MTJ Bottom Electrode Width Reduction for Etching Damage Control

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Solution Overview

Problem

Current magnetic tunnel junction (MTJ) devices face challenges in etching processes, particularly at tight pitches, where ion beam etching (IBE) and chemical etching in reactive ion etching (RIE) lead to damage zones and metal redeposition, affecting tunnel magnetoresistance ratio and energy barrier variations, thus limiting downscaling in high-density MRAMs.

Innovation Solution

The solution involves reducing the width of the bottom electrode to be less than the MTJ stack pillar and embedding a metal seed layer within the bottom electrode to minimize metal redeposition during etching, thereby reducing the height of the MTJ stack pillar and avoiding over-etching of the bottom electrode, which helps in preventing metal shorts across the tunnel barrier.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Productivity

If ion beam etching (IBE) and chemical etching in reactive ion etching (RIE) are used to etch MTJ devices at tight pitches, then the etching process can be completed, but metal redeposition occurs on the MTJ stack pillar causing damage zones and affecting tunnel magnetoresistance ratio

Engineering Contradiction:
Improveetching process completionVSAvoidtunnel magnetoresistance ratio
Core Design Contradiction:
ProductivityVSManufacturing precision

Solution Approach 1:

The patent extracts the bottom electrode from the etching process by making it narrower than the MTJ stack pillar, so that the bottom electrode is not etched during the over-etching step. This prevents metal redeposition on the MTJ stack pillar while still completing the necessary etching of the MTJ stack and isolation structures.

Inventive Principle:
Principle #2Taking out (Extraction)

Solution Approach 2:

The patent introduces a spacer layer as an intermediary between the bottom electrode and the MTJ stack pillar. The spacer layer protects the bottom electrode from etching and prevents metal redeposition, while allowing the etching process to complete the MTJ stack formation and isolation.

Inventive Principle:
Principle #24Intermediary (Mediator)

2Manufacturing precision

If the bottom electrode width is reduced to prevent metal redeposition, then tunnel barrier integrity is maintained, but the electrical connection area is reduced

Engineering Contradiction:
Improvetunnel barrier integrityVSAvoidelectrical connection area
Core Design Contradiction:
Manufacturing precisionVSQuantity of substance

Solution Approach 1:

The patent extracts the bottom electrode from the etching process by making it narrower, which maintains tunnel barrier integrity by preventing metal redeposition. The electrical connection area is sufficient for device operation while the narrower width prevents redeposition issues.

Inventive Principle:
Principle #2Taking out (Extraction)

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

This approach effectively reduces metal redeposition and etching damage, enhancing the reliability and scalability of MTJ devices by minimizing the redeposition of metal material during the etching process, thus maintaining the integrity of the tunnel barrier and improving the performance of MRAMs.

Implementation Method 1

ion beam etching (IBE)

Methodology Applied
Scientific EffectIon beam etching: Ion Beam

Implementation Method 2

chemical etching in reactive ion etching (RIE)

Methodology Applied
Scientific EffectChemical etching: Chemical Bonding

Data Source

PatentEP3472875B1Reducing or avoiding metal deposition from etching magnetic tunnel junction (MTJ) devices, including magnetic random access memory (MRAM) devices
Publication Date: 2020.10.21 QUALCOMM INC
  • EP3472875B1 patent drawingFigure 1
  • EP3472875B1 patent drawingFigure 2
  • EP3472875B1 patent drawingFigure 3

AI summary

Aspects disclosed include reducing or avoiding metal deposition from etching magnetic tunnel junction (MTJ) devices. In one example, a width of a bottom electrode of an MTJ device is provided to be less than a width of the MTJ stack of the MTJ device. In this manner, etching of the bottom electrode may be reduced or avoided to reduce or avoid metal redeposition as a result of over-etching the MTJ device to avoid horizontal shorts between an adjacent device(s). In another example, a seed layer is embedded in a bottom electrode of the MTJ device. In this manner, the MTJ stack is reduced in height to reduce or avoid metal redeposition as a result of over-etching the MTJ device. In another example, an MTJ device includes an embedded seed layer in a bottom electrode which also has a width less than a width of the MTJ stack.