Modular Mercury Speciation Device for Fluid Analysis

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Solution Overview

Problem

Current methods lack effective and affordable protocols for monitoring and assessing mercury (Hg) species in environments, particularly in distinguishing organic Hg from inorganic and elemental Hg, and determining their presence and concentration in aqueous samples.

Innovation Solution

A modular Hg speciation device comprising multiple modules that can be combined to target specific Hg species, including filtration, reduction, and amalgamation modules, which physically filter, reduce, and capture Hg species, allowing for sequential analysis to determine the presence and quantity of different Hg species in a fluid sample.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Measurement precision

If traditional Hg monitoring methods are used, then Hg species can be detected, but the protocols are complex and expensive

Engineering Contradiction:
ImproveHg species detection accuracyVSAvoidprotocol complexity
Core Design Contradiction:
Measurement precisionVSDevice complexity

Solution Approach 1:

The device is divided into multiple functional modules (filtration module, reduction module, amalgamation module, capture module) that can be selectively assembled. Each module performs a specific function in the Hg speciation analysis protocol, allowing complex analytical tasks to be broken down into manageable, standardized components that simplify the overall protocol while maintaining detection accuracy.

Inventive Principle:
Principle #1Segmentation

Solution Approach 2:

The modular device design allows a single platform to perform multiple Hg speciation analysis protocols by differentially assembling modules. The same basic module structure can be configured for different analytical requirements, making the system universally applicable to various Hg species detection needs without requiring separate complex protocols for each analysis type.

Inventive Principle:
Principle #6Universality (Multi-functionality)

2Measurement precision

If traditional Hg monitoring methods are used, then Hg species can be detected, but the cost is high

Engineering Contradiction:
ImproveHg species detection accuracyVSAvoiddevice cost
Core Design Contradiction:
Measurement precisionVSEase of manufacture

Solution Approach 1:

By segmenting the device into standardized modules, each component can be manufactured independently using cost-effective materials and assembly methods. This modular approach allows for economies of scale in module production and enables selective assembly based on analytical needs, reducing overall device cost while maintaining the precision required for Hg species detection.

Inventive Principle:
Principle #1Segmentation

Solution Approach 2:

The device utilizes changes in chemical parameters (reduction potential, amalgamation affinity, capture specificity) across different modules to achieve Hg speciation. By relying on well-established chemical principles rather than expensive specialized equipment, the system achieves high measurement precision at lower manufacturing costs.

Inventive Principle:
Principle #35Parameter changes

3Measurement precision

If Hg species are differentiated using traditional methods, then organic Hg and inorganic Hg can be distinguished, but the protocol is not easily modified for specific species

Engineering Contradiction:
ImproveHg species differentiation accuracyVSAvoidprotocol flexibility
Core Design Contradiction:
Measurement precisionVSAdaptability or versatility

Solution Approach 1:

The segmentation of the device into functionally distinct modules (filtration, reduction, amalgamation, capture) enables flexible reconfiguration for different Hg species analysis. Each module can be selectively assembled or removed based on the specific analytical protocol required, allowing the system to adapt to different species differentiation needs while maintaining accurate measurement through the standardized functional components.

Inventive Principle:
Principle #1Segmentation

Solution Approach 2:

The modular device architecture provides dynamic adaptability, allowing the system configuration to change based on analytical requirements. Modules can be added, removed, or repositioned to create different protocol configurations, making the system versatile for various Hg species differentiation tasks while preserving measurement precision through consistent module performance.

Inventive Principle:
Principle #15Dynamics

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

Enables accurate and simple determination of Hg species in environmental samples, providing valuable information for risk assessment by selectively separating and quantifying mercury species, thereby improving monitoring and risk assessment capabilities.

Implementation Method 1

a filtration module that can physically filter a sample to remove particles of a predetermined size from a fluid sample

Methodology Applied
Scientific EffectFiltration: Filter (physical)

Implementation Method 2

a reduction module that includes a reductant configured to interact with and reduce inorganic and ionic Hg species to form elemental Hg

Methodology Applied
Scientific EffectReduction: Reduction

Implementation Method 3

an amalgamation agent that is configured to form an amalgam with elemental mercury. The amalgamation agent can be retained in a module and utilized to capture elemental Hg flowing through the module

Methodology Applied
Scientific EffectAmalgamation: Absorption (physical)

Data Source

PatentUS11319225B2Modular system and method for mercury speciation in a fluid sample
Publication Date: 2022.05.03 BATTELLE SAVANNAH RIVER ALLIANCE LLC
  • US11319225B2 patent drawing
  • US11319225B2 patent drawing

AI summary

Modular Hg analysis devices and methods are described for use in mercury speciation protocols. Modules can be selected and removably connected to one another to specifically target mercury species in a sample so as to accurately determine the presence or quantity of different mercury species in a fluid sample. Modules can include reductants for reducing inorganic mercury to form elemental mercury and amalgamation agents to capture the elemental mercury. Modules can include filters for capture of particulates as well as capture agents, e.g., solid phase extraction agents, for capture of organic mercury species.