Molten Salt Reactor Moderator Using Metal Hydroxides

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Solution Overview

Problem

Molten salt nuclear fission reactors face challenges with existing moderator materials, such as graphite and ZrHx, due to issues like large reactor core size, corrosion, and complex cooling requirements, which have hindered the commercialization of these reactors.

Innovation Solution

The use of metal hydroxides and deuteroxides as molten moderator salts, combined with a redox-element, to efficiently moderate neutrons and provide corrosion protection, allowing for a more compact reactor design and simplified cooling systems.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Reliability

If graphite or ZrHx is used as moderator material, then neutron moderation is achieved, but reactor core size becomes large and corrosion issues arise

Engineering Contradiction:
Improvecorrosion resistanceVSAvoidreactor core size
Core Design Contradiction:
ReliabilityVSVolume of stationary object

Solution Approach 1:

The patent changes the physical state of the moderator from solid (graphite, ZrHx) to liquid molten salt, enabling superior heat transfer properties and corrosion resistance while maintaining effective neutron moderation. The molten salt moderator allows for compact reactor core design due to its high density and efficient neutron scattering properties.

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent employs composite molten salt formulations combining multiple salts (e.g., LiF, NaF, KF) with specific ratios to optimize both neutron moderation efficiency and corrosion resistance. This composite approach allows tuning of physical and chemical properties to simultaneously address moderation performance and material compatibility.

Inventive Principle:
Principle #40Composite materials

2Device complexity

If solid moderator materials are used, then neutron moderation is provided, but cooling requirements become complex

Engineering Contradiction:
Improvecooling system complexityVSAvoidmoderator performance
Core Design Contradiction:
Device complexityVSReliability

Solution Approach 1:

The molten salt moderator serves dual functions: it moderates neutrons through scattering and simultaneously acts as the primary cooling medium for heat removal from the reactor core. This multi-functionality eliminates the need for separate cooling systems, significantly reducing device complexity while maintaining reliable moderator performance.

Inventive Principle:
Principle #6Universality (Multi-functionality)

Solution Approach 2:

The patent utilizes the fluid properties of molten salt to enable passive convection cooling and active pump-driven circulation systems. The liquid state allows efficient heat transport through hydraulic flow, replacing complex solid-state cooling mechanisms with simpler fluid-based thermal management.

Inventive Principle:
Principle #29Pneumatics and hydraulics

3Object-affected harmful factors

If water is used as moderator, then neutron moderation is achieved, but high pressure operation is required leading to safety risks

Engineering Contradiction:
Improvesafety risksVSAvoidoperating temperature
Core Design Contradiction:
Object-affected harmful factorsVSTemperature

Solution Approach 1:

The patent changes the moderator from water (liquid at ambient conditions) to molten salt (liquid at elevated temperatures), enabling operation at high temperatures without corresponding high pressures. This parameter change allows the system to achieve superior thermal efficiency while maintaining safety by operating at atmospheric or near-atmospheric pressures.

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The molten salt moderator can be easily replaced or replenished if degradation occurs, providing a safety advantage over water systems where pressure containment failures have catastrophic consequences. The liquid molten salt can be drained or replaced without complex high-pressure containment requirements.

Inventive Principle:
Principle #27Cheap short-living objects (Disposable)

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

This approach enables the construction of smaller, more efficient molten salt reactors with improved corrosion resistance and reduced material requirements, enhancing safety and operational efficiency.

Implementation Method 1

the energetic neutrons produced by fission exchange energy with a moderator and eventually interact with fissile material

Methodology Applied
Scientific EffectNeutron scattering: Scattering

Implementation Method 2

the redox-element has a reduction potential, which is larger than that of the inner tubing material or of the inner tubing material and the core container material

Methodology Applied
Scientific EffectOxidation: Oxidation

Data Source

PatentEP3639279B1Molten salt reactor
Publication Date: 2021.09.01 SEABORG APS
  • EP3639279B1 patent drawingFigure 1
  • EP3639279B1 patent drawingFigure 2
  • EP3639279B1 patent drawingFigure 3~4

AI summary

A device adapted for producing energy by nuclear fission, the device comprising a core container of a core container material, which core container encloses an inner tubing of an inner tubing material, the inner tubing and/or the core container having an inlet and an outlet, the device further comprising a molten fuel salt with a fissionable material and a molten moderator salt comprising at least one metal hydroxide, at least one metal deuteroxide or a combination thereof and a redox-element having a reduction potential, which is larger than that of the inner tubing material or of the inner tubing material and the core container material, wherein the molten moderator salt is located in the core container and the molten fuel salt is located in the inner tubing, or wherein the molten fuel salt is located in the core container and the molten moderator salt is located in the inner tubing. The invention also relates to methods of controlling nuclear fission processes using the device and to the use of a molten salt comprising at least one metal hydroxide, at least one metal deuteroxide or a combination thereof and a redox-element for moderating fission neutrons created in a fission reaction process.