Molding Compound With Randomly Oriented Filaments

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Solution Overview

Problem

Fiber-reinforced composites face challenges in achieving isotropic and uniform material properties, high tensile strengths, and efficient processing due to limitations in fiber orientation and distribution, leading to increased production costs and unsuitability for structural applications.

Innovation Solution

A method involving the formation of a molding compound with unidirectionally aligned multifilament tows impregnated with a curable resin composition, which are then cut into strips, randomly oriented, and fused to create a mat with randomly oriented filaments, allowing for high fiber content and isotropic properties without the need for refrigeration or specialized handling.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Strength

If fibers are aligned unidirectionally to achieve high tensile strength, then tensile strength is improved, but isotropic properties deteriorate

Engineering Contradiction:
Improvetensile strengthVSAvoidisotropic properties
Core Design Contradiction:
StrengthVSStability of the object's composition

Solution Approach 1:

The continuous fiber bed is segmented into strips of controlled length (10-100 mm), which are then randomly distributed during molding. This segmentation allows individual fiber segments to be oriented in multiple directions throughout the mold, achieving isotropic properties while maintaining the high strength characteristics of aligned fibers within each segment

Inventive Principle:
Principle #1Segmentation

Solution Approach 2:

The invention transitions from a single-dimension aligned fiber structure to a multi-dimensional random distribution of fiber strips. By controlling the length-to-width ratio and randomly depositing strips in multiple orientations, the composite achieves isotropic properties in three-dimensional space while preserving the inherent strength of the fiber material

Inventive Principle:
Principle #17Another dimension (Dimensionality change)

2Manufacturing precision

If prepregs are cut precisely to mold dimensions to achieve uniform fiber distribution, then manufacturing precision is improved, but device complexity and production costs worsen

Engineering Contradiction:
Improvefiber distribution uniformityVSAvoidproduction process complexity
Core Design Contradiction:
Manufacturing precisionVSDevice complexity

Solution Approach 1:

Fibers are pre-aligned in a controlled bed formation step before being cut into strips and randomly distributed. This preliminary alignment ensures uniform fiber content and distribution characteristics in the final composite without requiring complex precision cutting to match specific mold dimensions, thereby simplifying the overall manufacturing process

Inventive Principle:
Principle #10Preliminary action

Solution Approach 2:

The invention changes the critical parameters from precise dimensional cutting to controlled fiber bed areal weight (80-400 g/m²) and strip length-to-width ratio (16-150). By controlling areal weight and strip geometry rather than precise dimensions, the process achieves uniform fiber distribution with simpler equipment and lower production complexity

Inventive Principle:
Principle #35Parameter changes

3Ease of manufacture

If resin is made tacky at room temperature to impregnate fibers, then ease of manufacture is improved, but storage stability deteriorates requiring refrigeration

Engineering Contradiction:
Improvefiber impregnationVSAvoidstorage stability
Core Design Contradiction:
Ease of manufactureVSStability of the object's composition

Solution Approach 1:

The resin composition parameters are specifically selected to achieve optimal impregnation at room temperature without excessive tackiness. The resin has a viscosity of 50-500 Pa·s at 25°C and a glass transition temperature of -50 to 0°C, allowing sufficient flow to impregnate fibers while maintaining storage stability without refrigeration

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The invention uses a composite resin system combining epoxy resin with specific curing agents and modifiers to achieve the desired balance between impregnation capability and storage stability. The resin formulation includes epoxy resin (30-70 wt%), curing agent (10-40 wt%), and modifiers (5-20 wt%) to optimize both processing and storage characteristics

Inventive Principle:
Principle #40Composite materials

4Strength

If high fiber content is used to achieve high tensile strength, then strength is improved, but fiber orientation control worsens reducing isotropic properties

Engineering Contradiction:
Improvetensile strengthVSAvoidfiber orientation distribution
Core Design Contradiction:
StrengthVSStability of the object's composition

Solution Approach 1:

The high fiber content bed is segmented into numerous short strips that can be randomly distributed throughout the mold. This segmentation enables high overall fiber content (40-80 wt%) while maintaining isotropic properties, as the random orientation of many small segments averages out to uniform reinforcement in all directions

Inventive Principle:
Principle #1Segmentation

Solution Approach 2:

The invention achieves high fiber content with isotropic properties by transitioning from continuous aligned fibers to randomly oriented short strips. The length-to-width ratio control (16-150) ensures strips are sufficiently long to provide strength but short enough to randomize orientation, achieving both high fiber content and isotropic reinforcement

Inventive Principle:
Principle #17Another dimension (Dimensionality change)

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The resulting composites exhibit high strength and isotropic properties, suitable for structural applications, with improved handling and storage stability, enabling robotic manipulation and reduced manufacturing costs by eliminating the need for precise mold matching.

Implementation Method 1

heating the curable resin composition to a temperature of at least 40° C.

Methodology Applied
Scientific EffectViscosity reduction through heating: Heating

Implementation Method 2

applying pressure to the bed and the heated curable resin composition to form an impregnated multifilament bed

Methodology Applied
Scientific EffectPressure-driven flow: Pressure Gradient

Implementation Method 3

cooling the impregnated multifilament bed to below 40° C.

Methodology Applied
Scientific EffectSolidification through cooling: Cooling

Implementation Method 4

heating the mat to an elevated temperature and compressing the mat to fuse said strips together

Methodology Applied
Scientific EffectThermal fusion: Heating

Implementation Method 5

compressing the mat to fuse said strips together to form a molding compound

Methodology Applied
Scientific EffectCompression bonding: Compression

Data Source

PatentUS11286358B2Molding compound having randomly oriented filaments and methods for making and using same
Publication Date: 2022.03.29 DOW GLOBAL TECHNOLOGIES LLC
  • US11286358B2 patent drawing

AI summary

A molding compound is made by heat-softening, fusing and compressing strips of unidirectionally aligned filaments embedded in a thermosetting resin. The thermosetting resin is non-tacky at room temperature, which allows for easy handling, elimination of cold storage and the use of robotic manufacturing methods. Composites made by molding the molding compound have excellent, highly isotropic tensile properties.