MRAM MTJ Capping Structure for Impurity Diffusion Blocking

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Solution Overview

Problem

The challenge in manufacturing magnetoresistive random access memory (MRAM) devices is preventing impurities from diffusing into the magnetic tunneling junction (MTJ), which can cause abnormal tunneling magnetoresistance and affect the device's functionality.

Innovation Solution

The solution involves a magnetic memory device structure with a bottom electrode layer, a magnetic tunneling junction (MTJ) stack, a capping layer with a diffusion barrier, and a top electrode layer, where the capping layer includes a MgO layer and a TaN layer, and optionally a RuO2 diffusion barrier layer, and the top electrode layer comprises RuO2, further enhanced with a hard mask layer of TiN.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Reliability

If conventional manufacturing processes are used for MRAM devices, then the manufacturing process is simple, but impurities diffuse into the MTJ causing abnormal tunneling magnetoresistance

Engineering Contradiction:
Improvetunneling magnetoresistance stabilityVSAvoidmanufacturing process complexity
Core Design Contradiction:
ReliabilityVSDevice complexity

Solution Approach 1:

A capping layer structure comprising MgO, TaN, and RuO2 layers is introduced as an intermediary barrier between the MTJ and the top electrode. This multi-layer structure acts as a mediator that selectively blocks impurity diffusion (particularly Ru atoms) into the MTJ while maintaining manufacturing feasibility through standard semiconductor processes

Inventive Principle:
Principle #24Intermediary (Mediator)

Solution Approach 2:

The capping layer employs a composite structure combining MgO (magnetic field shielding), TaN (diffusion barrier), and RuO2 (oxidation resistance and diffusion barrier) materials. Each material contributes specific properties that collectively prevent impurity diffusion into the MTJ, ensuring stable tunneling magnetoresistance

Inventive Principle:
Principle #40Composite materials

2Reliability

If impurity diffusion is prevented using multiple barrier layers, then tunneling magnetoresistance stability is improved, but the device structure becomes more complex

Engineering Contradiction:
ImproveMTJ integrityVSAvoidlayer structure complexity
Core Design Contradiction:
ReliabilityVSDevice complexity

Solution Approach 1:

The capping layer is segmented into three distinct functional layers: MgO for magnetic field shielding, TaN for diffusion barrier, and RuO2 for oxidation resistance and additional diffusion barrier. This segmentation allows each layer to perform its specific function efficiently while maintaining overall structural organization

Inventive Principle:
Principle #1Segmentation

Solution Approach 2:

The RuO2 layer serves multiple functions simultaneously: it acts as a diffusion barrier to prevent Ru atom migration, provides oxidation resistance to protect underlying layers, and contributes to the overall structural integrity of the capping layer. This multi-functionality reduces the need for additional dedicated layers

Inventive Principle:
Principle #6Universality (Multi-functionality)

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

This configuration effectively prevents impurity diffusion, ensuring stable tunneling magnetoresistance and improving the reliability and performance of the MRAM device by blocking the diffusion of atoms like Ru, Ti, and N, thereby maintaining the integrity of the MTJ.

Implementation Method 1

the top electrode layer comprises RuO2... the capping layer comprises a diffusion barrier layer between the TaN layer and the MgO layer... the diffusion barrier layer comprises a RuO2 layer

Methodology Applied
Scientific EffectDiffusion barrier: Diffusion Barrier

Data Source

PatentUS20240057483A1Magnetic memory device and fabrication method thereof
Publication Date: 2024.02.15 UNITED MICROELECTRONICS CORP
  • US20240057483A1 patent drawing
  • US20240057483A1 patent drawing
  • US20240057483A1 patent drawing

AI summary

A magnetic memory device includes a bottom electrode layer, a magnetic tunneling junction (MTJ) stack disposed on the bottom electrode layer, a capping layer disposed on the MTJ stack, and a top electrode layer disposed on the capping layer. The top electrode layer comprises RuO2.