Multi-branched Surfactant for Synthetic Fiber Soil Release

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Solution Overview

Problem

Current soil release agents struggle to effectively remove soil and oil stains from textiles, particularly synthetic fibers, as they are hydrophobic and oleophilic, leading to redeposition of stains during washing and incomplete cleaning, resulting in textiles appearing gray or yellowish due to residual contaminants.

Innovation Solution

A multi-branched soil release/wetting agent comprising an oxygen-containing polyfunctional base compound with surfactant branches, including hydrophilic and hydrophobic constituents, is applied in an aqueous solution, enhancing cleanability and moisture management without using fluorochemicals, and can be added to fabric conditioners or used in dryer sheets for improved performance.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Reliability

If conventional soil release agents are used on synthetic fibers, then the fibers remain hydrophobic and oleophilic, but this causes oil and grime to be readily embedded in the fiber while preventing water from entering to remove contaminants

Engineering Contradiction:
Improvesoil release performanceVSAvoidcleanability
Core Design Contradiction:
ReliabilityVSEase of operation

Solution Approach 1:

The invention uses a composite soil release agent comprising a polyol backbone with multiple surfactant branches (including both anionic and nonionic surfactants). This composite structure combines the hydrophobicity needed for oil release with hydrophilic components that enable water penetration, resolving the contradiction between soil release performance and cleanability.

Inventive Principle:
Principle #40Composite materials

Solution Approach 2:

The surfactant branches provide local quality variation around the polyol backbone, with different regions having different wettability characteristics. The anionic surfactant branches provide hydrophilic zones for water penetration while nonionic branches provide hydrophobic zones for oil repellency, enabling simultaneous soil release and cleanability.

Inventive Principle:
Principle #3Local quality

2Stability of the object's composition

If synthetic fibers are treated with traditional soil release agents, then the treatment is permanent via crosslinking or heat-setting, but the fibers remain hydrophobic and oil stains are readily embedded

Engineering Contradiction:
Improvepermanence of treatmentVSAvoidoil and grime embedding
Core Design Contradiction:
Stability of the object's compositionVSObject-affected harmful factors

Solution Approach 1:

The invention changes the chemical parameters of the soil release agent by using a polyol backbone with multiple surfactant branches instead of traditional single-function agents. This parameter change enables the treatment to be permanent while simultaneously providing both hydrophobic and hydrophilic properties to prevent oil embedding.

Inventive Principle:
Principle #35Parameter changes

3Productivity

If textiles are washed with conventional detergents, then some soil is removed, but soil remaining in wash water is redeposited onto the textile material prior to the end of the wash cycle

Engineering Contradiction:
Improvecleaning efficiencyVSAvoidcomplete soil removal
Core Design Contradiction:
ProductivityVSReliability

Solution Approach 1:

The polyol backbone with surfactant branches acts as an intermediary agent that modifies the interaction between wash water and textile soils. The hydrophilic components facilitate water penetration while hydrophobic components prevent redeposition, enabling complete soil removal without compromising cleaning efficiency.

Inventive Principle:
Principle #24Intermediary (Mediator)

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The solution significantly enhances soil and oil release properties, improves moisture transport, and provides a biodegradable alternative, resulting in better cleaning efficacy and fabric comfort without adverse environmental impact, while also acting as an emulsion stabilizer and ironing aid.

Implementation Method 1

a multi-branched soil release/wetting agent having an oxygen-containing polyfunctional base compound and at least two surfactant branches attached thereto, wherein each surfactant branch includes at least one hydrophilic and at least one hydrophobic constituent

Methodology Applied
Scientific EffectSurfactant: Surfactant

Implementation Method 2

each surfactant branch includes at least one hydrophilic and at least one hydrophobic constituent

Methodology Applied
Scientific EffectHydrophilic interaction: Hydrophile

Implementation Method 3

synthetic fibers, and, therefore, fabrics having synthetic fibers incorporated therein or made entirely of synthetic fibers, are hydrophobic and oleophilic

Methodology Applied
Scientific EffectHydrophobic interaction: Hydrophobe

Data Source

PatentUS7655609B2Soil release agent
Publication Date: 2010.02.02 MILLIKEN & CO

AI summary

The invention relates to a soil release agent comprising a multi-branched soil release/wetting agent having an oxygen-containing polyfunctional base compound and at least two surfactant branches attached thereto, wherein each surfactant branch includes at least one hydrophilic and at least one hydrophobic constituent and a polyester release agent in an aqueous solution.