Monosodium Citrate Treatment for Acrylamide Reduction in Heated Carbohydrate Foods

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Solution Overview

Problem

Carbohydrate-containing foods, such as French fries and chips, form acrylamide when heated, which is carcinogenic and mutagenic, and existing methods to reduce acrylamide formation either alter the food's taste, appearance, or are not effective enough.

Innovation Solution

Treating foods with an aqueous solution of monosodium citrate before heating, with concentrations between 0.1% to 3% by weight, effectively reduces acrylamide formation without affecting the food's sensory properties.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Object-affected harmful factors

If pH-reducing agents (acids, buffer solutions, or fruit juice) are used to treat food, then acrylamide formation is reduced, but the food's taste and sensory properties are impaired

Engineering Contradiction:
Improveacrylamide formationVSAvoidfood taste and sensory properties
Core Design Contradiction:
Object-affected harmful factorsVSEase of manufacture

Solution Approach 1:

The patent changes the chemical parameter from acidic substances (pH-reducing agents) to monosodium citrate, which has different chemical properties. Monosodium citrate reduces acrylamide formation through a different mechanism that does not involve significant pH reduction, thereby preserving the food's taste and sensory properties while achieving the desired acrylamide reduction effect.

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

Monosodium citrate acts as an intermediary substance that interferes with the acrylamide formation pathway without directly altering the food's sensory characteristics. It mediates between the conflicting requirements of reducing acrylamide and maintaining food quality by providing a chemical mechanism that suppresses acrylamide formation independently of pH changes.

Inventive Principle:
Principle #24Intermediary (Mediator)

2Object-affected harmful factors

If polyvalent cations are added to reduce acrylamide, then acrylamide formation is inhibited, but the food's properties and appearance are altered

Engineering Contradiction:
Improveacrylamide formationVSAvoidfood properties and appearance
Core Design Contradiction:
Object-affected harmful factorsVSStability of the object's composition

Solution Approach 1:

The patent transitions from using polyvalent cations (which alter food composition and appearance) to monosodium citrate, changing the chemical approach from cation-based inhibition to citrate-based inhibition. This parameter change allows for acrylamide reduction while maintaining the stability of the food's composition, appearance, and sensory properties.

Inventive Principle:
Principle #35Parameter changes

3Object-affected harmful factors

If heating temperature is reduced to limit acrylamide formation, then acrylamide content decreases, but the cooking process becomes less effective and food quality deteriorates

Engineering Contradiction:
Improveacrylamide contentVSAvoidcooking effectiveness
Core Design Contradiction:
Object-affected harmful factorsVSProductivity

Solution Approach 1:

The patent applies monosodium citrate treatment before the heating process, performing a preliminary action that pre-conditioning the food to resist acrylamide formation. This preliminary treatment allows subsequent high-temperature heating to proceed effectively for cooking purposes while the pre-applied monosodium citrate continuously suppresses acrylamide formation throughout the heating process.

Inventive Principle:
Principle #10Preliminary action

Solution Approach 2:

Monosodium citrate serves as an intermediary that enables the separation of cooking effectiveness from acrylamide formation. It provides a chemical barrier that allows high-temperature heating to achieve proper cooking results while simultaneously blocking the acrylamide formation pathway, thus resolving the contradiction between cooking effectiveness and acrylamide reduction.

Inventive Principle:
Principle #24Intermediary (Mediator)

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

Significantly reduces acrylamide content in heated carbohydrate-containing foods, maintaining the food's taste, appearance, and crispiness, while being more effective than other proposed methods like citric acid or trisodium citrate.

Implementation Method 1

acrylamide is formed upon heating by a Maillard reaction of the amino group of aspartic acid with the anomeric center of sugars

Methodology Applied
Scientific EffectMaillard reaction: Chemical Bonding

Data Source

PatentEP2074890B1Method for reducing the acrylamide content of food containing carbohydrates
Publication Date: 2014.11.26 JUNGBUNZLAUER LADENBURG
  • EP2074890B1 patent drawingFigure 1~2
  • EP2074890B1 patent drawingFigure 3
  • EP2074890B1 patent drawingFigure 4

AI summary

The present invention relates to a method for reducing the acrylamide content in heated, carbohydrate-containing foods, in which the food is treated with monosodium citrate before heating. The invention further relates to carbohydrate-containing foods with a reduced potential for acrylamide formation upon heating, which have been treated with monosodium citrate.