Thin Metal-Organic Mixed Layer for OLED Reflectance Reduction

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Solution Overview

Problem

Existing organic light emitting devices (OLEDs) face challenges with high ambient light reflection, leading to reduced image contrast, and instability due to reactive cathode materials that degrade in ambient conditions.

Innovation Solution

The use of thin metal-organic mixed layers (MOMLs) with a thickness of 5 nm to 175 nm, comprising a metal and an organic material, are integrated into the display device structure to reduce ambient light reflection and enhance stability by acting as a light-reflection-reduction layer.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Ease of manufacture

If a highly reflective back electrode is used in OLEDs, then the device structure is simple and manufacturing is easier, but ambient light reflection increases causing image washout and reduced contrast

Engineering Contradiction:
Improveease of manufactureVSAvoidambient light reflection
Core Design Contradiction:
Ease of manufactureVSObject-affected harmful factors

Solution Approach 1:

The patent applies composite materials by creating a metal-organic mixed layer (MOML) that combines metal particles (such as aluminum, silver, or magnesium) dispersed in an organic matrix material. This composite structure provides both the electrical conductivity needed for the cathode function and the optical properties to reduce ambient light reflection. The organic matrix allows for uniform distribution of metal particles and enables the layer to function as both an electrode and an anti-reflection coating, thus resolving the contradiction between manufacturing simplicity and reducing harmful reflections.

Inventive Principle:
Principle #40Composite materials

Solution Approach 2:

The patent applies local quality by creating a MOML with specific local optical properties at the back electrode interface. The metal particle concentration, size, and distribution are optimized locally within the organic matrix to achieve the desired reflectance reduction while maintaining electrical functionality. This localized optimization allows the back electrode to have different properties in different regions or aspects (electrical conductivity vs. optical reflection) without compromising overall device performance or manufacturing simplicity.

Inventive Principle:
Principle #3Local quality

2Power

If reactive metals with low work functions are used in cathodes, then electron injection efficiency is improved, but stability deteriorates due to reaction with atmospheric O2 and water forming non-emissive dark spots

Engineering Contradiction:
Improveelectron injection efficiencyVSAvoidstability
Core Design Contradiction:
PowerVSReliability

Solution Approach 1:

The patent uses composite materials to create a MOML that combines reactive metal particles (providing low work function for efficient electron injection) with an organic matrix material (providing stability and protection). The organic matrix acts as a protective environment that prevents direct exposure of the reactive metal particles to atmospheric oxygen and water, thereby maintaining both the electron injection efficiency of the reactive metals and the stability required for long-term operation without forming non-emissive dark spots.

Inventive Principle:
Principle #40Composite materials

Solution Approach 2:

The organic matrix material serves as an intermediary between the reactive metal particles and the ambient atmosphere. It mediates the interaction by providing a stable environment that allows the metal particles to maintain their low work function properties for electron injection while preventing direct contact with oxygen and water that would cause degradation. This intermediary layer enables the system to achieve both high electron injection efficiency and long-term stability.

Inventive Principle:
Principle #24Intermediary (Mediator)

3Object-affected harmful factors

If the metal-organic mixed layer thickness is increased, then light reflection reduction is improved, but device complexity and fabrication difficulty increase

Engineering Contradiction:
Improvelight reflection reductionVSAvoiddevice complexity
Core Design Contradiction:
Object-affected harmful factorsVSDevice complexity

Solution Approach 1:

The patent applies parameter changes by optimizing the thickness of the MOML to a specific range (5 nm to 175 nm) where the layer achieves effective light reflection reduction without excessive complexity. By controlling the thickness parameter within this optimized range, the patent finds a balance point where the MOML is thin enough to maintain fabrication simplicity and device structure clarity, yet thick enough to provide the desired anti-reflection performance. This parameter optimization resolves the contradiction between reflection reduction effectiveness and device complexity.

Inventive Principle:
Principle #35Parameter changes

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The thin MOMLs effectively reduce ambient light reflection by at least 30% and improve the stability of OLEDs by minimizing the formation of non-emissive dark spots, thereby enhancing image contrast and device longevity.

Implementation Method 1

The thin metal-organic mixed layers comprise metal particles in an organic matrix material... effectively reduce ambient light reflection by at least 30%

Methodology Applied
Scientific EffectLight absorption: Absorption (EM radiation)

Implementation Method 2

metal particles in an organic matrix material... reduce the ambient illumination reflection

Methodology Applied
Scientific EffectLight scattering: Scattering

Data Source

PatentUS7795806B2Reduced reflectance display devices containing a thin-layer metal-organic mixed layer (MOML)
Publication Date: 2010.09.14 LG DISPLAY CO LTD
  • US7795806B2 patent drawing
  • US7795806B2 patent drawing
  • US7795806B2 patent drawing

AI summary

A display device comprising a thin metal-organic mixed layer (MOML) comprising a metal (containing material) and an organic material, and having a thickness of less than 175 nm. A thin metal-organic mixed layer may be of a single or multi-layer configuration. The percent reflectance of a device may be controlled by varying the thickness of the MOML(s) and the metal component and concentration thereof in the MOML(s).