Mud Gas Chromatography for Natural vs Cracked Hydrocarbon Differentiation

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Solution Overview

Problem

The petroleum industry faces challenges in accurately determining the presence and severity of hydrocarbon cracking during drilling operations, which can lead to false positives in hydrocarbon detection and affect reservoir evaluation and production decisions.

Innovation Solution

A method is developed to collect and analyze mud gas samples from drilling fluids to differentiate between natural and artificially-generated hydrocarbons by detecting concentrations of methane, ethane, and total C2 gases, and calculating differences between their logarithmic values, allowing for the determination of artifact gases and adjusting drilling parameters accordingly.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Measurement precision

If conventional mud gas analysis is used to detect hydrocarbons, then hydrocarbon presence can be identified, but false positives occur due to inability to distinguish natural from cracked hydrocarbons

Engineering Contradiction:
Improvehydrocarbon detection accuracyVSAvoidfalse positive rate
Core Design Contradiction:
Measurement precisionVSReliability

Solution Approach 1:

The patent segments the C2 hydrocarbon measurement into separate components (ethane and ethylene) and calculates their individual concentrations and ratios. This segmentation allows differentiation between natural hydrocarbons (higher ethane/ethylene ratio) and cracked hydrocarbons (lower ratio), resolving the false positive issue while maintaining detection accuracy.

Inventive Principle:
Principle #1Segmentation

Solution Approach 2:

The patent introduces a new parameter - the ethane/ethylene ratio - to distinguish between natural and cracked hydrocarbons. By changing the detection parameter from simple hydrocarbon presence to compositional ratio analysis, the system achieves both high measurement precision and reliability by identifying the characteristic compositional differences between the two hydrocarbon types.

Inventive Principle:
Principle #35Parameter changes

2Measurement precision

If detailed mud gas compositional analysis is performed, then differentiation between natural and cracked hydrocarbons is achieved, but measurement complexity increases

Engineering Contradiction:
Improvehydrocarbon type differentiationVSAvoidgas analysis system complexity
Core Design Contradiction:
Measurement precisionVSDevice complexity

Solution Approach 1:

The patent uses a single gas chromatograph instrument to perform multiple functions: measuring total hydrocarbons, separating and quantifying ethane and ethylene components, and calculating the differentiation ratio. This multi-functionality approach achieves detailed compositional analysis without proportionally increasing device complexity, as one instrument performs all necessary measurements.

Inventive Principle:
Principle #6Universality (Multi-functionality)

Solution Approach 2:

The patent performs preliminary separation of hydrocarbon components using gas chromatography before final quantification and ratio calculation. This preliminary action simplifies the subsequent measurement process by pre-separating the complex mixture into identifiable components, making the overall system more manageable while maintaining high differentiation precision.

Inventive Principle:
Principle #10Preliminary action

3Productivity

If real-time mud gas monitoring is implemented, then drilling efficiency is improved through timely adjustments, but operational complexity increases

Engineering Contradiction:
Improvedrilling efficiencyVSAvoidoperational complexity
Core Design Contradiction:
ProductivityVSEase of operation

Solution Approach 1:

The patent implements a feedback mechanism where real-time mud gas analysis results are continuously monitored and used to adjust drilling parameters. The ethane/ethylene ratio serves as an immediate indicator of cracking conditions, allowing operators to modify drilling parameters (such as rate of penetration or mud weight) to mitigate cracking while maintaining productivity. This automated feedback loop reduces operational complexity by providing clear, actionable guidance.

Inventive Principle:
Principle #23Feedback

Solution Approach 2:

The system performs self-service through automated gas chromatographic analysis and ratio calculation, eliminating the need for manual intervention in the measurement process. The instrument automatically separates, quantifies, and compares hydrocarbon components, providing real-time data for drilling adjustments without increasing operational complexity through automation rather than manual procedures.

Inventive Principle:
Principle #25Self-service

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

This method enables real-time monitoring and feedback to operators to mitigate hydrocarbon cracking, providing accurate hydrocarbon detection and improving drilling efficiency and reservoir evaluation by distinguishing between natural and artificially-generated hydrocarbons.

Implementation Method 1

a gas chromatograph to determine the concentration of ethane and the concentration of ethylene in the mud gas sample

Methodology Applied
Scientific EffectGas chromatography: Chromatography

Implementation Method 2

a mass spectrometer to determine the concentration of total C2 gases in the mud gas sample

Methodology Applied
Scientific EffectMass spectrometry:

Data Source

PatentUS11320414B2Method for differentiating between natural formation hydrocarbon and cracked hydrocarbon using mud gas measurements
Publication Date: 2022.05.03 SAUDI ARABIAN OIL CO
  • US11320414B2 patent drawing
  • US11320414B2 patent drawing
  • US11320414B2 patent drawing

AI summary

A method may include collecting a sample of mud gas during a wellbore drilling operation, associating the sample with a depth of the wellbore, and detecting concentrations of methane, ethane and ethylene. With the detected concentrations, a determination can be made as to the degree of a mud gas artifact event occurring, including determining the differences between the logarithmic values of concentrations of methane and total C2 concentration and the logarithmic values of total C2 concentration and ethane. A visually displayed mud gas log is modified to indicate the degree of the determined mud gas artifact event.