MRAM Cap Structure With Alternating Layers for Higher TMR

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Solution Overview

Problem

Magnetoresistive memory devices face challenges in achieving improved electrical characteristics and reliability due to limitations in the cap structure design, which affects the tunneling magneto-resistance ratio and coercivity distribution.

Innovation Solution

A magnetoresistive memory device is designed with a cap structure comprising alternately layered non-magnetic and magnetic material layers, forming a multilayer oxide structure that is thicker than the upper magnetic material layer, enhancing oxidation control and forming a uniform amorphous oxide film, thereby improving interfacial vertical anisotropy and coercivity distribution.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Reliability

If a conventional cap structure is used, then the device structure is simple, but the tunneling magneto-resistance ratio is insufficient and coercivity distribution is poor

Engineering Contradiction:
Improvetunneling magneto-resistance ratioVSAvoidcap structure complexity
Core Design Contradiction:
ReliabilityVSDevice complexity

Solution Approach 1:

The cap structure is divided into multiple alternating layers of non-magnetic material and magnetic material, with each layer having specific thickness ranges. This segmentation allows independent optimization of each layer's properties to achieve uniform amorphous oxide film formation and improved interfacial vertical anisotropy, resolving the contradiction between structural complexity and performance improvement

Inventive Principle:
Principle #1Segmentation

Solution Approach 2:

The cap structure uses composite materials consisting of non-magnetic material layers and magnetic material layers alternately stacked. This composite structure enables the formation of uniform amorphous oxide films at interfaces while controlling oxidation, achieving both improved tunneling magneto-resistance ratio and coercivity distribution without excessive complexity

Inventive Principle:
Principle #40Composite materials

2Manufacturing precision

If the cap structure thickness is increased, then the amorphous oxide film uniformity is improved, but the manufacturing process complexity increases

Engineering Contradiction:
Improveamorphous oxide film uniformityVSAvoidcap structure thickness control
Core Design Contradiction:
Manufacturing precisionVSDevice complexity

Solution Approach 1:

Specific thickness parameters are defined for each layer in the cap structure (non-magnetic material layers: 1-5 nm, magnetic material layers: 1-3 nm, total cap structure thickness: 5-20 nm). These parameter specifications ensure uniform amorphous oxide film formation while providing clear manufacturing guidelines to control complexity

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The cap structure is designed with predetermined layer configurations and thickness ranges before the oxidation process. This preliminary design ensures that when oxidation occurs, uniform amorphous oxide films form automatically at the interfaces, reducing the need for post-process adjustments and simplifying manufacturing

Inventive Principle:
Principle #10Preliminary action

3Reliability

If oxidation is enhanced to form uniform amorphous oxide film, then the interfacial vertical anisotropy is improved, but the process complexity increases

Engineering Contradiction:
Improveinterfacial vertical anisotropyVSAvoidoxidation process control
Core Design Contradiction:
ReliabilityVSEase of manufacture

Solution Approach 1:

The alternating non-magnetic and magnetic material layers in the cap structure self-organize during oxidation to form uniform amorphous oxide films at the interfaces. The specific material composition and thickness ratios enable spontaneous formation of the desired oxide structure without complex process control, improving interfacial vertical anisotropy while maintaining manufacturing ease

Inventive Principle:
Principle #25Self-service

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The solution increases the tunneling magneto-resistance ratio and decreases parallel resistance, leading to enhanced electrical characteristics and reliability of the magnetoresistive memory device.

Implementation Method 1

oxidizing at least one of the non-magnetic material layers and the magnetic material layers

Methodology Applied
Scientific EffectOxidation: Oxidation

Implementation Method 2

forming a uniform amorphous oxide film

Methodology Applied
Scientific EffectAmorphous oxide film formation: Vitrification

Implementation Method 3

A resistance value of the magnetic tunnel junction pattern may be changed according to magnetization directions of the two magnetic materials

Methodology Applied
Scientific EffectMagnetoresistance: Magnetoresistance

Data Source

PatentUS20230371392A1Magnetoresistive memory device and semiconductor device including the same
Publication Date: 2023.11.16 SAMSUNG ELECTRONICS CO LTD
  • US20230371392A1 patent drawing
  • US20230371392A1 patent drawing
  • US20230371392A1 patent drawing

AI summary

A magnetoresistive memory device includes: a lower electrode; a lower magnetic material layer on the lower electrode; a tunnel barrier layer on the lower magnetic material layer; an upper magnetic material layer on the tunnel barrier layer; a cap structure, on the upper magnetic material layer, including first layers and second layers, alternately layered; a cap conductive layer on the cap structure; and an upper electrode on the cap conductive layer, wherein the first layers include a first material including a non-magnetic material, and the second layers include a second material including a magnetic material.