MoO3-Pd Nanocomposite Hydrogen Sensor Color Change

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Solution Overview

Problem

Current hydrogen detection sensors using metal oxides like WO3 suffer from reduced reaction efficiency and reliability over time due to catalyst degradation, necessitating a new sensor that is inexpensive, durable, and maintains sensitivity without external power sources.

Innovation Solution

A hydrogen detection sensor is developed using a molybdenum oxide (MoO3) nanostructure and palladium catalyst nanocomposite, synthesized via hydrothermal methods and coated on a substrate, which changes color visibly upon hydrogen exposure, enhancing sensitivity and long-term stability.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Area of moving object

If WO3 nanoparticles are used as catalyst in hydrogen sensor, then the contact area of catalyst with WO3 is greatly increased, but the reaction efficiency and reliability of the sensor deteriorate over time due to catalyst degradation

Engineering Contradiction:
Improvecontact area of catalystVSAvoidreaction efficiency and reliability over time
Core Design Contradiction:
Area of moving objectVSReliability

Solution Approach 1:

The patent changes the metal oxide from WO3 to MoO3, which has different catalytic properties and stability characteristics. MoO3 maintains its catalytic activity and structural integrity over time, resolving the degradation issue while preserving the high surface area benefit through nanoparticle formulation.

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent creates a composite material system combining MoO3 nanoparticles with specific support materials and potentially other metal components. This composite structure provides both the high surface area contact needed for sensitivity and the structural stability required for long-term reliability, overcoming the limitations of pure WO3 systems.

Inventive Principle:
Principle #40Composite materials

2Ease of manufacture

If inexpensive sensors are used to provide as many sensors as possible, then the cost is reduced, but the sensing performance and long-term stability may be compromised

Engineering Contradiction:
Improvemanufacturing costVSAvoidsensing performance and long-term stability
Core Design Contradiction:
Ease of manufactureVSReliability

Solution Approach 1:

The patent employs MoO3 nanoparticles as the active sensing material, which are inexpensive and can be easily synthesized through hydrothermal methods. This allows for mass production of cost-effective sensors that maintain high sensing performance and long-term stability, eliminating the need for expensive rare earth metals or complex catalyst systems.

Inventive Principle:
Principle #27Cheap short-living objects (Disposable)

Solution Approach 2:

The patent optimizes the size, shape, and surface area of the MoO3 nanoparticles to maximize sensing performance while minimizing material cost. By controlling nanoparticle dimensions and morphology, the system achieves high sensitivity and stability without requiring large amounts of expensive materials, enabling inexpensive mass production.

Inventive Principle:
Principle #35Parameter changes

3Device complexity

If simple manufacturing process is used to reduce costs, then the manufacturing complexity is reduced, but the manufacturing precision and sensor performance may be affected

Engineering Contradiction:
Improvemanufacturing process complexityVSAvoidsensor performance consistency
Core Design Contradiction:
Device complexityVSManufacturing precision

Solution Approach 1:

The patent employs hydrothermal synthesis to pre-form MoO3 nanoparticles with controlled size and morphology before incorporating them into the sensor device. This preliminary synthesis step ensures uniform nanoparticle characteristics that translate to consistent sensor performance, while the overall process remains simple and cost-effective.

Inventive Principle:
Principle #10Preliminary action

Solution Approach 2:

The hydrothermal synthesis method allows the MoO3 nanoparticles to self-assemble and self-organize into the desired structure without requiring complex external processing. The nanoparticles automatically arrange themselves in configurations that optimize both performance and manufacturing simplicity, eliminating the need for precise manual assembly or complex equipment.

Inventive Principle:
Principle #25Self-service

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The MoO3-Pd nanocomposite sensor exhibits improved hydrogen sensing and long-term stability with a simple manufacturing process, reducing costs and maintaining sensitivity through a visible color change mechanism.

Implementation Method 1

the molybdenum oxide, color change before and after the exposure to hydrogen may be visibly so obvious

Methodology Applied
Scientific EffectColor change: Photochromism

Implementation Method 2

irradiating UV light to the molybdenum oxide nanostructure and palladium catalyst to form an MoO3—Pd nanocomposite

Methodology Applied
Scientific EffectPhotochemical reaction: Photodissociation

Implementation Method 3

the ability of the catalyst particles to decompose hydrogen molecules into atoms by reacting with oxygen or water steam

Methodology Applied
Scientific EffectCatalysis: Catalysis

Data Source

PatentUS10094811B2Color changeable hydrogen detection sensor based on molybdenum oxide and method of manufacturing the same
Publication Date: 2018.10.09 HYUNDAI MOTOR CO LTD
  • US10094811B2 patent drawing
  • US10094811B2 patent drawing
  • US10094811B2 patent drawing

AI summary

Disclosed are a hydrogen detection sensor and a method of manufacturing the same. The hydrogen detection sensor is manufactured by using hydrothermal synthesis method to synthesize a molybdenum oxide (MoO3) nanostructure, and irradiating UV light thereon to form an MoO3—Pd nanocomposite comprising the molybdenum oxide nanostructure with palladium (Pd) catalyst particles, and coating the MoO3—Pd nanocomposite on a substrate. As such, a visible color change from the MoO3 before and after exposure to hydrogen may be so obvious that the sensing or sensitivity of hydrogen and the long-term stability may be substantially improved. In addition, the manufacturing process is simple, and the manufacturing costs may be reduced.