Metal-Organic Framework Filter Hot-Pressing Production

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Solution Overview

Problem

Current methods for preparing metal-organic framework filters face challenges such as long production cycles, low yields, high production costs, and limited batch production capacity, making them inefficient and costly.

Innovation Solution

A hot-pressing method is employed to mix metal sources with organic ligands, forming a metal-organic framework filter on substrates, using specific metal ions and coordination functional groups, with adjustable hot-pressing conditions and additives like polyvinyl alcohol or polyethylene glycol, to achieve rapid and high-purity production.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Ease of operation

If in-situ growth method is used, then operation simplicity is improved, but production time increases and production efficiency decreases

Engineering Contradiction:
Improveoperation simplicityVSAvoidproduction efficiency
Core Design Contradiction:
Ease of operationVSProductivity

Solution Approach 1:

The patent applies preliminary action by pre-modifying the substrate surface with organic groups before the actual metal-organic framework growth. This pre-treatment step enables faster subsequent growth while maintaining operational simplicity, thus resolving the contradiction between ease of operation and production efficiency.

Inventive Principle:
Principle #10Preliminary action

Solution Approach 2:

The patent uses organic groups as an intermediary substance that facilitates the interaction between the substrate and metal ions. This intermediary enables controlled and accelerated framework formation, improving production efficiency while keeping the process simple to operate.

Inventive Principle:
Principle #24Intermediary (Mediator)

2Manufacturing precision

If LBL deposition method is used, then product purity is improved, but processing time increases and production efficiency decreases

Engineering Contradiction:
Improveproduct purityVSAvoidproduction efficiency
Core Design Contradiction:
Manufacturing precisionVSProductivity

Solution Approach 1:

The patent merges the advantages of LBL deposition (high purity) with in-situ growth (simplicity) by combining surface pre-modification with subsequent metal-organic framework growth in a unified process. This achieves high purity products with reduced processing time, resolving the contradiction between manufacturing precision and productivity.

Inventive Principle:
Principle #5Merging (Combining)

3Reliability

If crystal-seed method is used, then membrane defect reduction is improved, but production time increases and production efficiency decreases

Engineering Contradiction:
Improvemembrane qualityVSAvoidproduction efficiency
Core Design Contradiction:
ReliabilityVSProductivity

Solution Approach 1:

The patent applies preliminary action by pre-modifying the substrate surface with organic groups that serve as nucleation sites. This preliminary preparation promotes uniform crystal growth and reduces defects while shortening the overall production time, thus resolving the contradiction between reliability and productivity.

Inventive Principle:
Principle #10Preliminary action

4Speed

If ultrasonic chemistry method is used, then reaction speed is improved, but product purity decreases and production efficiency remains limited

Engineering Contradiction:
Improvereaction speedVSAvoidproduct purity
Core Design Contradiction:
SpeedVSManufacturing precision

Solution Approach 1:

The patent replaces the mechanical ultrasonic treatment with a chemically-driven approach using surface-modified substrates and controlled coordination reactions. This substitution achieves fast reaction speeds through chemical mechanisms while maintaining high product purity, resolving the contradiction between speed and manufacturing precision.

Inventive Principle:
Principle #28Mechanics substitution (Replace mechanical system)

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

This method enables the rapid and cost-effective production of high-purity metal-organic framework filters with a porous mesh structure, overcoming the limitations of existing methods by simplifying operations and scaling up production efficiently.

Implementation Method 1

metal-organic frameworks consist of metal clusters or metal ions and organic ligands by coordination effect

Methodology Applied
Scientific EffectCoordination effect: Chemical Bonding

Implementation Method 2

forming a metal-organic framework filter on substrates by a hot-pressing method

Methodology Applied
Scientific EffectHot-pressing: Heating

Data Source

PatentUS11395991B2Metal-organic framework filter and preparation method thereof
Publication Date: 2022.07.26 ZHONGNENG KETAI BEIJING TECH CO LTD
  • US11395991B2 patent drawing
  • US11395991B2 patent drawing
  • US11395991B2 patent drawing

AI summary

The present disclosure discloses a method for preparing a metal-organic framework filter comprising the steps of bringing metal sources into contact with organic ligands and forming a metal-organic framework filter on substrates by a hot-pressing method. By the method of the present disclosure, a large amount of metal-organic framework filters with high purity can be obtained quickly and easily, thereby realizing industrialized production and application and the method has such advantages as low cost, simple operation, rapid production, batch product and high purity.