Multi-Bed PSA Cycle for Hydrogen Recovery and Compression Reduction

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Solution Overview

Problem

Current pressure swing adsorption (PSA) processes face challenges in reducing compression requirements, increasing hydrogen production and recovery, and lowering capital and operating costs, particularly in multi-bed systems for hydrogen production from gas mixtures like reformate streams.

Innovation Solution

The implementation of a PSA process utilizing multiple adsorption beds with specific cycles that include a combination of depressurizing and pressurizing equalization steps, purge steps, and repressurization steps, optimized to enhance hydrogen recovery and reduce costs by improving the efficiency of gas processing and bed utilization.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Productivity

If traditional PSA cycles are used with multiple adsorption beds, then hydrogen separation can be achieved, but compression requirements remain high and hydrogen recovery is limited

Engineering Contradiction:
Improvehydrogen recoveryVSAvoidcompression requirements
Core Design Contradiction:
ProductivityVSUse of energy by moving object

Solution Approach 1:

The PSA system is divided into multiple adsorption beds (at least two beds) that operate in parallel with different cycle phases. Each bed undergoes separate adsorption, depressurization, purge, and repressurization steps, allowing continuous hydrogen production while reducing the workload on compression systems by distributing the gas handling across multiple independent units.

Inventive Principle:
Principle #1Segmentation

Solution Approach 2:

The invention implements periodic cycling of the adsorption beds through distinct operational phases (adsorption at high pressure, depressurization to low pressure, purge, and repressurization). This periodic action creates pressure differentials that drive hydrogen transfer between beds without requiring continuous high-energy compression, thereby reducing overall compression requirements while maintaining high hydrogen recovery.

Inventive Principle:
Principle #19Periodic action

2Productivity

If more adsorption beds are added to increase hydrogen production, then productivity improves, but capital and operating costs increase

Engineering Contradiction:
Improvehydrogen productionVSAvoidnumber of beds
Core Design Contradiction:
ProductivityVSDevice complexity

Solution Approach 1:

The invention combines multiple functional operations (adsorption, depressurization, purge, and repressurization) into an integrated multi-bed system where beds share common piping and control systems. This merging approach allows the system to achieve high hydrogen production capacity while avoiding the proportional increase in capital costs that would result from completely independent bed operations, as infrastructure can be shared across all beds.

Inventive Principle:
Principle #5Merging (Combining)

Solution Approach 2:

Each adsorption bed is designed to perform multiple functions throughout its cycle: it acts as an adsorption column during the adsorption phase, a depressurization vessel during the depressurization phase, and a source of purified hydrogen during the product withdrawal phase. This multi-functionality allows a smaller number of beds to achieve higher productivity compared to specialized single-function configurations, thereby reducing both capital and operating costs.

Inventive Principle:
Principle #6Universality (Multi-functionality)

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

This approach enhances hydrogen recovery and reduces operational costs by optimizing the PSA cycle, allowing for more efficient hydrogen production and processing in multi-bed systems, thereby addressing the limitations of existing PSA technologies.

Implementation Method 1

a multicomponent gas is passed to at least one of multiple adsorption beds at an elevated pressure to adsorb at least one strongly sorbed component while at least one component passes through the adsorption bed

Methodology Applied
Scientific EffectAdsorption: Adsorption

Implementation Method 2

Pressure swing adsorption (PSA) processes are well-known for the separation of gas mixtures that contain components with different adsorbing characteristics

Methodology Applied
Scientific EffectPressure swing adsorption: Pressure Swing Adsorption

Data Source

PatentUS9381460B2Pressure swing adsorption process
Publication Date: 2016.07.05 AIR PROD & CHEM INC
  • US9381460B2 patent drawing
  • US9381460B2 patent drawing
  • US9381460B2 patent drawing

AI summary

A pressure swing adsorption process for an adsorption system having 12 adsorption beds, the process having a cycle with 5 pressure equalization steps. Background is provided for the various pressure swing adsorption cycle steps.