Multi-Capsule Fragrance Delivery System for Surfactant Stability

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Solution Overview

Problem

Fragrance materials in consumer products face premature release due to permeable capsule shells, especially when stored in aqueous bases with surfactants, leading to reduced effectiveness and increased costs, as existing encapsulation technologies struggle to maintain stability and desirable release profiles.

Innovation Solution

A capsule delivery system comprising multiple types of microcapsules with different wall materials, curing temperatures, and heating rates to enhance retention and stability, including melamine-formaldehyde and urea-formaldehyde capsules, which are designed to maintain fragrance release profiles and stability in consumer products for extended periods.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Reliability

If a single type of capsule shell is used to encapsulate fragrance materials, then the capsule provides basic protection and delivery, but the fragrance is prematurely released when stored in aqueous bases with surfactants

Engineering Contradiction:
Improvecapsule stabilityVSAvoidfragrance retention period
Core Design Contradiction:
ReliabilityVSDuration of action of moving object

Solution Approach 1:

The invention divides the capsule population into multiple segments with different wall compositions and properties. Each capsule type is formulated with specific wall materials (e.g., melamine-formaldehyde, polyurea, polyacrylamide/acrylate copolymers) and curing conditions to achieve different release profiles, collectively providing stable fragrance retention in surfactant-containing bases

Inventive Principle:
Principle #1Segmentation

Solution Approach 2:

The invention uses composite capsule walls made from multiple polymer materials with complementary properties. For example, melamine-formaldehyde provides structural integrity and chemical resistance, while polyacrylamide/acrylate copolymers provide controlled permeability. These composite structures resist surfactant penetration while allowing timed fragrance release

Inventive Principle:
Principle #40Composite materials

2Ease of manufacture

If conventional capsule shells are used in surfactant-containing bases, then the product can be manufactured with standard materials, but the active material is diffused from the core over time through leaching

Engineering Contradiction:
Improvecapsule production simplicityVSAvoidactive material loss
Core Design Contradiction:
Ease of manufactureVSLoss of substance

Solution Approach 1:

The invention modifies key parameters of capsule wall formation, including curing temperature (e.g., 70-90°C for polyacrylamide/acrylate copolymers, higher temperatures for melamine-formaldehyde), curing time, and wall composition ratios. These parameter changes create cross-linked polymer networks with reduced surfactant permeability while maintaining manufacturability through established encapsulation processes

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The capsule wall acts as an intermediary barrier between the fragrance core and the surfactant-containing base. The polymer matrix, particularly when cross-linked, provides a selective interface that allows controlled fragrance diffusion while blocking surfactant penetration, preventing leaching of active material

Inventive Principle:
Principle #24Intermediary (Mediator)

3Reliability

If higher concentrations of microcapsules are used to compensate for premature release, then fragrance delivery can be maintained initially, but product costs increase

Engineering Contradiction:
Improvefragrance delivery effectivenessVSAvoidmicrocapsule concentration required
Core Design Contradiction:
ReliabilityVSQuantity of substance

Solution Approach 1:

The invention creates a dynamic release system where different capsule types release fragrance at different rates. Fast-release capsules provide initial fragrance impact, while slow-release capsules with enhanced surfactant resistance provide sustained delivery. This dynamic multi-rate release maintains effective fragrance levels throughout product use without requiring excessive microcapsule concentrations

Inventive Principle:
Principle #15Dynamics

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The system effectively retains fragrance materials for longer periods, maintaining stability and desirable release profiles even in surfactant-containing bases, reducing the need for higher microcapsule concentrations and extending product shelf life while ensuring consistent sensory performance.

Implementation Method 1

the capsule shell is somewhat permeable to the core contents when stored under certain conditions

Methodology Applied
Scientific EffectPermeability: Permeation

Implementation Method 2

The overall leaching mechanism may be viewed as a diffusion process, with transfer occurring from the capsule core to the aqueous media

Methodology Applied
Scientific EffectDiffusion: Diffusion

Implementation Method 3

The polymeric material is used to protect the fragrance material from evaporation, reaction, oxidation or otherwise dissipating prior to use

Methodology Applied
Scientific EffectEvaporation: Evaporation

Data Source

PatentUS11471707B2Multi-capsule compositions
Publication Date: 2022.10.18 INTERNATIONAL FLAVORS & FRAGRANCES INC
  • US11471707B2 patent drawing
  • US11471707B2 patent drawing

AI summary

A capsule delivery system. The system has a first capsule containing a first capsule wall encapsulating a first active material and a second capsule containing a second capsule wall encapsulating a second active material. The first and second capsules differ in their wall materials, amounts of wall materials, ratios of wall materials, core modifiers, scavengers, active materials, curing temperatures, heating rates, curing times, or a combination thereof. Also provided is a consumer product containing this capsule delivery system.