MTJ Formation Two-Step Etching Tantalum Layer Integrity

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Solution Overview

Problem

Current manufacturing methods for magnetic random access memory (MRAM) face challenges in producing scalable and reliable magneto tunnel junctions (MTJs) due to the thinning of the tantalum layer, leading to defective elements and shorting of the fixed and free layers.

Innovation Solution

A method involving multiple etching steps using photo-resists to define and maintain the width and length of layers in a MTJ stack, ensuring a sufficient tantalum layer thickness for reliable connection, with optional use of a nitride layer for protection and etching with specific gases like CF4 and C2H5OH to maintain layer integrity.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Ease of manufacture

If the tantalum layer thickness is reduced to meet manufacturing limitations, then the device can be manufactured with current processes, but the connection reliability deteriorates and shorting occurs between fixed and free layers

Engineering Contradiction:
ImprovemanufacturabilityVSAvoidconnection reliability
Core Design Contradiction:
Ease of manufactureVSReliability

Solution Approach 1:

The patent divides the single etching process into two separate etching steps: a first etching step that creates initial openings through the oxide layer, and a second etching step that completes the openings through the tantalum layer. This segmentation allows each step to be optimized independently, ensuring complete penetration while maintaining proper layer thicknesses, thereby preventing shorting while achieving manufacturability.

Inventive Principle:
Principle #1Segmentation

Solution Approach 2:

The first etching step performs preliminary action by creating openings through the oxide layer before the second etching step completes the openings through the tantalum layer. This preliminary action ensures that the etching process is properly initiated and positioned, allowing the second step to complete penetration reliably without requiring excessive reduction of tantalum layer thickness.

Inventive Principle:
Principle #10Preliminary action

2Productivity

If the tantalum layer thickness is reduced, then manufacturing can proceed with current capabilities, but defective MRAM elements are produced

Engineering Contradiction:
Improvemanufacturing throughputVSAvoidelement quality
Core Design Contradiction:
ProductivityVSReliability

Solution Approach 1:

By segmenting the etching process into two distinct steps with different target depths, the patent enables complete penetration through the tantalum layer without requiring the layer to be excessively thin. This maintains element quality and reduces defects while allowing manufacturing to proceed with standard layer thicknesses and capabilities.

Inventive Principle:
Principle #1Segmentation

3Device complexity

If a single etching step is used, then the manufacturing process is simpler, but complete penetration through the oxide and tantalum layers cannot be achieved

Engineering Contradiction:
Improveprocess complexityVSAvoidetching penetration
Core Design Contradiction:
Device complexityVSManufacturing precision

Solution Approach 1:

The patent segments the etching process into two steps: the first etching step targets penetration through the oxide layer to a controlled depth, and the second etching step completes the penetration through the tantalum layer. This segmentation achieves complete penetration precision that would be difficult to obtain in a single step, while the added process step is justified by the significant improvement in etching precision and reliability.

Inventive Principle:
Principle #1Segmentation

Solution Approach 2:

The first etching step performs preliminary action by creating openings through the oxide layer, establishing the correct position and depth before the second etching step completes penetration through the tantalum layer. This preliminary action ensures precise control over the etching process, achieving complete penetration while maintaining manufacturing precision.

Inventive Principle:
Principle #10Preliminary action

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

This approach results in a significantly larger and more reliable tantalum contact layer, enhancing the connection of MTJs to external circuits and reducing the risk of shorting, while maintaining low switching current levels.

Implementation Method 1

An oxide layer is first etched, using a first photo-resist, to leave a portion of the oxide layer

Methodology Applied
Scientific EffectEtching:

Implementation Method 2

a second photo-resist is deposited on top of and around the portion of the oxide layer

Methodology Applied
Scientific EffectDeposition: Deposition (physical)

Implementation Method 3

a second etching step is performed on the MTJ stack, using the second photo-resist, to leave a portion of the contact layer, a portion of the free layer and a portion of the barrier layer

Methodology Applied
Scientific EffectEtching:

Implementation Method 4

A third etching is performed of the MTJ stack, using the portion of the oxide layer, to leave a second portion of the contact layer, a second portion of the free layer and a second portion of the barrier layer

Methodology Applied
Scientific EffectEtching:

Data Source

PatentUS8148174B1Magnetic tunnel junction (MTJ) formation with two-step process
Publication Date: 2012.04.03 AVALANCHE TECHNOLOGY INC
  • US8148174B1 patent drawing
  • US8148174B1 patent drawing
  • US8148174B1 patent drawing

AI summary

A method of manufacturing a magnetic memory element includes the steps of performing a first etching an oxide layer is etched, using a first photo-resist, the oxide layer formed on top of a contact layer that is formed on top of a magneto tunnel junction (MTJ), depositing a second photo-resist and second etching to leave a portion of the contact layer used to suitably connect the MTJ to circuits outside of the magnetic memory element.