MOL Interconnect Structure With Ruthenium Oxide Diffusion Barrier

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Solution Overview

Problem

Existing integrated circuit manufacturing processes face challenges with high contact resistance, void formation, and reliability issues due to oxidation and diffusion of metal liners, particularly in middle-of-the-line (MOL) interconnect structures, which are exacerbated by the use of traditional materials like tungsten and cobalt.

Innovation Solution

The introduction of a ruthenium-based intermixing barrier layer formed through annealing, eliminating the need for glue and barrier layers, which enhances adhesion and prevents diffusion, thereby reducing contact resistance and void formation, and simplifying the manufacturing process.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Reliability

If traditional materials like tungsten and cobalt are used in MOL interconnect structures, then structural integrity is maintained, but contact resistance increases and reliability deteriorates due to oxidation and diffusion of metal liners

Engineering Contradiction:
Improvecontact resistanceVSAvoidoxidation and diffusion of metal liners
Core Design Contradiction:
ReliabilityVSObject-affected harmful factors

Solution Approach 1:

A ruthenium oxide intermixing barrier layer is introduced as an intermediary between the metal liner and the dielectric layer. This barrier layer prevents direct contact between the metal liner and oxygen-containing environments, thereby preventing oxidation. It also acts as a diffusion barrier to prevent metal liner atoms from diffusing into the dielectric layer, solving both oxidation and diffusion problems simultaneously.

Inventive Principle:
Principle #24Intermediary (Mediator)

Solution Approach 2:

The patent uses a composite structure consisting of a ruthenium oxide intermixing barrier layer combined with a metal liner (tungsten or cobalt). The ruthenium oxide layer provides protective functions while the metal liner provides structural integrity and conductivity, creating a composite material system that overcomes the limitations of traditional single-material approaches.

Inventive Principle:
Principle #40Composite materials

2Reliability

If glue and barrier layers are used in traditional MOL processes, then adhesion and diffusion prevention are achieved, but device complexity and manufacturing process complexity increase

Engineering Contradiction:
Improveadhesion and diffusion preventionVSAvoidnumber of layers and processes
Core Design Contradiction:
ReliabilityVSDevice complexity

Solution Approach 1:

The patent merges the functions of the glue layer and the barrier layer into a single ruthenium oxide intermixing barrier layer. This consolidated layer simultaneously provides adhesion between the metal liner and dielectric layer, prevents diffusion of metal atoms, and protects against oxidation, thereby reducing the total number of layers and simplifying the manufacturing process.

Inventive Principle:
Principle #5Merging (Combining)

Solution Approach 2:

The ruthenium oxide intermixing barrier layer is designed to perform multiple functions: it provides adhesion, prevents diffusion, and protects against oxidation. This multi-functional layer replaces multiple separate layers (glue layer and barrier layer), reducing device complexity while maintaining or improving protective and adhesive functions.

Inventive Principle:
Principle #6Universality (Multi-functionality)

3Reliability

If ion implantation processes are used to prevent diffusion, then diffusion prevention is achieved, but manufacturing process complexity and time increase

Engineering Contradiction:
Improvediffusion preventionVSAvoidmanufacturing process time
Core Design Contradiction:
ReliabilityVSProductivity

Solution Approach 1:

The patent replaces the ion implantation process (a complex, time-consuming, and equipment-intensive process) with a ruthenium oxide intermixing barrier layer that provides diffusion prevention through its physical and chemical properties. The barrier layer inherently prevents diffusion without requiring additional processing steps, thereby improving productivity while maintaining diffusion prevention effectiveness.

Inventive Principle:
Principle #28Mechanics substitution (Replace mechanical system)

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The ruthenium oxide intermixing barrier layer improves contact resistance by up to 40% and enhances reliability by eliminating the need for ion implantation processes, while maintaining structural integrity during subsequent manufacturing steps.

Implementation Method 1

an intermixing barrier layer of ruthenium oxide disposed between the upper conductive plug and the upper ILD layer and acting as a homogeneous glue layer therebetween

Methodology Applied
Scientific EffectDiffusion barrier: Diffusion Barrier

Implementation Method 2

The intermixing barrier layer may be formed by an annealing process following a filling process of the ruthenium conductive plug

Methodology Applied
Scientific EffectAnnealing: Annealing

Implementation Method 3

The introduction of a ruthenium-based intermixing barrier layer formed through annealing, eliminating the need for glue and barrier layers, which enhances adhesion and prevents diffusion

Methodology Applied
Scientific EffectOxidation: Oxidation

Data Source

PatentUS20250279353A1Middle-of-line interconnect structure and manufacturing method
Publication Date: 2025.09.04 TAIWAN SEMICONDUCTOR MANUFACTURING CO LTD
  • US20250279353A1 patent drawing
  • US20250279353A1 patent drawing
  • US20250279353A1 patent drawing

AI summary

In some embodiments, the present disclosure relates to an integrated circuit device. A transistor structure includes a gate electrode separated from a substrate by a gate dielectric and a pair of source/drain regions disposed within the substrate on opposite sides of the gate electrode. A lower conductive plug is disposed through a lower inter-layer dielectric (ILD) layer and contacting a first source/drain region. A capping layer is disposed directly on the lower conductive plug. An upper inter-layer dielectric (ILD) layer is disposed over the capping layer and the lower ILD layer. An upper conductive plug is disposed through the upper ILD layer and directly on the capping layer.