydrocarbon) mixture

Methodology Applied
Scientific EffectCatalysis: Catalysis

Implementation Method 2

the result of an endothermic reaction of incomplete combustion between air and methane (or another hydrocarbon), conducted in the absence of oxygen and in the absence of water/steam, to form reducing substances such as CO

Methodology Applied
Scientific EffectPartial oxidation: Oxidation

Implementation Method 3

a heating chamber that supplies heat to a catalytic reactor, placed inside it

Methodology Applied
Scientific EffectThermal heating: Heating

Implementation Method 4

followed by a heat exchanger, usually gas/water, to rapidly cool the reaction products so as to avoid that the reaction proceeds further forming CO2 in high quantities

Methodology Applied
Scientific EffectHeat exchange: Heat Exchanger

Implementation Method 5

The endogas is the result of an endothermic reaction of incomplete combustion between air and methane (or another hydrocarbon)

Methodology Applied
Scientific EffectEndothermic reaction: Endothermic Reaction

Data Source

PatentEP3789344B1Modulable system for the generation of endogas with carbon monoxide content that can be set
Publication Date: 2021.11.10 NIPPON GASES IND SRL
  • EP3789344B1 patent drawingFigure 1
  • EP3789344B1 patent drawingFigure 2
  • EP3789344B1 patent drawingFigure 3

AI summary

A description is given of an endogas generator (100) which comprises a catalytic reactor inside a heating chamber (1) where the catalytic reactor consists of at least three catalytic tubes (4) in the form of a tube bundle, each containing a noble metal oxide-based catalyst for the partial oxidation of a binary air-methane (or another hydrocarbon) or ternary air-methane-CO2 (or another hydrocarbon) mixture, said generator providing moreover an automated system (200) with two mixing and control units (501;502) independent one of the other, for controlling singly shut-off valves (6in) placed upstream of said catalytic tubes so as to be able to manage simultaneously the flow rate of endogas, the possible CO enrichment of the endogas and the number of catalytic tubes (4) in regeneration.