Molybdenum Correlated Metal Compounds for Transparent Conductive Oxides
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Solution Overview
Problem
Current transparent conductive oxide (TCO) materials, such as doped zinc oxide and tin oxide, face limitations in improving optical transmission and electrical conductivity simultaneously, necessitating the development of new transparent conductive materials (TCMs).
Innovation Solution
The development of compounds represented by formulas Ba a Mo b O c, Mo d P e O f, and Ba g Mo h P i O j, where the molybdenum is in the 4+ oxidation state, offering alternative routes for TCMs with enhanced optical and electrical properties.
Engineering Contradictions & Design Principles
Engineering Contradiction Analysis
1Reliability
If heavy doping is used to improve carrier concentration in TCOs, then electrical conductivity is improved, but optical transmission deteriorates due to increased free carrier reflection
Solution Approach 1:
The patent changes the fundamental material parameter from wide band gap semiconductor to correlated metal, which inherently provides high carrier density without requiring heavy doping. This parameter change shifts the plasma frequency out of the visible region through interelectron repulsion, simultaneously achieving high electrical conductivity and high optical transmission in the visible spectrum
Solution Approach 2:
The patent creates composite transparent conductive materials by combining metal elements with specific oxidation states (such as Mo4+) and dopants (such as alkali metals like K, Rb, Cs) to form correlated metal compounds. This composite approach enables the material to exhibit both high carrier density from the metal and enhanced optical transmission from the correlated electron effects
2Reliability
If conventional metals are used to provide high carrier density, then electrical conductivity is improved, but optical transmission deteriorates due to free carrier reflection in the visible spectrum
Solution Approach 1:
The patent changes the electronic structure parameter of the metal by introducing correlated electron effects through specific oxidation states and doping. This changes the plasma frequency from the visible region to other spectral regions, allowing the metal to maintain high conductivity while becoming transparent in the visible spectrum
Solution Approach 2:
The patent introduces dopant elements (such as alkali metals) as intermediaries that modify the electronic structure of the metal. These dopants create correlated electron states that shift the plasma frequency, acting as a mediator between the high carrier density requirement and the optical transmission requirement
Data Source
Figure 1~2

AI summary
A compound represented by one of the formulae: BaaMobOc (1) , ModPeOf (2) or BagMohPiOj (3) wherein for formula (1) the ratio of a:b is greater than 1:1, wherein for formula (2) the ratio of d:e is from 1:100 to 0.45:1 or from 0.55:1 to 100:1, wherein for formula (3) the ratio of g:h is from 1:7 to 1:2 and the ratio of g:i is from 1:3 to 1:1, or the ratio of g:h is from 0.6:1 to 100:1 and the ratio of g:i is from 2.2:1 to 100:1, and wherein the molybdenum present within the compound is in the 4+ oxidation state.