Multi-Cavity Photoacoustic Cell for Simultaneous Gas Detection

Solution Overview

Problem

Current multi-gas detection systems based on photoacoustic spectroscopy face challenges in complexity, response time, and processing difficulty due to the need for multiple lasers and buffer chambers, which hinder simultaneous and rapid measurement of multiple gases.

Innovation Solution

A multi-cavity semi-open resonant photoacoustic cell structure with unique resonant cavities and a simplified design that eliminates the need for openings in the cavities, allowing simultaneous measurement of multiple gases with reduced gas equilibrium time and sample volume.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Adaptability or versatility

If multiple lasers are connected in parallel to measure multiple gases simultaneously, then the measurement capability is improved, but the system complexity increases

Engineering Contradiction:
Core Design Contradiction:
Adaptability or versatilityVSDevice complexity

Solution Approach 1:

The photoacoustic cell is divided into multiple independent resonant cavities, each optimized for a specific gas measurement. This segmentation allows different gases to be measured simultaneously in separate cavities without interfering with each other, enabling multi-gas capability while keeping each individual cavity simple in structure.

Inventive Principle:
Principle #1Segmentation

Solution Approach 2:

The photoacoustic cell is designed as a multi-functional device that can simultaneously measure multiple gases through its multiple resonant cavities. Each cavity serves a specific measurement function, and the entire cell integrates all these functions into a single instrument, eliminating the need for separate measurement systems.

Inventive Principle:
Principle #6Universality (Multi-functionality)

2Productivity

If multiple lasers are used to measure multiple gases, then the measurement speed is improved, but the response time increases

Engineering Contradiction:
Core Design Contradiction:
ProductivityVSLoss of time

Solution Approach 1:

The multiple resonant cavities are pre-configured with different resonance frequencies tailored to specific gases before measurement begins. This preliminary configuration allows the system to immediately start measuring multiple gases simultaneously without requiring sequential laser switching or warm-up periods for each gas type.

Inventive Principle:
Principle #10Preliminary action

Solution Approach 2:

The photoacoustic cell enables continuous simultaneous measurement of multiple gases through its multiple resonant cavities, which operate independently and continuously. This eliminates the need to switch between different measurement modes or wait for sequential measurements, maintaining continuous productive action.

Inventive Principle:
Principle #20Continuity of useful action

3Difficulty of detecting and measuring

If openings are made in the resonant cavities for acoustic sensor placement, then the measurement capability is improved, but the processing difficulty increases

Engineering Contradiction:
Core Design Contradiction:
Difficulty of detecting and measuringVSEase of manufacture

Solution Approach 1:

A flexible membrane is introduced as an intermediary element that separates the acoustic sensor from the resonant cavity interior. The membrane allows acoustic signals to pass through while maintaining the sealed cavity structure, eliminating the need for openings in the resonant cavities and simplifying manufacturing.

Inventive Principle:
Principle #24Intermediary (Mediator)

Solution Approach 2:

The mechanical opening in the cavity wall is replaced by a flexible membrane barrier that transmits acoustic signals without requiring physical penetration of the cavity. This substitution maintains the structural integrity and sealing of the resonant cavity while enabling acoustic sensor placement.

Inventive Principle:
Principle #28Mechanics substitution (Replace mechanical system)

4Stability of the object's composition

If buffer chambers are added to the photoacoustic cell, then the gas equilibrium is improved, but the gas equilibrium time increases

Engineering Contradiction:
Core Design Contradiction:
Stability of the object's compositionVSLoss of time

Solution Approach 1:

The buffer chamber is extracted or removed from the photoacoustic cell structure. By eliminating this component, the system achieves gas equilibrium more rapidly without the delay introduced by the buffer chamber, while still maintaining sufficient gas stability for accurate measurement through the optimized resonant cavity design.

Inventive Principle:
Principle #2Taking out (Extraction)

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

Enables rapid and sensitive simultaneous measurement of multiple gases with a simpler structure and reduced processing complexity, improving the efficiency and applicability of photoacoustic spectroscopy in multi-gas detection.

Implementation Method 1

Photoacoustic spectroscopy is a kind of spectral calorimetry technology that directly measures the thermal energy generated by the absorption of light energy. When a periodic modulation light source covers the absorption line of to-be-measured gas molecules, the gas molecules transit from a ground state to an excited state, and then return to the ground state through the non-radiative transition emitting heat

Methodology Applied
Scientific EffectPhotoacoustic effect: Photoacoustic Effect

Implementation Method 2

Because most gas molecules have absorption characteristic lines in the near- and mid-infrared spectral regions, the concentration of most gas molecules can be measured by using appropriate light sources and infrared absorption spectroscopy analysis methods

Methodology Applied
Scientific EffectAbsorption spectroscopy: Absorption Spectroscopy

Implementation Method 3

A resonant photoacoustic cell has a high sensitivity, and can achieve resonant amplification of sound waves. In a laser-based resonance photoacoustic system, a modulation frequency of an excitation light source needs to be matched with the resonance frequency of a photoacoustic cell

Methodology Applied
Scientific EffectResonance: Resonance

Implementation Method 4

the gas molecules periodically expand to generate sound waves. Because the amplitude of the sound wave is proportional to the concentration of the to-be-measured gas, the concentration information of the to-be-measured gas can be obtained by detecting a photoacoustic signal through an acoustic sensor

Methodology Applied
Scientific EffectSound wave generation: Sound

Data Source

PatentUS11300499B2Multi-cavity semi-open resonant photoacoustic cell and multi-gas simultaneous measurement system
Publication Date: 2022.04.12
  • US11300499B2 patent drawing
  • US11300499B2 patent drawing

AI summary

The present invention belongs to the technical field of trace gas detection, and relates to a multi-cavity semi-open resonant photoacoustic cell and a multi-gas simultaneous measurement system. The photoacoustic cell includes multiple resonant cavities. Each resonant cavity has a unique length and a unique resonant frequency, so each resonant cavity corresponds to one to-be-measured gas. A sensitive diaphragm of an acoustic sensor is fixed on one end face of the photoacoustic cell. Photoacoustic signals of different frequencies generated in the resonant cavities act on the sensitive diaphragm of the acoustic sensor, causing the sensitive diaphragm of the acoustic sensor to vibrate periodically. Concentration information of multiple to-be-measured gases can be obtained by analyzing the vibration of the sensitive diaphragm of the acoustic sensor.