MOx Gas Sensor Ozone Interference Reduction via Temperature Cycling

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Solution Overview

Problem

Gas sensors using metal oxide (MOx) chemiresistors struggle to accurately measure volatile organic compounds (VOCs) due to interference from ozone, leading to shifted baselines and underreporting of indoor air quality (IAQ) and TVOC levels.

Innovation Solution

A method and system that control the temperature of the MOx sensor by initially setting it to a low temperature to reduce ozone concentration, then increasing it to an operating temperature for data acquisition, and processing the resistance data to minimize ozone interference, using a heater driver and processor to manage the temperature and data processing.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Measurement precision

If the MOx sensor is heated to high operating temperature continuously, then the sensor can detect VOCs effectively, but ozone interference increases causing baseline shifts and measurement errors

Engineering Contradiction:
ImproveVOC detection accuracyVSAvoidozone interference
Core Design Contradiction:
Measurement precisionVSObject-affected harmful factors

Solution Approach 1:

The patent implements periodic temperature cycling where the heater alternates between high temperature (for VOC detection) and low temperature (for ozone reduction). This periodic action allows the sensor to achieve both accurate VOC measurement and ozone interference reduction by switching between operational states at different temperatures.

Inventive Principle:
Principle #19Periodic action

Solution Approach 2:

The patent applies preliminary action by reducing ozone concentration through low-temperature operation before performing VOC measurements at high temperature. This preparatory step eliminates the harmful ozone interference in advance, ensuring that subsequent measurements are not affected by baseline shifts or false readings.

Inventive Principle:
Principle #10Preliminary action

2Speed

If the sensor operates continuously at high temperature, then response time to VOC changes is fast, but energy consumption increases and ozone reactions are enhanced

Engineering Contradiction:
Improveresponse timeVSAvoidheater power consumption
Core Design Contradiction:
SpeedVSUse of energy by moving object

Solution Approach 1:

The patent uses periodic temperature cycling to alternate between high-temperature measurement phases (providing fast VOC response) and low-temperature energy-saving phases (reducing power consumption and ozone formation). This approach maintains measurement capability while reducing overall energy consumption compared to continuous high-temperature operation.

Inventive Principle:
Principle #19Periodic action

Solution Approach 2:

The patent maintains continuous monitoring capability by rapidly cycling between temperature states, ensuring that the sensor is ready to detect VOC changes at any time while minimizing the duration of high-power consumption states. The continuous operation at reduced power levels with periodic measurement bursts achieves both energy efficiency and responsiveness.

Inventive Principle:
Principle #20Continuity of useful action

3Object-affected harmful factors

If low temperature is maintained to reduce ozone, then ozone interference is minimized, but VOC detection sensitivity decreases

Engineering Contradiction:
Improveozone interferenceVSAvoidVOC detection sensitivity
Core Design Contradiction:
Object-affected harmful factorsVSMeasurement precision

Solution Approach 1:

The patent periodically switches between low-temperature ozone-reduction mode and high-temperature VOC-detection mode. During low-temperature phases, ozone interference is minimized; during high-temperature phases, VOC detection sensitivity is maximized. This temporal separation allows both requirements to be satisfied at different times in the operational cycle.

Inventive Principle:
Principle #19Periodic action

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

This approach effectively reduces ozone interference, allowing for accurate VOC and IAQ measurements by isolating ozone reactions at low temperatures, thereby improving the reliability of gas concentration readings.

Implementation Method 1

setting power to a heater in contact with a MOx sensor to provide a temperature

Methodology Applied
Scientific EffectJoule heating: Joule Heating

Implementation Method 2

The resistance of the MOx resistor is sensitive to impurity gas concentrations in the air. The change in resistance from a baseline is based on gas type and concentration

Methodology Applied
Scientific EffectChemical reaction: Chemical Bonding

Data Source

PatentUS11674940B2System and method to avoid the influence of ozone for a gas sensor
Publication Date: 2023.06.13 RENESAS ELECTRONICS AMERICA INC
  • US11674940B2 patent drawing
  • US11674940B2 patent drawing
  • US11674940B2 patent drawing

AI summary

In some embodiments, a method of operating a gas sensor includes setting power to a heater in contact with a MOx sensor to provide a temperature that is below a threshold temperature; holding the temperature below the threshold temperature for a period of time to reduce ozone concentration in a gas sample in contact with the MOx sensor; increasing power to the heater to increase the temperature of the MOx sensor to an operating temperature; acquiring resistance data from the MOx sensor at the operating temperature; and processing the resistance data to provide a result related the gas sample.