MOSFET Interfacial Oxide Layer Threshold Voltage Modulation

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Solution Overview

Problem

The production of MOSFETs and CMOSFETs is complicated by the need to form gate electrodes with optimum threshold voltages, leading to increased production costs and efficiency losses.

Innovation Solution

Incorporating third elements, such as Al and Ge, into the interfacial oxide and high-k dielectric layers of MOSFETs, with peak doping densities located below the high-k/interfacial oxide interface, to modulate the threshold voltage through simpler procedures.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Reliability

If gate electrodes with optimum threshold voltages are formed according to device structure and conductivity types, then device performance is improved, but production process complexity and costs increase

Engineering Contradiction:
Improvedevice performanceVSAvoidproduction process complexity
Core Design Contradiction:
ReliabilityVSDevice complexity

Solution Approach 1:

The patent applies parameter changes by modifying the doping concentration and depth parameters of the interfacial oxide layer to achieve different threshold voltages. By controlling the peak doping concentration (e.g., 1×10^19 to 1×10^21 atoms/cm³) and peak depth (e.g., 0.5 nm to 5 nm below the high-k/interfacial oxide interface), the work function of the gate electrode is adjusted, enabling threshold voltage optimization without adding process steps.

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent implements preliminary action by incorporating dopants into the interfacial oxide layer during the gate dielectric formation process, before gate electrode deposition. This preliminary doping establishes the desired threshold voltage characteristics in advance, eliminating the need for subsequent gate electrode modification steps and simplifying the overall production process.

Inventive Principle:
Principle #10Preliminary action

2Manufacturing precision

If conventional doping methods are used to modulate threshold voltage, then threshold voltage control is achieved, but dosing amount and process complexity increase

Engineering Contradiction:
Improvethreshold voltage controlVSAvoiddosing amount
Core Design Contradiction:
Manufacturing precisionVSQuantity of substance

Solution Approach 1:

The patent applies local quality by concentrating dopants at a specific depth within the interfacial oxide layer rather than uniform distribution. The peak doping concentration is localized at a controlled depth (e.g., 1 nm to 10 nm below the high-k/interfacial oxide interface), creating a localized region that efficiently modulates the work function with minimal total dopant dosage while achieving precise threshold voltage control.

Inventive Principle:
Principle #3Local quality

Solution Approach 2:

The patent replaces conventional mechanical doping methods (such as ion implantation requiring high doses) with a chemical vapor deposition-based doping approach. By incorporating dopants during the atomic layer deposition or chemical vapor deposition of the interfacial oxide layer, the process achieves efficient doping with lower dosing amounts and reduced process complexity.

Inventive Principle:
Principle #28Mechanics substitution (Replace mechanical system)

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

This approach allows for enhanced threshold voltage modulation with improved device performance, reducing the complexity and cost of producing MOSFETs and CMOSFETs by enabling easier work function modulation with less dosing compared to conventional methods.

Implementation Method 1

an interfacial oxide layer (IL) formed on the channel region into which at least one element disparate from Si, O, or N is incorporated at a peak concentration greater than 1×10^19 atoms/cm2

Methodology Applied
Scientific EffectDoping: Dopants

Data Source

PatentUS8217440B2Semiconductor device and method of fabricating the same
Publication Date: 2012.07.10 KIOXIA CORP
  • US8217440B2 patent drawing
  • US8217440B2 patent drawing
  • US8217440B2 patent drawing

AI summary

MOSFETs and methods of making MOSFETs are provided. According to one embodiment, a semiconductor device includes a substrate and a Metal-Oxide-Semiconductor (MOS) transistor that includes a semiconductor region formed on the substrate, a source region and drain region formed in the semiconductor region that are separated from each other, a channel region formed in the semiconductor region that separates the source region and the drain region, an interfacial oxide layer (IL) formed on the channel region into which at least one element disparate from Si, O, or N is incorporated at a peak concentration greater than 1×1019 atoms/cm2, and a high-k dielectric layer formed on the interfacial oxide layer having a high-k/IL interface at a depth substantially adjacent to the IL. In addition, at least one depth of peak density of the incorporated element(s) is located substantially below the high-k/IL interface.