Montmorillonite-PVA Barrier Layer for Flexible Medical Patches

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Solution Overview

Problem

Medical adhesive patches with flexible supports face issues maintaining barrier properties during elongation, leading to cracks and degradation of barrier layers, which can result in inadequate medicine administration and adverse effects from plasticizers.

Innovation Solution

A medical adhesive patch with a support film containing a barrier layer of polyvinyl alcohol and montmorillonite, laminated on a polyurethane surface, and an adhesive layer with a rubber-based polymer and specific plasticizers, ensuring excellent barrier properties even with elongation.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Adaptability or versatility

If a flexible support material is used to allow elongation during attachment and use, then flexibility and adaptability are improved, but the barrier layer develops cracks and loses barrier properties

Engineering Contradiction:
ImproveflexibilityVSAvoidbarrier property
Core Design Contradiction:
Adaptability or versatilityVSReliability

Solution Approach 1:

The barrier layer is constructed as a composite material containing polyvinyl alcohol as the base polymer and montmorillonite as the reinforcing filler. This composite structure provides both flexibility and crack resistance, allowing the barrier layer to maintain its integrity during support elongation while preserving barrier properties against plasticizer and medicine migration.

Inventive Principle:
Principle #40Composite materials

Solution Approach 2:

The patent optimizes the montmorillonite content parameter within a specific range (5-20 parts by weight per 100 parts of polyvinyl alcohol) and controls the degree of saponification (70-95.5%). These parameter adjustments balance the flexibility and barrier performance, ensuring the barrier layer can accommodate elongation without cracking while maintaining effective barrier properties.

Inventive Principle:
Principle #35Parameter changes

2Reliability

If the barrier layer is made thicker or more rigid to improve barrier properties, then barrier performance is improved, but flexibility and ability to respond to shape changes deteriorate

Engineering Contradiction:
Improvebarrier propertyVSAvoidflexibility
Core Design Contradiction:
ReliabilityVSAdaptability or versatility

Solution Approach 1:

The patent achieves optimal barrier properties through careful control of material parameters rather than increasing thickness. By adjusting the montmorillonite content (5-20 parts by weight per 100 parts of polyvinyl alcohol) and degree of saponification (70-95.5%), the barrier layer achieves effective barrier performance while maintaining flexibility and the ability to respond to shape changes during elongation.

Inventive Principle:
Principle #35Parameter changes

3Reliability

If a barrier coating material is applied to prevent plasticizer adsorption, then barrier properties are improved, but the support loses flexibility and elongation capability

Engineering Contradiction:
Improvebarrier propertyVSAvoidflexibility
Core Design Contradiction:
ReliabilityVSEase of operation

Solution Approach 1:

The barrier layer is constructed as a composite material containing polyvinyl alcohol as the base polymer and montmorillonite as the reinforcing filler. This composite structure provides both flexibility and barrier performance, allowing the barrier layer to maintain its integrity during support elongation while preserving barrier properties against plasticizer and medicine migration.

Inventive Principle:
Principle #40Composite materials

Solution Approach 2:

The patent optimizes the montmorillonite content parameter within a specific range (5-20 parts by weight per 100 parts of polyvinyl alcohol) and controls the degree of saponification (70-95.5%). These parameter adjustments balance the flexibility and barrier performance, ensuring the barrier layer can accommodate elongation without cracking while maintaining effective barrier properties.

Inventive Principle:
Principle #35Parameter changes

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The patch maintains excellent barrier properties during and after attachment, preventing medicine and plasticizer transition to the support, thus ensuring effective and prolonged medicine administration without adverse effects.

Implementation Method 1

Since there is a concern of a negative effect due to adsorption of a plasticizer depending on the material of a support, it is preferable that at least a surface of the support which comes in contact with the adhesive layer has barrier properties.

Methodology Applied
Scientific EffectAdsorption: Adsorption

Implementation Method 2

it is necessary for the support to obtain a barrier property

Methodology Applied
Scientific EffectBarrier property:

Implementation Method 3

a barrier layer containing polyvinyl alcohol with a degree of saponification in a range equal to or more than 70% and equal to or less than 95.5% and montmorillonite, the barrier layer being laminated on one surface of a support including polyurethane

Methodology Applied
Scientific EffectLamination: Lamination

Data Source

PatentEP2599500B1Medical adhesive patch
Publication Date: 2016.04.06 HISAMITSU PHARM CO INC
  • EP2599500B1 patent drawingFigure 1~2
  • EP2599500B1 patent drawingFigure 3~4
  • EP2599500B1 patent drawingFigure 5

AI summary

A medical adhesive patch, includes: a support film including a barrier layer which contains a water-soluble polymer compound and montmorillonite, and which is laminated on one surface of a support including polyurethane; an adhesive layer which contains a medicine and a plasticizer, and which is laminated on a barrier layer of the support film, the medical adhesive patch has a percentage content of montmorillonite in the barrier layer is equal to or more than 2 percent by weight and equal to or less than 22 percent by weight.