Magnetic Tunnel Junctions with Composite Fixed Layers for MRAM

Resolve Bottlenecks,
Find Innovative Solutions
Generate Solutions

Solution Overview

Problem

Magnetoresistive random access memory (MRAM) devices with perpendicular magnetic anisotropy (PMA) face challenges in read operations due to low magnetoresistance and increased fixed layer dipolar fields, which affect the bistability and switching mode of magnetic tunnel junctions (MTJs) as they are scaled down.

Innovation Solution

Incorporating a composite fixed layer, synthetic antiferromagnetic (SAF) structure, and dipole layer in the magnetic stack of MTJs to reduce the fixed layer dipolar field and free layer loop offset, thereby enhancing the magnetoresistance and maintaining bistability across the full temperature range.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Use of energy by moving object

If PMA materials are used in MTJs, then write current density is reduced, but magnetoresistance becomes low due to structural and chemical incompatibility between material layers

Engineering Contradiction:
Improvewrite current densityVSAvoidmagnetoresistance
Core Design Contradiction:
Use of energy by moving objectVSReliability

Solution Approach 1:

The patent employs composite material structures including CoFeB/MgO/CoFeB tunnel junctions with specific layer compositions and thicknesses. The composite structure of perpendicular magnetization layers combined with tunnel barrier layers creates both the desired PMA for low write current and sufficient magnetoresistance for reliable read operations

Inventive Principle:
Principle #40Composite materials

Solution Approach 2:

The patent optimizes various parameters including layer thicknesses (e.g., 3-5 nm for CoFeB layers, 1-2 nm for MgO barrier), material compositions, and thermal treatment parameters to achieve the balance between PMA and magnetoresistance. By carefully controlling these parameters, the device achieves both low write current density and high magnetoresistance ratio

Inventive Principle:
Principle #35Parameter changes

2Use of energy by moving object

If MTJ size is reduced to lower write current, then write current decreases, but fixed layer dipolar field increases and affects bistability

Engineering Contradiction:
Improvewrite currentVSAvoidbistability
Core Design Contradiction:
Use of energy by moving objectVSStability of the object's composition

Solution Approach 1:

The patent introduces non-magnetic spacer layers (e.g., Ru, Ta, or MgO layers 0.5-2 nm thick) between the fixed layer and adjacent layers. These intermediary layers act as magnetic shields that reduce the dipolar field coupling between the fixed layer and free layer, thereby maintaining bistability in scaled-down devices

Inventive Principle:
Principle #24Intermediary (Mediator)

Solution Approach 2:

The magnetic stack is segmented into distinct functional layers with non-magnetic spacers separating magnetic layers. This segmentation isolates the fixed layer's dipolar field from affecting the free layer, allowing independent optimization of each layer's properties while maintaining overall device functionality at small dimensions

Inventive Principle:
Principle #1Segmentation

3Ease of operation

If fixed layer dipolar field is strong, then magnetization switching is affected, but reducing MTJ size increases the dipolar field impact

Engineering Contradiction:
Improvemagnetization switchingVSAvoidfixed layer dipolar field
Core Design Contradiction:
Ease of operationVSObject-affected harmful factors

Solution Approach 1:

Non-magnetic spacer layers are positioned between the fixed layer and other magnetic layers to mediate and reduce the dipolar field interaction. These spacers attenuate the harmful dipolar field while allowing the fixed layer to maintain its magnetization direction for read operations

Inventive Principle:
Principle #24Intermediary (Mediator)

Solution Approach 2:

The patent utilizes the dipolar field from the fixed layer in a controlled manner by designing the stack structure so that the dipolar field primarily affects the tunnel barrier and free layer magnetization switching in a beneficial way, while the harmful effects are minimized through spacer layers and geometric configuration

Inventive Principle:
Principle #22Blessing in disguise (Convert harm into benefit)

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The solution results in MTJs with high magnetoresistance and reduced fixed layer dipolar fields, ensuring stable resistance states and improved read operations in MRAM devices, even as they are miniaturized.

Implementation Method 1

Magnetic stacks with perpendicular magnetic anisotropy for spin momentum transfer magnetoresistive random access memory

Methodology Applied
Scientific EffectPerpendicular magnetic anisotropy: Anisotropy

Implementation Method 2

MRAM is a type of solid state memory that uses tunneling magnetoresistance (MR) to store information

Methodology Applied
Scientific EffectTunneling magnetoresistance: Magnetoresistance

Implementation Method 3

The magnetization state of the free layer may be changed by a spin torque switched (STT) write method, in which a write current is applied

Methodology Applied
Scientific EffectSpin torque:

Implementation Method 4

Incorporating a composite fixed layer, synthetic antiferromagnetic (SAF) structure, and dipole layer in the magnetic stack of MTJs to reduce the fixed layer dipolar field

Methodology Applied
Scientific EffectSynthetic antiferromagnetic coupling:

Data Source

PatentUS8866207B2Magnetic stacks with perpendicular magnetic anisotropy for spin momentum transfer magnetoresistive random access memory
Publication Date: 2014.10.21 INTERNATIONAL BUSINESS MACHINE CORPORATION
  • US8866207B2 patent drawing
  • US8866207B2 patent drawing
  • US8866207B2 patent drawing

AI summary

A magnetic tunnel junction (MTJ) includes a magnetic free layer, having a variable magnetization direction; an insulating tunnel barrier located adjacent to the free layer; a magnetic fixed layer having an invariable magnetization direction, the fixed layer disposed adjacent the tunnel barrier such that the tunnel barrier is located between the free layer and the fixed layer, wherein the free layer and the fixed layer have perpendicular magnetic anisotropy; and one or more of: a composite fixed layer, the composite fixed layer comprising a dusting layer, a spacer layer, and a reference layer; a synthetic antiferromagnetic (SAF) fixed layer structure, the SAF fixed layer structure comprising a SAF spacer located between the fixed layer and a second fixed magnetic layer; and a dipole layer, wherein the free layer is located between the dipole layer and the tunnel barrier.