Modular Endogas Generator Tube Bundle Flow Modulation

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Solution Overview

Problem

Existing endogas generators face challenges in modulating flow rates while maintaining optimal composition, especially at reduced rates, due to limitations in catalyst activity and system design, leading to inefficiencies and potential catalyst damage.

Innovation Solution

A modular endogas generator with a tube bundle configuration using noble metal oxide-based catalysts, each catalyst tube being independently supplied and cooled, allowing for adjustable flow rates without compromising composition, and featuring a heating chamber with burners to ensure uniform temperature distribution across the catalyst bed.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Productivity

If the flow rate is reduced to modulate production, then productivity is improved (lower production demand), but the gas velocity in the retort decreases causing incomplete contact with catalyst and loss of optimal composition

Engineering Contradiction:
Improveflow rate modulationVSAvoidendogas composition
Core Design Contradiction:
ProductivityVSStability of the object's composition

Solution Approach 1:

The single retort is divided into multiple parallel retorts (first, second, and third retorts). Each retort can be independently supplied with gas mixture through separate control valves, allowing the system to maintain optimal gas velocity in each retort even when overall production demand is reduced by excluding certain retorts from operation.

Inventive Principle:
Principle #1Segmentation

Solution Approach 2:

The system dynamically adjusts the number of active retorts based on production demand. Control valves independently regulate the gas mixture flow to each retort, enabling the system to maintain optimal operating conditions (gas velocity, composition) in active retorts while modulating total output by activating or deactivating specific retorts.

Inventive Principle:
Principle #15Dynamics

2Quantity of substance

If a single large diameter retort is used, then catalyst volume is sufficient for nominal production, but the system becomes complex and less modulable when production reduction is needed

Engineering Contradiction:
Improvecatalyst volumeVSAvoidsystem complexity
Core Design Contradiction:
Quantity of substanceVSDevice complexity

Solution Approach 1:

Instead of using a single large diameter retort, the system employs multiple smaller diameter retorts arranged in parallel. This segmentation provides sufficient total catalyst volume while enabling independent control of each retort through separate supply lines and control valves, significantly improving system modulability without increasing overall complexity.

Inventive Principle:
Principle #1Segmentation

Solution Approach 2:

Each retort is equipped with its own control valve and supply mechanism, allowing local adjustment and independent operation. This local control capability enables flexible modulation of production by activating or deactivating specific retorts based on demand, while each retort maintains optimal local operating conditions.

Inventive Principle:
Principle #3Local quality

3Productivity

If excessive reduction in flow rate occurs, then productivity matches low demand, but catalyst is exposed to localised excess temperatures causing early damaging

Engineering Contradiction:
Improveflow rate matching demandVSAvoidcatalyst durability
Core Design Contradiction:
ProductivityVSReliability

Solution Approach 1:

The catalyst is distributed across multiple separate retorts rather than concentrated in a single retort. When production demand is reduced, the system excludes specific retorts from operation while maintaining optimal flow rates in active retorts, preventing localised excess temperatures and protecting catalyst durability.

Inventive Principle:
Principle #1Segmentation

Solution Approach 2:

The system dynamically redistributes the gas mixture flow among available retorts based on operational conditions. By actively controlling the number and configuration of active retorts, the system maintains optimal flow velocity and temperature distribution in active catalyst beds, preventing thermal runaway and catalyst damage even at reduced overall production levels.

Inventive Principle:
Principle #15Dynamics

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

Enables production of endogas with constant optimal composition at flow rates reduced by up to 90% of the nominal rate, while reducing system complexity and costs, and allowing for efficient maintenance by enabling selective catalyst tube exclusion and replacement.

Implementation Method 1

a heating chamber which supplies heat to a catalytic reactor

Methodology Applied
Scientific EffectCombustion: Combustion

Implementation Method 2

supplies heat to a catalytic reactor, placed in its interior

Methodology Applied
Scientific EffectHeat conduction: Conduction (thermal)

Implementation Method 3

an endothermic reaction of incomplete combustion between air and methane (or another hydrocarbon), performed with a lack of oxygen and in the absence of water/steam, to form reducing substances such as CO

Methodology Applied
Scientific EffectCatalysis: Catalysis

Implementation Method 4

endothermic reaction of incomplete combustion between air and methane

Methodology Applied
Scientific EffectEndothermic reaction: Endothermic Reaction

Implementation Method 5

followed by a heat exchanger, generally gas/water, for cooling the reaction products rapidly so as to prevent the reaction from proceeding further

Methodology Applied
Scientific EffectHeat exchange: Heat Exchanger

Data Source

PatentEP2851339B1Modulable system for the generation of endogas
Publication Date: 2021.01.27 NIPPON GASES ITAL SRL
  • EP2851339B1 patent drawingFigure 1
  • EP2851339B1 patent drawingFigure 2
  • EP2851339B1 patent drawingFigure 3

AI summary

A description is given of a generator of endogas (100) which comprises an outer heating chamber (1) for supplying heat to an inner catalytic reactor containing a catalyst based on oxides of noble metals for the partial oxidation of a mixture of air-methane (or another hydrocarbon) and at least one heat exchanger for the rapid cooling of the endogas produced wherein the catalytic reactor inside the heating chamber (1) is constituted by at least three catalyst tubes (4) arranged in the form of a tube bundle, each of which having a diameter equal to or smaller than 80 mm, said catalyst tubes (4) being arranged parallel one to the other in the form of a tube bundle, each catalyst tube (4) being in fluid communication with a respective supply tube (5), outside of said heating chamber (1).